Waste NR latex based-precursors as carbon source for CNTs eco-fabrications

In this work, the potential of utilizing a waste latex-based precursor (i.e., natural rubber glove (NRG)) as a carbon source for carbon nanotube (CNT) fabrication via chemical vapor deposition has been demonstrated. Gas chromatography-mass spectroscopy (GC-MS) analysis reveals that the separation of...

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Main Authors: Hazan, Mohd Adib, Chan, Kar Fei, Jofri, Khairun Afiqa, Mamat, Md Shuhazlly, Endot, Nor Azam, Shahira Liza, Ismail, Ismayadi, Hussein, Mohd Zobir, Tanemura, Masaki, Yaakob, Yazid
Format: Article
Language:English
Published: MDPI 2021
Online Access:http://psasir.upm.edu.my/id/eprint/93566/1/Waste%20NR%20latex%20based-precursors.pdf
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author Hazan, Mohd Adib
Chan, Kar Fei
Jofri, Khairun Afiqa
Mamat, Md Shuhazlly
Endot, Nor Azam
Shahira Liza
Ismail, Ismayadi
Hussein, Mohd Zobir
Tanemura, Masaki
Yaakob, Yazid
author_facet Hazan, Mohd Adib
Chan, Kar Fei
Jofri, Khairun Afiqa
Mamat, Md Shuhazlly
Endot, Nor Azam
Shahira Liza
Ismail, Ismayadi
Hussein, Mohd Zobir
Tanemura, Masaki
Yaakob, Yazid
author_sort Hazan, Mohd Adib
collection UPM
description In this work, the potential of utilizing a waste latex-based precursor (i.e., natural rubber glove (NRG)) as a carbon source for carbon nanotube (CNT) fabrication via chemical vapor deposition has been demonstrated. Gas chromatography-mass spectroscopy (GC-MS) analysis reveals that the separation of the lightweight hydrocarbon chain from the heavier long chain differs in hydrocarbon contents in the NRG fraction (NRG-L). Both solid NRG (NRG-S) and NRG-L samples contain >63% carbon, <0.6% sulfur and <0.08% nitrogen content, respectively, as per carbon-nitrogen-sulfur (CNS) analysis. Growth of CNTs on the samples was confirmed by Raman spectra, SEM and TEM images, whereby it was shown that NRG-S is better than NRG-L in terms of synthesized CNTs yield percentage with similar quality. The optimum vaporization and reaction temperatures were 350 and 800 °C, respectively, considering the balance of good yield percentage (26.7%) and quality of CNTs (ID/IG = 0.84 ± 0.08, diameter ≈ 122 nm) produced. Thus, utilization of waste NRG as a candidate for carbon feedstock to produce value-added CNTs products could be a significant approach for eco-technology.
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spelling upm.eprints-935662022-11-22T08:49:22Z http://psasir.upm.edu.my/id/eprint/93566/ Waste NR latex based-precursors as carbon source for CNTs eco-fabrications Hazan, Mohd Adib Chan, Kar Fei Jofri, Khairun Afiqa Mamat, Md Shuhazlly Endot, Nor Azam Shahira Liza Ismail, Ismayadi Hussein, Mohd Zobir Tanemura, Masaki Yaakob, Yazid In this work, the potential of utilizing a waste latex-based precursor (i.e., natural rubber glove (NRG)) as a carbon source for carbon nanotube (CNT) fabrication via chemical vapor deposition has been demonstrated. Gas chromatography-mass spectroscopy (GC-MS) analysis reveals that the separation of the lightweight hydrocarbon chain from the heavier long chain differs in hydrocarbon contents in the NRG fraction (NRG-L). Both solid NRG (NRG-S) and NRG-L samples contain >63% carbon, <0.6% sulfur and <0.08% nitrogen content, respectively, as per carbon-nitrogen-sulfur (CNS) analysis. Growth of CNTs on the samples was confirmed by Raman spectra, SEM and TEM images, whereby it was shown that NRG-S is better than NRG-L in terms of synthesized CNTs yield percentage with similar quality. The optimum vaporization and reaction temperatures were 350 and 800 °C, respectively, considering the balance of good yield percentage (26.7%) and quality of CNTs (ID/IG = 0.84 ± 0.08, diameter ≈ 122 nm) produced. Thus, utilization of waste NRG as a candidate for carbon feedstock to produce value-added CNTs products could be a significant approach for eco-technology. MDPI 2021-10-04 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/93566/1/Waste%20NR%20latex%20based-precursors.pdf Hazan, Mohd Adib and Chan, Kar Fei and Jofri, Khairun Afiqa and Mamat, Md Shuhazlly and Endot, Nor Azam and Shahira Liza and Ismail, Ismayadi and Hussein, Mohd Zobir and Tanemura, Masaki and Yaakob, Yazid (2021) Waste NR latex based-precursors as carbon source for CNTs eco-fabrications. Polymers, 13 (19). Jan-17. ISSN 2073-4360 https://www.mdpi.com/2073-4360/13/19/3409 10.3390/polym13193409
spellingShingle Hazan, Mohd Adib
Chan, Kar Fei
Jofri, Khairun Afiqa
Mamat, Md Shuhazlly
Endot, Nor Azam
Shahira Liza
Ismail, Ismayadi
Hussein, Mohd Zobir
Tanemura, Masaki
Yaakob, Yazid
Waste NR latex based-precursors as carbon source for CNTs eco-fabrications
title Waste NR latex based-precursors as carbon source for CNTs eco-fabrications
title_full Waste NR latex based-precursors as carbon source for CNTs eco-fabrications
title_fullStr Waste NR latex based-precursors as carbon source for CNTs eco-fabrications
title_full_unstemmed Waste NR latex based-precursors as carbon source for CNTs eco-fabrications
title_short Waste NR latex based-precursors as carbon source for CNTs eco-fabrications
title_sort waste nr latex based precursors as carbon source for cnts eco fabrications
url http://psasir.upm.edu.my/id/eprint/93566/1/Waste%20NR%20latex%20based-precursors.pdf
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