Cation/Anion substitution into spinel LiMn2O4 cathode material for Li-ion battery application: a review of recent progress
Spinel LiMn2O4 is a positive electrode material with a robust structure. It has a three-dimensional network of channels for fast lithium-ion diffusion in state-of-the-art lithium rechargeable batteries. It is commercialized because of its high-power and cost-effective natural abundant element. Howev...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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The Electrochemical Society
2021
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| Online Access: | http://psasir.upm.edu.my/id/eprint/96304/1/MJMS28042021_14.pdf |
| _version_ | 1825937691263369216 |
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| author | Zahoor, Ahmed Liew, Josephine Ying Chyi Talib, Zainal Abidin |
| author_facet | Zahoor, Ahmed Liew, Josephine Ying Chyi Talib, Zainal Abidin |
| author_sort | Zahoor, Ahmed |
| collection | UPM |
| description | Spinel LiMn2O4 is a positive electrode material with a robust structure. It has a three-dimensional network of channels for fast lithium-ion diffusion in state-of-the-art lithium rechargeable batteries. It is commercialized because of its high-power and cost-effective natural abundant element. However, its capacity fading and cycle performance, originating from Mn dissolution, still need improvement. In this review, the recent development of the effect of cation and anion doped into the spinel LiMn2O4 cathode material is thoroughly investigated. The effect of anion substitution on the morphology and electrochemical properties were investigated. Cation/anion substitution shows improvement in the structural stability and suppresses lattice deformation of the material. Finally, some insight into the future prospects for spinel cathode developments is provided. |
| first_indexed | 2024-03-06T11:03:21Z |
| format | Article |
| id | upm.eprints-96304 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T11:03:21Z |
| publishDate | 2021 |
| publisher | The Electrochemical Society |
| record_format | dspace |
| spelling | upm.eprints-963042023-01-31T02:57:40Z http://psasir.upm.edu.my/id/eprint/96304/ Cation/Anion substitution into spinel LiMn2O4 cathode material for Li-ion battery application: a review of recent progress Zahoor, Ahmed Liew, Josephine Ying Chyi Talib, Zainal Abidin Spinel LiMn2O4 is a positive electrode material with a robust structure. It has a three-dimensional network of channels for fast lithium-ion diffusion in state-of-the-art lithium rechargeable batteries. It is commercialized because of its high-power and cost-effective natural abundant element. However, its capacity fading and cycle performance, originating from Mn dissolution, still need improvement. In this review, the recent development of the effect of cation and anion doped into the spinel LiMn2O4 cathode material is thoroughly investigated. The effect of anion substitution on the morphology and electrochemical properties were investigated. Cation/anion substitution shows improvement in the structural stability and suppresses lattice deformation of the material. Finally, some insight into the future prospects for spinel cathode developments is provided. The Electrochemical Society 2021 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/96304/1/MJMS28042021_14.pdf Zahoor, Ahmed and Liew, Josephine Ying Chyi and Talib, Zainal Abidin (2021) Cation/Anion substitution into spinel LiMn2O4 cathode material for Li-ion battery application: a review of recent progress. Solid State Science and Technology, 28 (4). pp. 138-145. ISSN 2162-8769; ESSN: 2162-8777 https://myjms.mohe.gov.my/index.php/masshp/article/view/17278 10.21315/mjms2021.28.4.14 |
| spellingShingle | Zahoor, Ahmed Liew, Josephine Ying Chyi Talib, Zainal Abidin Cation/Anion substitution into spinel LiMn2O4 cathode material for Li-ion battery application: a review of recent progress |
| title | Cation/Anion substitution into spinel LiMn2O4 cathode material for Li-ion battery application: a review of recent progress |
| title_full | Cation/Anion substitution into spinel LiMn2O4 cathode material for Li-ion battery application: a review of recent progress |
| title_fullStr | Cation/Anion substitution into spinel LiMn2O4 cathode material for Li-ion battery application: a review of recent progress |
| title_full_unstemmed | Cation/Anion substitution into spinel LiMn2O4 cathode material for Li-ion battery application: a review of recent progress |
| title_short | Cation/Anion substitution into spinel LiMn2O4 cathode material for Li-ion battery application: a review of recent progress |
| title_sort | cation anion substitution into spinel limn2o4 cathode material for li ion battery application a review of recent progress |
| url | http://psasir.upm.edu.my/id/eprint/96304/1/MJMS28042021_14.pdf |
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