1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]- 3-methylthiourea
In the title thiosemicarbazone Schiff base compound, C10H13N3O2S, the dihedral angle between the benzene ring and methyl carbothioamide side arm was found to be 17.4 (4)�. The presence of two intramolecular hydrogen bonds is noted, namely hydroxy-O—H� � �O(methoxy) and amine-N—H� � �N(imine). In...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016
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| Subjects: | |
| Online Access: | http://eprints.usm.my/37935/1/1-%5B%28E%29-%283-Hydroxy-4-methoxybenzylidene%29amino%5D-.pdf |
| _version_ | 1797009931980767232 |
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| author | Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. |
| author_facet | Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. |
| author_sort | Arafath, Md. Azharul |
| collection | USM |
| description | In the title thiosemicarbazone Schiff base compound, C10H13N3O2S, the dihedral
angle between the benzene ring and methyl carbothioamide side arm was found
to be 17.4 (4)�. The presence of two intramolecular hydrogen bonds is noted,
namely hydroxy-O—H� � �O(methoxy) and amine-N—H� � �N(imine). In the
crystal, pairwise amine-N—H� � �S hydrogen bonds give rise to centrosymmetric
{� � �HNCS}2 synthons, which lead to dimeric aggregates. |
| first_indexed | 2024-03-06T15:12:33Z |
| format | Article |
| id | usm.eprints-37935 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:12:33Z |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | usm.eprints-379352017-12-15T03:58:33Z http://eprints.usm.my/37935/ 1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]- 3-methylthiourea Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. QD1-999 Chemistry In the title thiosemicarbazone Schiff base compound, C10H13N3O2S, the dihedral angle between the benzene ring and methyl carbothioamide side arm was found to be 17.4 (4)�. The presence of two intramolecular hydrogen bonds is noted, namely hydroxy-O—H� � �O(methoxy) and amine-N—H� � �N(imine). In the crystal, pairwise amine-N—H� � �S hydrogen bonds give rise to centrosymmetric {� � �HNCS}2 synthons, which lead to dimeric aggregates. International Union of Crystallography 2016 Article PeerReviewed application/pdf en http://eprints.usm.my/37935/1/1-%5B%28E%29-%283-Hydroxy-4-methoxybenzylidene%29amino%5D-.pdf Arafath, Md. Azharul and Adam, Farook and Razali, Mohd. R. (2016) 1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]- 3-methylthiourea. IUCrData, 2016 (1). pp. 1-6. ISSN 2414-3146 http://dx.doi.org/10.1107/S2414314616015996 |
| spellingShingle | QD1-999 Chemistry Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. 1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]- 3-methylthiourea |
| title | 1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]-
3-methylthiourea |
| title_full | 1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]-
3-methylthiourea |
| title_fullStr | 1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]-
3-methylthiourea |
| title_full_unstemmed | 1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]-
3-methylthiourea |
| title_short | 1-[(E)-(3-Hydroxy-4-methoxybenzylidene)amino]-
3-methylthiourea |
| title_sort | 1 e 3 hydroxy 4 methoxybenzylidene amino 3 methylthiourea |
| topic | QD1-999 Chemistry |
| url | http://eprints.usm.my/37935/1/1-%5B%28E%29-%283-Hydroxy-4-methoxybenzylidene%29amino%5D-.pdf |
| work_keys_str_mv | AT arafathmdazharul 1e3hydroxy4methoxybenzylideneamino3methylthiourea AT adamfarook 1e3hydroxy4methoxybenzylideneamino3methylthiourea AT razalimohdr 1e3hydroxy4methoxybenzylideneamino3methylthiourea |