Characterization of microstructures evolution on electrical responses of CaCu3Ti4O12 ceramics
CaCu3Ti4O12 (CCTO) ceramics was prepared by solid state method. The raw materials of CaCO3, CuO, and TiO2 were ball milled for 1 h. The mixed powders were calcined at 900 oC for 12 h. The phase formations of calcined powders were analyzed by using X-ray Diffraction (XRD). The calcined powders wer...
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| Format: | Article |
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Elsevier
2016
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| author | Ab Rahman, Mohd Fariz Hutagalung, Sabar Derita Ahmad, Zainal Arifin Ain, Mohd Fadzil Mohamed, Julie Juliewatty |
| author_facet | Ab Rahman, Mohd Fariz Hutagalung, Sabar Derita Ahmad, Zainal Arifin Ain, Mohd Fadzil Mohamed, Julie Juliewatty |
| author_sort | Ab Rahman, Mohd Fariz |
| collection | USM |
| description | CaCu3Ti4O12 (CCTO) ceramics was prepared by solid state method. The raw materials
of CaCO3, CuO, and TiO2 were ball milled for 1 h. The mixed powders were calcined at 900 oC for
12 h. The phase formations of calcined powders were analyzed by using X-ray Diffraction (XRD).
The calcined powders were pressed into pellet shape at 300 MPa and then were sintered at 1020,
1030 and 1040 oC for 10 h, respectively. The sintered samples were subjected to XRD, Scanning
Electron Microscopy (SEM) and Impedance Analyzer for phase formation, microstructural and
dielectric measurement analysis respectively. XRD analysis shows the presence of CCTO and secondary
phases for the calcined powders. The samples sintered at 1020 and 1040 oC show the formation
of CCTO phase with trace of secondary phases while complete formation of CCTO single
phase was obtained for the sample sintered at 1030 oC. SEM analysis shows the phenomena of
abnormal grain growth for the samples sintered at 1020 and 1040 oC while fine grain was observed
for the sample sintered at 1030 oC. Sample sintered at 1040 oC was the densest sample while the
sample sintered at 1020 oC had the highest percent of porosity. The highest dielectric constant
(-3748) was achieved for samples sintered at 1040 oC while the lowest dielectric loss (-0.025)
was obtained for the samples sintered at 1020 oC. These results indicate that sintering temperatures
effectively changed the properties of CCTO. |
| first_indexed | 2024-03-06T15:09:26Z |
| format | Article |
| id | usm.eprints-36830 |
| institution | Universiti Sains Malaysia |
| last_indexed | 2024-03-06T15:09:26Z |
| publishDate | 2016 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | usm.eprints-368302017-09-29T02:12:17Z http://eprints.usm.my/36830/ Characterization of microstructures evolution on electrical responses of CaCu3Ti4O12 ceramics Ab Rahman, Mohd Fariz Hutagalung, Sabar Derita Ahmad, Zainal Arifin Ain, Mohd Fadzil Mohamed, Julie Juliewatty TK1-9971 Electrical engineering. Electronics. Nuclear engineering TN1-997 Mining engineering. Metallurgy CaCu3Ti4O12 (CCTO) ceramics was prepared by solid state method. The raw materials of CaCO3, CuO, and TiO2 were ball milled for 1 h. The mixed powders were calcined at 900 oC for 12 h. The phase formations of calcined powders were analyzed by using X-ray Diffraction (XRD). The calcined powders were pressed into pellet shape at 300 MPa and then were sintered at 1020, 1030 and 1040 oC for 10 h, respectively. The sintered samples were subjected to XRD, Scanning Electron Microscopy (SEM) and Impedance Analyzer for phase formation, microstructural and dielectric measurement analysis respectively. XRD analysis shows the presence of CCTO and secondary phases for the calcined powders. The samples sintered at 1020 and 1040 oC show the formation of CCTO phase with trace of secondary phases while complete formation of CCTO single phase was obtained for the sample sintered at 1030 oC. SEM analysis shows the phenomena of abnormal grain growth for the samples sintered at 1020 and 1040 oC while fine grain was observed for the sample sintered at 1030 oC. Sample sintered at 1040 oC was the densest sample while the sample sintered at 1020 oC had the highest percent of porosity. The highest dielectric constant (-3748) was achieved for samples sintered at 1040 oC while the lowest dielectric loss (-0.025) was obtained for the samples sintered at 1020 oC. These results indicate that sintering temperatures effectively changed the properties of CCTO. Elsevier 2016 Article PeerReviewed Ab Rahman, Mohd Fariz and Hutagalung, Sabar Derita and Ahmad, Zainal Arifin and Ain, Mohd Fadzil and Mohamed, Julie Juliewatty (2016) Characterization of microstructures evolution on electrical responses of CaCu3Ti4O12 ceramics. Journal of King Saud University (Engineering Science), 2016 (28). pp. 240-245. ISSN 1018-3639 http://dx.doi.org/10.1016/j.jksues.2014.03.008 |
| spellingShingle | TK1-9971 Electrical engineering. Electronics. Nuclear engineering TN1-997 Mining engineering. Metallurgy Ab Rahman, Mohd Fariz Hutagalung, Sabar Derita Ahmad, Zainal Arifin Ain, Mohd Fadzil Mohamed, Julie Juliewatty Characterization of microstructures evolution on electrical responses of CaCu3Ti4O12 ceramics |
| title | Characterization of microstructures evolution
on electrical responses of CaCu3Ti4O12 ceramics |
| title_full | Characterization of microstructures evolution
on electrical responses of CaCu3Ti4O12 ceramics |
| title_fullStr | Characterization of microstructures evolution
on electrical responses of CaCu3Ti4O12 ceramics |
| title_full_unstemmed | Characterization of microstructures evolution
on electrical responses of CaCu3Ti4O12 ceramics |
| title_short | Characterization of microstructures evolution
on electrical responses of CaCu3Ti4O12 ceramics |
| title_sort | characterization of microstructures evolution on electrical responses of cacu3ti4o12 ceramics |
| topic | TK1-9971 Electrical engineering. Electronics. Nuclear engineering TN1-997 Mining engineering. Metallurgy |
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