Effect of diacylglycerol interfacial crystallization on the physical stability of water-in-oil emulsions

The influence of diacylglycerol (DAG) combined with polyglycerol polyricinoleate (PGPR) on the stability of water-in-oil (W/O) emulsions containing hydrogenated palm oil (HPO) was studied. Polarized light microscope revealed that DAG promoted HPO to crystallize at the water–oil interface, providing...

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Main Authors: Yang, Jia, Qiu, Chaoying, Li, Guanghui, Wan, Jun Lee, Tan, Chin Ping, Lai, Oi Ming, Wang, Yong
Format: Article
Language:English
Published: Elsevier 2020
Online Access:http://psasir.upm.edu.my/id/eprint/88587/1/ABSTRACT.pdf
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author Yang, Jia
Qiu, Chaoying
Li, Guanghui
Wan, Jun Lee
Tan, Chin Ping
Lai, Oi Ming
Wang, Yong
author_facet Yang, Jia
Qiu, Chaoying
Li, Guanghui
Wan, Jun Lee
Tan, Chin Ping
Lai, Oi Ming
Wang, Yong
author_sort Yang, Jia
collection UPM
description The influence of diacylglycerol (DAG) combined with polyglycerol polyricinoleate (PGPR) on the stability of water-in-oil (W/O) emulsions containing hydrogenated palm oil (HPO) was studied. Polarized light microscope revealed that DAG promoted HPO to crystallize at the water–oil interface, providing the combination of Pickering and network stabilization effects. It was proposed that the molecular compatibility of fatty acids in DAG with HPO accounted for the promotional effect. The interfacial crystallization of DAG together with the surface activity of PGPR led to the formation of emulsions with uniform small droplets and high freeze–thaw stability. Further exploration of physical properties indicated that the combination of DAG and PGPR dramatically improved the emulsion’s viscoelasticity and obtained a larger deformation yield. Water droplets in DAG-based emulsions acted as active fillers to improve the network rigidity. Therefore, DAG is a promising material to be used as emulsifier to enhance the physical stability of W/O emulsions.
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spelling upm.eprints-885872021-12-22T02:01:35Z http://psasir.upm.edu.my/id/eprint/88587/ Effect of diacylglycerol interfacial crystallization on the physical stability of water-in-oil emulsions Yang, Jia Qiu, Chaoying Li, Guanghui Wan, Jun Lee Tan, Chin Ping Lai, Oi Ming Wang, Yong The influence of diacylglycerol (DAG) combined with polyglycerol polyricinoleate (PGPR) on the stability of water-in-oil (W/O) emulsions containing hydrogenated palm oil (HPO) was studied. Polarized light microscope revealed that DAG promoted HPO to crystallize at the water–oil interface, providing the combination of Pickering and network stabilization effects. It was proposed that the molecular compatibility of fatty acids in DAG with HPO accounted for the promotional effect. The interfacial crystallization of DAG together with the surface activity of PGPR led to the formation of emulsions with uniform small droplets and high freeze–thaw stability. Further exploration of physical properties indicated that the combination of DAG and PGPR dramatically improved the emulsion’s viscoelasticity and obtained a larger deformation yield. Water droplets in DAG-based emulsions acted as active fillers to improve the network rigidity. Therefore, DAG is a promising material to be used as emulsifier to enhance the physical stability of W/O emulsions. Elsevier 2020 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/88587/1/ABSTRACT.pdf Yang, Jia and Qiu, Chaoying and Li, Guanghui and Wan, Jun Lee and Tan, Chin Ping and Lai, Oi Ming and Wang, Yong (2020) Effect of diacylglycerol interfacial crystallization on the physical stability of water-in-oil emulsions. Food Chemistry, 327. art. no. 127014. pp. 1-9. ISSN 0308-8146; ESSN: 1873-7072 https://www.sciencedirect.com/science/article/pii/S0308814620308761 10.1016/j.foodchem.2020.127014
spellingShingle Yang, Jia
Qiu, Chaoying
Li, Guanghui
Wan, Jun Lee
Tan, Chin Ping
Lai, Oi Ming
Wang, Yong
Effect of diacylglycerol interfacial crystallization on the physical stability of water-in-oil emulsions
title Effect of diacylglycerol interfacial crystallization on the physical stability of water-in-oil emulsions
title_full Effect of diacylglycerol interfacial crystallization on the physical stability of water-in-oil emulsions
title_fullStr Effect of diacylglycerol interfacial crystallization on the physical stability of water-in-oil emulsions
title_full_unstemmed Effect of diacylglycerol interfacial crystallization on the physical stability of water-in-oil emulsions
title_short Effect of diacylglycerol interfacial crystallization on the physical stability of water-in-oil emulsions
title_sort effect of diacylglycerol interfacial crystallization on the physical stability of water in oil emulsions
url http://psasir.upm.edu.my/id/eprint/88587/1/ABSTRACT.pdf
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