Bifunctional biomass-based catalyst for biodiesel production via hydrothermal carbonization (HTC) pretreatment – synthesis, characterization and optimization
The hydrothermal carbonization (HTC) technique is known for its advantages in producing hydrochar from biomass samples with high water content compared to conventional pyrolysis techniques. This study utilized HTC to produce an activated carbon catalyst from renewable mesocarp fiber derived from pal...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Published: |
Elsevier
2021
|
| _version_ | 1796983205290573824 |
|---|---|
| author | Abdullah, Rose Fadzilah Rashid, Umer Ibrahim, Mohd Lokman NolHakim, Muhammad Amirrul Hakim Lokman Moser, Bryan R. Alharthi, Fahad A. |
| author_facet | Abdullah, Rose Fadzilah Rashid, Umer Ibrahim, Mohd Lokman NolHakim, Muhammad Amirrul Hakim Lokman Moser, Bryan R. Alharthi, Fahad A. |
| author_sort | Abdullah, Rose Fadzilah |
| collection | UPM |
| description | The hydrothermal carbonization (HTC) technique is known for its advantages in producing hydrochar from biomass samples with high water content compared to conventional pyrolysis techniques. This study utilized HTC to produce an activated carbon catalyst from renewable mesocarp fiber derived from palm oil processing. The introduction of K2CO3 and Cu(NO3)2 produced a bifunctional catalyst suitable for conversion of used cooking oil to biodiesel. The catalyst possessed a mesoporous structure with a BET surface area of 3909.33 m2/g. An optimum treatment ratio of 4:1 (K2CO3: Cu(NO3)2) provided elevated basic (5.52 mmol/g) and acidic (1.68 mmol/g) concentrations on the catalytic surface, which promoted esterification and transesterification reactions. Maximum yield (96.4%) of biodiesel was obtained at 70 °C for 2 h with 5 wt% catalyst and a 12:1 molar ratio of methanol to oil. The catalyst endured up to 5 reaction cycles while maintaining biodiesel yields of more than 80%. These findings indicated that HTC pretreatment yielded a high-quality bifunctional catalyst for conversion of low-quality used cooking oil for production of biodiesel. |
| first_indexed | 2024-03-06T11:03:10Z |
| format | Article |
| id | upm.eprints-96203 |
| institution | Universiti Putra Malaysia |
| last_indexed | 2024-03-06T11:03:10Z |
| publishDate | 2021 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | upm.eprints-962032023-01-31T03:15:08Z http://psasir.upm.edu.my/id/eprint/96203/ Bifunctional biomass-based catalyst for biodiesel production via hydrothermal carbonization (HTC) pretreatment – synthesis, characterization and optimization Abdullah, Rose Fadzilah Rashid, Umer Ibrahim, Mohd Lokman NolHakim, Muhammad Amirrul Hakim Lokman Moser, Bryan R. Alharthi, Fahad A. The hydrothermal carbonization (HTC) technique is known for its advantages in producing hydrochar from biomass samples with high water content compared to conventional pyrolysis techniques. This study utilized HTC to produce an activated carbon catalyst from renewable mesocarp fiber derived from palm oil processing. The introduction of K2CO3 and Cu(NO3)2 produced a bifunctional catalyst suitable for conversion of used cooking oil to biodiesel. The catalyst possessed a mesoporous structure with a BET surface area of 3909.33 m2/g. An optimum treatment ratio of 4:1 (K2CO3: Cu(NO3)2) provided elevated basic (5.52 mmol/g) and acidic (1.68 mmol/g) concentrations on the catalytic surface, which promoted esterification and transesterification reactions. Maximum yield (96.4%) of biodiesel was obtained at 70 °C for 2 h with 5 wt% catalyst and a 12:1 molar ratio of methanol to oil. The catalyst endured up to 5 reaction cycles while maintaining biodiesel yields of more than 80%. These findings indicated that HTC pretreatment yielded a high-quality bifunctional catalyst for conversion of low-quality used cooking oil for production of biodiesel. Elsevier 2021 Article PeerReviewed Abdullah, Rose Fadzilah and Rashid, Umer and Ibrahim, Mohd Lokman and NolHakim, Muhammad Amirrul Hakim Lokman and Moser, Bryan R. and Alharthi, Fahad A. (2021) Bifunctional biomass-based catalyst for biodiesel production via hydrothermal carbonization (HTC) pretreatment – synthesis, characterization and optimization. Process Safety and Environmental Protection, 156. 219 - 230. ISSN 0957-5820 https://www.sciencedirect.com/science/article/pii/S0957582021005280 10.1016/j.psep.2021.10.007 |
| spellingShingle | Abdullah, Rose Fadzilah Rashid, Umer Ibrahim, Mohd Lokman NolHakim, Muhammad Amirrul Hakim Lokman Moser, Bryan R. Alharthi, Fahad A. Bifunctional biomass-based catalyst for biodiesel production via hydrothermal carbonization (HTC) pretreatment – synthesis, characterization and optimization |
| title | Bifunctional biomass-based catalyst for biodiesel production via hydrothermal carbonization (HTC) pretreatment – synthesis, characterization and optimization |
| title_full | Bifunctional biomass-based catalyst for biodiesel production via hydrothermal carbonization (HTC) pretreatment – synthesis, characterization and optimization |
| title_fullStr | Bifunctional biomass-based catalyst for biodiesel production via hydrothermal carbonization (HTC) pretreatment – synthesis, characterization and optimization |
| title_full_unstemmed | Bifunctional biomass-based catalyst for biodiesel production via hydrothermal carbonization (HTC) pretreatment – synthesis, characterization and optimization |
| title_short | Bifunctional biomass-based catalyst for biodiesel production via hydrothermal carbonization (HTC) pretreatment – synthesis, characterization and optimization |
| title_sort | bifunctional biomass based catalyst for biodiesel production via hydrothermal carbonization htc pretreatment synthesis characterization and optimization |
| work_keys_str_mv | AT abdullahrosefadzilah bifunctionalbiomassbasedcatalystforbiodieselproductionviahydrothermalcarbonizationhtcpretreatmentsynthesischaracterizationandoptimization AT rashidumer bifunctionalbiomassbasedcatalystforbiodieselproductionviahydrothermalcarbonizationhtcpretreatmentsynthesischaracterizationandoptimization AT ibrahimmohdlokman bifunctionalbiomassbasedcatalystforbiodieselproductionviahydrothermalcarbonizationhtcpretreatmentsynthesischaracterizationandoptimization AT nolhakimmuhammadamirrulhakimlokman bifunctionalbiomassbasedcatalystforbiodieselproductionviahydrothermalcarbonizationhtcpretreatmentsynthesischaracterizationandoptimization AT moserbryanr bifunctionalbiomassbasedcatalystforbiodieselproductionviahydrothermalcarbonizationhtcpretreatmentsynthesischaracterizationandoptimization AT alharthifahada bifunctionalbiomassbasedcatalystforbiodieselproductionviahydrothermalcarbonizationhtcpretreatmentsynthesischaracterizationandoptimization |