Exploratory study of heterocyclic nitrogen-based ionic liquids as supramolecular structure-directing agents in zeolite synthesis.
This project reported the synthesis of novel heterocyclic nitrogen-based ionic liquid molecules as novel structure-directing agents (SDAs) in the synthesis uf zeulite microporous materials. The first part of this project discussed about the synthesis of several types of heterocyclic nitrogen-based...
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| Format: | Monograph |
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Universiti Sains Malaysia
2017
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| _version_ | 1825833552721215488 |
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| author | Ng , Eng Poh |
| author_facet | Ng , Eng Poh |
| author_sort | Ng , Eng Poh |
| collection | USM |
| description | This project reported the synthesis of novel heterocyclic nitrogen-based ionic liquid molecules as novel structure-directing agents (SDAs) in the synthesis uf zeulite microporous materials. The first part of this project discussed about the synthesis of several types of
heterocyclic nitrogen-based SDAs. The prepared SDAs were then characterized using IR, IH NMR, TG/DTG and CHN analyses. The experiment was then followed by the formation study of iron-containing AIPO-5 crystals in the presence of phosphorous acid (H3P03) by using
imidazolium-based SDA ([bdmim ]el) under ionothermal condition. The formation process of FeAPO-5 during the ionothermal synthesis was monitored by microscopic and spectroscopic methods. The roles of Fe3+ and H3POJ in the formation of the FeAPO-5 framework were investigated. Possible mechanism for the growth of FeAPO-5 crystals was proposed based on the experimental results.
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| first_indexed | 2024-03-06T15:09:32Z |
| format | Monograph |
| id | usm.eprints-36867 |
| institution | Universiti Sains Malaysia |
| last_indexed | 2024-03-06T15:09:32Z |
| publishDate | 2017 |
| publisher | Universiti Sains Malaysia |
| record_format | dspace |
| spelling | usm.eprints-368672017-10-02T07:25:40Z http://eprints.usm.my/36867/ Exploratory study of heterocyclic nitrogen-based ionic liquids as supramolecular structure-directing agents in zeolite synthesis. Ng , Eng Poh QD1-999 Chemistry This project reported the synthesis of novel heterocyclic nitrogen-based ionic liquid molecules as novel structure-directing agents (SDAs) in the synthesis uf zeulite microporous materials. The first part of this project discussed about the synthesis of several types of heterocyclic nitrogen-based SDAs. The prepared SDAs were then characterized using IR, IH NMR, TG/DTG and CHN analyses. The experiment was then followed by the formation study of iron-containing AIPO-5 crystals in the presence of phosphorous acid (H3P03) by using imidazolium-based SDA ([bdmim ]el) under ionothermal condition. The formation process of FeAPO-5 during the ionothermal synthesis was monitored by microscopic and spectroscopic methods. The roles of Fe3+ and H3POJ in the formation of the FeAPO-5 framework were investigated. Possible mechanism for the growth of FeAPO-5 crystals was proposed based on the experimental results. Universiti Sains Malaysia 2017 Monograph NonPeerReviewed Ng , Eng Poh (2017) Exploratory study of heterocyclic nitrogen-based ionic liquids as supramolecular structure-directing agents in zeolite synthesis. Technical Report. Universiti Sains Malaysia. |
| spellingShingle | QD1-999 Chemistry Ng , Eng Poh Exploratory study of heterocyclic nitrogen-based ionic liquids as supramolecular structure-directing agents in zeolite synthesis. |
| title | Exploratory study of heterocyclic nitrogen-based ionic liquids as supramolecular structure-directing agents in zeolite synthesis. |
| title_full | Exploratory study of heterocyclic nitrogen-based ionic liquids as supramolecular structure-directing agents in zeolite synthesis. |
| title_fullStr | Exploratory study of heterocyclic nitrogen-based ionic liquids as supramolecular structure-directing agents in zeolite synthesis. |
| title_full_unstemmed | Exploratory study of heterocyclic nitrogen-based ionic liquids as supramolecular structure-directing agents in zeolite synthesis. |
| title_short | Exploratory study of heterocyclic nitrogen-based ionic liquids as supramolecular structure-directing agents in zeolite synthesis. |
| title_sort | exploratory study of heterocyclic nitrogen based ionic liquids as supramolecular structure directing agents in zeolite synthesis |
| topic | QD1-999 Chemistry |
| work_keys_str_mv | AT ngengpoh exploratorystudyofheterocyclicnitrogenbasedionicliquidsassupramolecularstructuredirectingagentsinzeolitesynthesis |