Modification of PPy-NW anode by carbon dots for high-performance mini-microbial fuel cells

To boost the performance of microbial fuel cells (MFCs), a novel material of polypyrrole nanowires (PPy-NWs) modified by carbon dots (CDs) is synthesized by polymerizing pyrrole monomers and CDs, in which CDs are attached and distributed on the surface of the PPy-NWs, thus leading to the rough surfa...

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Main Authors: Mohtar, Mohd Nazim, Zhao, Zhiwei, Weng, Z., Lei, W., Zhu, D., Jiang, H., Mohtar, M. N., Abdul Halin, Izhal
Format: Article
Language:English
Published: Wiley 2020
Online Access:http://psasir.upm.edu.my/id/eprint/86804/1/Modification%20of%20PPy-NW%20anode%20by%20carbon%20dots%20.pdf
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author Mohtar, Mohd Nazim
Zhao, Zhiwei
Weng, Z.
Lei, W.
Zhu, D.
Jiang, H.
Mohtar, M. N.
Abdul Halin, Izhal
author_facet Mohtar, Mohd Nazim
Zhao, Zhiwei
Weng, Z.
Lei, W.
Zhu, D.
Jiang, H.
Mohtar, M. N.
Abdul Halin, Izhal
author_sort Mohtar, Mohd Nazim
collection UPM
description To boost the performance of microbial fuel cells (MFCs), a novel material of polypyrrole nanowires (PPy-NWs) modified by carbon dots (CDs) is synthesized by polymerizing pyrrole monomers and CDs, in which CDs are attached and distributed on the surface of the PPy-NWs, thus leading to the rough surface with a special dot-line structure. Such CDs/PPy-NW composite with special unique structure exhibits superior properties, and excellent performance is found for MFC using CDs/PPy-NW composite as anode. The electron transfer rate increases to 0.0934 s−1 with a sharp rise by 26% over pure PPy-NWs, and the resistances of CDs/PPy-NW electrode are only one third of those of pure PPy-NWs electrode. Further, the mini-MFC equipped with the CDs/PPy-NW composite as anode exhibits a high open circuit voltage (630 mV) and its maximum power density with a value of 291.4 mW m−2 is twice that of the mini-MFC equipped with pure PPy-NWs anode. These results demonstrate CDs/PPy-NW with a unique dot-line structure as a more promising anode material for MFC application.
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spelling upm.eprints-868042021-11-22T02:09:55Z http://psasir.upm.edu.my/id/eprint/86804/ Modification of PPy-NW anode by carbon dots for high-performance mini-microbial fuel cells Mohtar, Mohd Nazim Zhao, Zhiwei Weng, Z. Lei, W. Zhu, D. Jiang, H. Mohtar, M. N. Abdul Halin, Izhal To boost the performance of microbial fuel cells (MFCs), a novel material of polypyrrole nanowires (PPy-NWs) modified by carbon dots (CDs) is synthesized by polymerizing pyrrole monomers and CDs, in which CDs are attached and distributed on the surface of the PPy-NWs, thus leading to the rough surface with a special dot-line structure. Such CDs/PPy-NW composite with special unique structure exhibits superior properties, and excellent performance is found for MFC using CDs/PPy-NW composite as anode. The electron transfer rate increases to 0.0934 s−1 with a sharp rise by 26% over pure PPy-NWs, and the resistances of CDs/PPy-NW electrode are only one third of those of pure PPy-NWs electrode. Further, the mini-MFC equipped with the CDs/PPy-NW composite as anode exhibits a high open circuit voltage (630 mV) and its maximum power density with a value of 291.4 mW m−2 is twice that of the mini-MFC equipped with pure PPy-NWs anode. These results demonstrate CDs/PPy-NW with a unique dot-line structure as a more promising anode material for MFC application. Wiley 2020-04 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/86804/1/Modification%20of%20PPy-NW%20anode%20by%20carbon%20dots%20.pdf Mohtar, Mohd Nazim and Zhao, Zhiwei and Weng, Z. and Lei, W. and Zhu, D. and Jiang, H. and Mohtar, M. N. and Abdul Halin, Izhal (2020) Modification of PPy-NW anode by carbon dots for high-performance mini-microbial fuel cells. Fuel Cells, 20 (2). 203 - 211. ISSN 1615-6846; ESSN: 1615-6854 https://onlinelibrary.wiley.com/doi/abs/10.1002/fuce.201900210 10.1002/fuce.201900210
spellingShingle Mohtar, Mohd Nazim
Zhao, Zhiwei
Weng, Z.
Lei, W.
Zhu, D.
Jiang, H.
Mohtar, M. N.
Abdul Halin, Izhal
Modification of PPy-NW anode by carbon dots for high-performance mini-microbial fuel cells
title Modification of PPy-NW anode by carbon dots for high-performance mini-microbial fuel cells
title_full Modification of PPy-NW anode by carbon dots for high-performance mini-microbial fuel cells
title_fullStr Modification of PPy-NW anode by carbon dots for high-performance mini-microbial fuel cells
title_full_unstemmed Modification of PPy-NW anode by carbon dots for high-performance mini-microbial fuel cells
title_short Modification of PPy-NW anode by carbon dots for high-performance mini-microbial fuel cells
title_sort modification of ppy nw anode by carbon dots for high performance mini microbial fuel cells
url http://psasir.upm.edu.my/id/eprint/86804/1/Modification%20of%20PPy-NW%20anode%20by%20carbon%20dots%20.pdf
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