A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies.
Novel silver(I)- and Mercury(II)-N-Heterocyclic Carbene (NHC) Complexes of pincer ligands were successfully synthesized in good yields. The prepared complexes were then used for the transmetallation reactions to synthesize the required Nickel(II)- and Palladium(II)-NHC complexes. All the synthesiz...
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Format: | Monograph |
Language: | English |
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Universiti Sains Malaysia
2015
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Online Access: | http://eprints.usm.my/36945/1/216e%20A%20green%20approach%20towards%20synthesis%20and%20characterization%20of%20Ni%28II%29-%20and%20Pd%28II%29-N-%20heterocyclic%20carbene%20complexes%20of%20pincer%20ligands%20their%20application%20in%20catalytic%20olefin%20oxidation%20studies..pdf |
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author | S.M Anwarul Haque, Rosenani |
author_facet | S.M Anwarul Haque, Rosenani |
author_sort | S.M Anwarul Haque, Rosenani |
collection | USM |
description | Novel silver(I)- and Mercury(II)-N-Heterocyclic Carbene (NHC) Complexes of pincer ligands were successfully
synthesized in good yields. The prepared complexes were then used for the transmetallation reactions to
synthesize the required Nickel(II)- and Palladium(II)-NHC complexes. All the synthesized compounds were
characterized by various spectroscopic and analytical techniques. X-ray crystallographic technique was used to
determine the structural orientations of the molecules. The compounds were tested for possible biological and
catalytic behavior. Silver(l) and palladium(lI) complexes showed excellent antibacterial and anticancer results. |
first_indexed | 2024-03-06T15:09:45Z |
format | Monograph |
id | usm.eprints-36945 |
institution | Universiti Sains Malaysia |
language | English |
last_indexed | 2024-03-06T15:09:45Z |
publishDate | 2015 |
publisher | Universiti Sains Malaysia |
record_format | dspace |
spelling | usm.eprints-369452022-12-14T02:06:38Z http://eprints.usm.my/36945/ A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies. S.M Anwarul Haque, Rosenani QD1-999 Chemistry Novel silver(I)- and Mercury(II)-N-Heterocyclic Carbene (NHC) Complexes of pincer ligands were successfully synthesized in good yields. The prepared complexes were then used for the transmetallation reactions to synthesize the required Nickel(II)- and Palladium(II)-NHC complexes. All the synthesized compounds were characterized by various spectroscopic and analytical techniques. X-ray crystallographic technique was used to determine the structural orientations of the molecules. The compounds were tested for possible biological and catalytic behavior. Silver(l) and palladium(lI) complexes showed excellent antibacterial and anticancer results. Universiti Sains Malaysia 2015 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/36945/1/216e%20A%20green%20approach%20towards%20synthesis%20and%20characterization%20of%20Ni%28II%29-%20and%20Pd%28II%29-N-%20heterocyclic%20carbene%20complexes%20of%20pincer%20ligands%20their%20application%20in%20catalytic%20olefin%20oxidation%20studies..pdf S.M Anwarul Haque, Rosenani (2015) A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies. Technical Report. Universiti Sains Malaysia. |
spellingShingle | QD1-999 Chemistry S.M Anwarul Haque, Rosenani A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies. |
title | A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies. |
title_full | A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies. |
title_fullStr | A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies. |
title_full_unstemmed | A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies. |
title_short | A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies. |
title_sort | green approach towards synthesis and characterization of ni ii and pd ii n heterocyclic carbene complexes of pincer ligands their application in catalytic olefin oxidation studies |
topic | QD1-999 Chemistry |
url | http://eprints.usm.my/36945/1/216e%20A%20green%20approach%20towards%20synthesis%20and%20characterization%20of%20Ni%28II%29-%20and%20Pd%28II%29-N-%20heterocyclic%20carbene%20complexes%20of%20pincer%20ligands%20their%20application%20in%20catalytic%20olefin%20oxidation%20studies..pdf |
work_keys_str_mv | AT smanwarulhaquerosenani agreenapproachtowardssynthesisandcharacterizationofniiiandpdiinheterocycliccarbenecomplexesofpincerligandstheirapplicationincatalyticolefinoxidationstudies AT smanwarulhaquerosenani greenapproachtowardssynthesisandcharacterizationofniiiandpdiinheterocycliccarbenecomplexesofpincerligandstheirapplicationincatalyticolefinoxidationstudies |