Effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar

The influence of biomass cellulosic content on biochar nanopore structure and adsorption capacity in aqueous phase was scarcely reported. Commercial cellulose (100% cellulose), oil palm frond (39.5% cellulose), and palm kernel shell (20.5% cellulose) were pyrolyzed AT 630 °C, characterized and teste...

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Main Authors: Lawal, Abubakar Abdullahi, Hassan, Mohd Ali, Zakaria @ Mamat, Mohd Rafein, Mohd Yusoff, Mohd Zulkhairi, Norrrahim, Mohd Nor Faiz, Mokhtar, Mohd Noriznan, Shirai, Yoshihito
Format: Article
Language:English
Published: Elsevier 2021
Online Access:http://psasir.upm.edu.my/id/eprint/96924/1/ABSTRACT.pdf
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author Lawal, Abubakar Abdullahi
Hassan, Mohd Ali
Zakaria @ Mamat, Mohd Rafein
Mohd Yusoff, Mohd Zulkhairi
Norrrahim, Mohd Nor Faiz
Mokhtar, Mohd Noriznan
Shirai, Yoshihito
author_facet Lawal, Abubakar Abdullahi
Hassan, Mohd Ali
Zakaria @ Mamat, Mohd Rafein
Mohd Yusoff, Mohd Zulkhairi
Norrrahim, Mohd Nor Faiz
Mokhtar, Mohd Noriznan
Shirai, Yoshihito
author_sort Lawal, Abubakar Abdullahi
collection UPM
description The influence of biomass cellulosic content on biochar nanopore structure and adsorption capacity in aqueous phase was scarcely reported. Commercial cellulose (100% cellulose), oil palm frond (39.5% cellulose), and palm kernel shell (20.5% cellulose) were pyrolyzed AT 630 °C, characterized and tested for the adsorption of iodine and organic contaminants. The external surface area and average pore size increased with cellulosic content, where commercial cellulose formed biochar with external surface area of 95.4 m2/g and average pore size of 4.1 nm. The biochar from commercial cellulose had the largest adsorption capacities: 371.40 mg/g for iodine, 86.7 mg/L for tannic acid, 17.89 mg/g for COD and 60.35 mg/g for colour, while biochar from palm kernel shell had the least adsorption capacities. The cellulosic content reflected the differences in biochar nanopore structure and adsorption capacities, signifying the suitability of highly cellulosic biomass for producing biochar to effectively treat wastewater.
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spelling upm.eprints-969242022-11-30T06:06:28Z http://psasir.upm.edu.my/id/eprint/96924/ Effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar Lawal, Abubakar Abdullahi Hassan, Mohd Ali Zakaria @ Mamat, Mohd Rafein Mohd Yusoff, Mohd Zulkhairi Norrrahim, Mohd Nor Faiz Mokhtar, Mohd Noriznan Shirai, Yoshihito The influence of biomass cellulosic content on biochar nanopore structure and adsorption capacity in aqueous phase was scarcely reported. Commercial cellulose (100% cellulose), oil palm frond (39.5% cellulose), and palm kernel shell (20.5% cellulose) were pyrolyzed AT 630 °C, characterized and tested for the adsorption of iodine and organic contaminants. The external surface area and average pore size increased with cellulosic content, where commercial cellulose formed biochar with external surface area of 95.4 m2/g and average pore size of 4.1 nm. The biochar from commercial cellulose had the largest adsorption capacities: 371.40 mg/g for iodine, 86.7 mg/L for tannic acid, 17.89 mg/g for COD and 60.35 mg/g for colour, while biochar from palm kernel shell had the least adsorption capacities. The cellulosic content reflected the differences in biochar nanopore structure and adsorption capacities, signifying the suitability of highly cellulosic biomass for producing biochar to effectively treat wastewater. Elsevier 2021 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/96924/1/ABSTRACT.pdf Lawal, Abubakar Abdullahi and Hassan, Mohd Ali and Zakaria @ Mamat, Mohd Rafein and Mohd Yusoff, Mohd Zulkhairi and Norrrahim, Mohd Nor Faiz and Mokhtar, Mohd Noriznan and Shirai, Yoshihito (2021) Effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar. Bioresource Technology, 332. art. no. 125070. pp. 1-7. ISSN 0960-8524; ESSN: 1873-2976 https://www.sciencedirect.com/science/article/pii/S0960852421004090 10.1016/j.biortech.2021.125070
spellingShingle Lawal, Abubakar Abdullahi
Hassan, Mohd Ali
Zakaria @ Mamat, Mohd Rafein
Mohd Yusoff, Mohd Zulkhairi
Norrrahim, Mohd Nor Faiz
Mokhtar, Mohd Noriznan
Shirai, Yoshihito
Effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar
title Effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar
title_full Effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar
title_fullStr Effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar
title_full_unstemmed Effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar
title_short Effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar
title_sort effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar
url http://psasir.upm.edu.my/id/eprint/96924/1/ABSTRACT.pdf
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