Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2 N1,S)nickel(II)
In the asymmetric unit of the title complex, [Ni(C16H14N3OS)2], the nickel ion is tetracoordinated in a distorted square-planar geometry by two independent molecules of the ligand which act as mononegative bidentate N,S-donors and form two five-membered chelate rings. The ligands are in trans (E)...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016
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| Subjects: | |
| Online Access: | http://eprints.usm.my/36881/1/%28Crystal_structure_of_bis%29_pj2029.pdf |
| _version_ | 1825833555288129536 |
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| author | Kadir, Faraidoon Karim Shamsuddin, Mustaffa Rosli, Mohd Mustaqim |
| author_facet | Kadir, Faraidoon Karim Shamsuddin, Mustaffa Rosli, Mohd Mustaqim |
| author_sort | Kadir, Faraidoon Karim |
| collection | USM |
| description | In the asymmetric unit of the title complex, [Ni(C16H14N3OS)2], the nickel ion is
tetracoordinated in a distorted square-planar geometry by two independent
molecules of the ligand which act as mononegative bidentate N,S-donors and
form two five-membered chelate rings. The ligands are in trans (E)
conformations with respect to the C N bonds. The close approach of hydrogen
atoms to the Ni2+ atom suggests anagostic interactions (Ni� � �H—C) are present.
The crystal structure is built up by a network of two C—H� � �O interactions. One
of the interactions forms inversion dimers and the other links the molecules into
infinite chains parallel to [100]. In addition, a weak C—H� � �� interaction is also present. |
| first_indexed | 2024-03-06T15:09:35Z |
| format | Article |
| id | usm.eprints-36881 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:09:35Z |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | usm.eprints-368812017-10-02T09:21:36Z http://eprints.usm.my/36881/ Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2 N1,S)nickel(II) Kadir, Faraidoon Karim Shamsuddin, Mustaffa Rosli, Mohd Mustaqim QC1 Physics (General) In the asymmetric unit of the title complex, [Ni(C16H14N3OS)2], the nickel ion is tetracoordinated in a distorted square-planar geometry by two independent molecules of the ligand which act as mononegative bidentate N,S-donors and form two five-membered chelate rings. The ligands are in trans (E) conformations with respect to the C N bonds. The close approach of hydrogen atoms to the Ni2+ atom suggests anagostic interactions (Ni� � �H—C) are present. The crystal structure is built up by a network of two C—H� � �O interactions. One of the interactions forms inversion dimers and the other links the molecules into infinite chains parallel to [100]. In addition, a weak C—H� � �� interaction is also present. International Union of Crystallography 2016 Article PeerReviewed application/pdf en http://eprints.usm.my/36881/1/%28Crystal_structure_of_bis%29_pj2029.pdf Kadir, Faraidoon Karim and Shamsuddin, Mustaffa and Rosli, Mohd Mustaqim (2016) Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2 N1,S)nickel(II). Acta Crystallographica Section E: Crystallographic Communications, 2016 (72). pp. 760-763. ISSN 2056-9890 http://dx.doi.org/10.1107/S2056989016006873 |
| spellingShingle | QC1 Physics (General) Kadir, Faraidoon Karim Shamsuddin, Mustaffa Rosli, Mohd Mustaqim Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2 N1,S)nickel(II) |
| title | Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2 N1,S)nickel(II) |
| title_full | Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2 N1,S)nickel(II) |
| title_fullStr | Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2 N1,S)nickel(II) |
| title_full_unstemmed | Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2 N1,S)nickel(II) |
| title_short | Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2 N1,S)nickel(II) |
| title_sort | crystal structure of bis aceto phenone 4 benzoyl thio semicarbazonato κ2 n1 s nickel ii |
| topic | QC1 Physics (General) |
| url | http://eprints.usm.my/36881/1/%28Crystal_structure_of_bis%29_pj2029.pdf |
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