(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis

(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis

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In the title compound, C23H14ClFO, the enone moiety adopts an E conformation. The dihedral angle between the benzene and anthracene ring is 63.42 (8)° and an intra­molecular C—H⋯F hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are arranged into centrosymmetric dimers via pair...

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Main Authors: Abdullah, Amzar Ahlami, Hassan, Nur Hafiq Hanif, Arshad, Suhana, Che Khalib, Nuridayanti, Razak, Ibrahim Abdul
Format: Article
Language:English
Published: International Union of Crystallography 2016
Subjects:
QC1-999 Physics
Online Access:http://eprints.usm.my/36907/1/%28E-1-%28Anthracen-9-yl%29-3-%282-chloro-6-fluoro%C2%ADphen%C2%ADyl%29_hb7569.pdf
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author Abdullah, Amzar Ahlami
Hassan, Nur Hafiq Hanif
Arshad, Suhana
Che Khalib, Nuridayanti
Razak, Ibrahim Abdul
author_facet Abdullah, Amzar Ahlami
Hassan, Nur Hafiq Hanif
Arshad, Suhana
Che Khalib, Nuridayanti
Razak, Ibrahim Abdul
author_sort Abdullah, Amzar Ahlami
collection USM
description In the title compound, C23H14ClFO, the enone moiety adopts an E conformation. The dihedral angle between the benzene and anthracene ring is 63.42 (8)° and an intra­molecular C—H⋯F hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are arranged into centrosymmetric dimers via pairs of C—H⋯F hydrogen bonds. The crystal structure also features C—H⋯π and π–π inter­actions. Hirshfeld surface analysis was used to confirm the existence of inter­molecular inter­actions.
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spelling usm.eprints-369072018-08-15T04:19:01Z http://eprints.usm.my/36907/ (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis Abdullah, Amzar Ahlami Hassan, Nur Hafiq Hanif Arshad, Suhana Che Khalib, Nuridayanti Razak, Ibrahim Abdul QC1-999 Physics In the title compound, C23H14ClFO, the enone moiety adopts an E conformation. The dihedral angle between the benzene and anthracene ring is 63.42 (8)° and an intra­molecular C—H⋯F hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are arranged into centrosymmetric dimers via pairs of C—H⋯F hydrogen bonds. The crystal structure also features C—H⋯π and π–π inter­actions. Hirshfeld surface analysis was used to confirm the existence of inter­molecular inter­actions. International Union of Crystallography 2016-05 Article PeerReviewed application/pdf en http://eprints.usm.my/36907/1/%28E-1-%28Anthracen-9-yl%29-3-%282-chloro-6-fluoro%C2%ADphen%C2%ADyl%29_hb7569.pdf Abdullah, Amzar Ahlami and Hassan, Nur Hafiq Hanif and Arshad, Suhana and Che Khalib, Nuridayanti and Razak, Ibrahim Abdul (2016) (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E: Crystallographic Communications, 72 (5). pp. 648-651. ISSN 2056-9890 https://doi.org/10.1107/S2056989016005028
spellingShingle QC1-999 Physics
Abdullah, Amzar Ahlami
Hassan, Nur Hafiq Hanif
Arshad, Suhana
Che Khalib, Nuridayanti
Razak, Ibrahim Abdul
(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title_full (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title_fullStr (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title_full_unstemmed (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title_short (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title_sort e 1 anthracen 9 yl 3 2 chloro 6 fluorophenyl prop 2 en 1 one crystal structure and hirshfeld surface analysis
topic QC1-999 Physics
url http://eprints.usm.my/36907/1/%28E-1-%28Anthracen-9-yl%29-3-%282-chloro-6-fluoro%C2%ADphen%C2%ADyl%29_hb7569.pdf
work_keys_str_mv AT abdullahamzarahlami e1anthracen9yl32chloro6fluorophenylprop2en1onecrystalstructureandhirshfeldsurfaceanalysis
AT hassannurhafiqhanif e1anthracen9yl32chloro6fluorophenylprop2en1onecrystalstructureandhirshfeldsurfaceanalysis
AT arshadsuhana e1anthracen9yl32chloro6fluorophenylprop2en1onecrystalstructureandhirshfeldsurfaceanalysis
AT chekhalibnuridayanti e1anthracen9yl32chloro6fluorophenylprop2en1onecrystalstructureandhirshfeldsurfaceanalysis
AT razakibrahimabdul e1anthracen9yl32chloro6fluorophenylprop2en1onecrystalstructureandhirshfeldsurfaceanalysis

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