Effects of sintering temperature variation on synthesis of glass-ceramic phosphor using rice husk ash as silica source

In this study, the authors attempted to propose the very first study on fabrication and characterization of zinc-boro-silicate (ZBS) glass-ceramics derived from the ternary zinc-boro-silicate (ZnO)0.65(B2O3)0.15(RHA)0.2 glass system through a conventional melt-quenching method by incorporating rice...

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Main Authors: Abdul Wahab, Rabiatul Adawiyah, Mohd Zaid, Mohd Hafiz, Ab Aziz, Sidek, Matori, Khamirul Amin, Yap, Wing Fen, Yaakob, Yazid
Format: Article
Language:English
Published: Multidisciplinary Digital Publishing Institute 2020
Online Access:http://psasir.upm.edu.my/id/eprint/88729/1/ABSTRACT.pdf
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author Abdul Wahab, Rabiatul Adawiyah
Mohd Zaid, Mohd Hafiz
Ab Aziz, Sidek
Matori, Khamirul Amin
Yap, Wing Fen
Yaakob, Yazid
author_facet Abdul Wahab, Rabiatul Adawiyah
Mohd Zaid, Mohd Hafiz
Ab Aziz, Sidek
Matori, Khamirul Amin
Yap, Wing Fen
Yaakob, Yazid
author_sort Abdul Wahab, Rabiatul Adawiyah
collection UPM
description In this study, the authors attempted to propose the very first study on fabrication and characterization of zinc-boro-silicate (ZBS) glass-ceramics derived from the ternary zinc-boro-silicate (ZnO)0.65(B2O3)0.15(RHA)0.2 glass system through a conventional melt-quenching method by incorporating rice husk ash (RHA) as the silica (SiO2) source, followed by a sintering process. Optimization of sintering condition has densified the sintered samples while embedded beta willemite (β-Zn2SiO4) and alpha willemite (α-Zn2SiO4) were proven in X-ray diffraction (XRD) analysis. Field emission scanning electron microscopy (FESEM) has shown the distribution of willemite crystals in rhombohedral shape crystals and successfully form closely-packed grains due to intense crystallization. The photoluminescence (PL) spectra of all sintered ZBS glasses presented various emission peaks at 425, 463, 487, 531, and 643 nm corresponded to violet, blue, green, and red emission, respectively. The correlation between the densification, phase transformation, microstructure, and photoluminescence of Zn2SiO4 glass-ceramic phosphor is discussed in detail.
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spelling upm.eprints-887292021-11-03T06:23:17Z http://psasir.upm.edu.my/id/eprint/88729/ Effects of sintering temperature variation on synthesis of glass-ceramic phosphor using rice husk ash as silica source Abdul Wahab, Rabiatul Adawiyah Mohd Zaid, Mohd Hafiz Ab Aziz, Sidek Matori, Khamirul Amin Yap, Wing Fen Yaakob, Yazid In this study, the authors attempted to propose the very first study on fabrication and characterization of zinc-boro-silicate (ZBS) glass-ceramics derived from the ternary zinc-boro-silicate (ZnO)0.65(B2O3)0.15(RHA)0.2 glass system through a conventional melt-quenching method by incorporating rice husk ash (RHA) as the silica (SiO2) source, followed by a sintering process. Optimization of sintering condition has densified the sintered samples while embedded beta willemite (β-Zn2SiO4) and alpha willemite (α-Zn2SiO4) were proven in X-ray diffraction (XRD) analysis. Field emission scanning electron microscopy (FESEM) has shown the distribution of willemite crystals in rhombohedral shape crystals and successfully form closely-packed grains due to intense crystallization. The photoluminescence (PL) spectra of all sintered ZBS glasses presented various emission peaks at 425, 463, 487, 531, and 643 nm corresponded to violet, blue, green, and red emission, respectively. The correlation between the densification, phase transformation, microstructure, and photoluminescence of Zn2SiO4 glass-ceramic phosphor is discussed in detail. Multidisciplinary Digital Publishing Institute 2020 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/88729/1/ABSTRACT.pdf Abdul Wahab, Rabiatul Adawiyah and Mohd Zaid, Mohd Hafiz and Ab Aziz, Sidek and Matori, Khamirul Amin and Yap, Wing Fen and Yaakob, Yazid (2020) Effects of sintering temperature variation on synthesis of glass-ceramic phosphor using rice husk ash as silica source. Materials, 13 (23). pp. 1-14. ISSN 1996-1944 https://www.mdpi.com/1996-1944/13/23/5413 10.3390/ma13235413
spellingShingle Abdul Wahab, Rabiatul Adawiyah
Mohd Zaid, Mohd Hafiz
Ab Aziz, Sidek
Matori, Khamirul Amin
Yap, Wing Fen
Yaakob, Yazid
Effects of sintering temperature variation on synthesis of glass-ceramic phosphor using rice husk ash as silica source
title Effects of sintering temperature variation on synthesis of glass-ceramic phosphor using rice husk ash as silica source
title_full Effects of sintering temperature variation on synthesis of glass-ceramic phosphor using rice husk ash as silica source
title_fullStr Effects of sintering temperature variation on synthesis of glass-ceramic phosphor using rice husk ash as silica source
title_full_unstemmed Effects of sintering temperature variation on synthesis of glass-ceramic phosphor using rice husk ash as silica source
title_short Effects of sintering temperature variation on synthesis of glass-ceramic phosphor using rice husk ash as silica source
title_sort effects of sintering temperature variation on synthesis of glass ceramic phosphor using rice husk ash as silica source
url http://psasir.upm.edu.my/id/eprint/88729/1/ABSTRACT.pdf
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