2-Amino-5-bromopyridinium 2-phenoxyacetate
The phenoxyacetate anion of the title salt, C5H6BrN2 +C8H7O3 , is essentially planar, with a dihedral angle of 7.6 (5)� between the carboxylate group and the benzene ring. In the crystal, the cation and the anion are linked via N—HO hydrogen bonds, forming a helical chain along a 21 screw axis. In...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016
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| Online Access: | http://eprints.usm.my/37954/1/2-Amino-5-bromopyridinium_2-phenoxyacetate.pdf |
| _version_ | 1825833759543394304 |
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| author | Dhanabalan, Nallathambi Thanigaimani, Kaliyaperumal Che Khalib, Nuridayanti Santhanaraj, K. Joseph Razak, Ibrahim Abdul |
| author_facet | Dhanabalan, Nallathambi Thanigaimani, Kaliyaperumal Che Khalib, Nuridayanti Santhanaraj, K. Joseph Razak, Ibrahim Abdul |
| author_sort | Dhanabalan, Nallathambi |
| collection | USM |
| description | The phenoxyacetate anion of the title salt, C5H6BrN2
+C8H7O3 , is essentially planar, with a dihedral angle of 7.6 (5)� between the carboxylate group and the benzene ring. In the crystal, the cation and the anion are linked via N—HO hydrogen bonds, forming a helical chain along a 21 screw axis. In the chain, a – stacking interaction between the pyridinium and benzene rings, with a centroid– centroid distance of 3.854 (2) A˚ , and a C—HO interaction are observed. The chains are further linked through another C—HO hydrogen bond, forming a three-dimensional network. |
| first_indexed | 2024-03-06T15:12:36Z |
| format | Article |
| id | usm.eprints-37954 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:12:36Z |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | usm.eprints-379542018-08-15T04:22:47Z http://eprints.usm.my/37954/ 2-Amino-5-bromopyridinium 2-phenoxyacetate Dhanabalan, Nallathambi Thanigaimani, Kaliyaperumal Che Khalib, Nuridayanti Santhanaraj, K. Joseph Razak, Ibrahim Abdul QC1-999 Physics The phenoxyacetate anion of the title salt, C5H6BrN2 +C8H7O3 , is essentially planar, with a dihedral angle of 7.6 (5)� between the carboxylate group and the benzene ring. In the crystal, the cation and the anion are linked via N—HO hydrogen bonds, forming a helical chain along a 21 screw axis. In the chain, a – stacking interaction between the pyridinium and benzene rings, with a centroid– centroid distance of 3.854 (2) A˚ , and a C—HO interaction are observed. The chains are further linked through another C—HO hydrogen bond, forming a three-dimensional network. International Union of Crystallography 2016 Article PeerReviewed application/pdf en http://eprints.usm.my/37954/1/2-Amino-5-bromopyridinium_2-phenoxyacetate.pdf Dhanabalan, Nallathambi and Thanigaimani, Kaliyaperumal and Che Khalib, Nuridayanti and Santhanaraj, K. Joseph and Razak, Ibrahim Abdul (2016) 2-Amino-5-bromopyridinium 2-phenoxyacetate. IUCrData, 2016 (1). pp. 1-7. ISSN 2414-3146 https://doi.org/10.1107/S2414314616019398 |
| spellingShingle | QC1-999 Physics Dhanabalan, Nallathambi Thanigaimani, Kaliyaperumal Che Khalib, Nuridayanti Santhanaraj, K. Joseph Razak, Ibrahim Abdul 2-Amino-5-bromopyridinium 2-phenoxyacetate |
| title | 2-Amino-5-bromopyridinium 2-phenoxyacetate |
| title_full | 2-Amino-5-bromopyridinium 2-phenoxyacetate |
| title_fullStr | 2-Amino-5-bromopyridinium 2-phenoxyacetate |
| title_full_unstemmed | 2-Amino-5-bromopyridinium 2-phenoxyacetate |
| title_short | 2-Amino-5-bromopyridinium 2-phenoxyacetate |
| title_sort | 2 amino 5 bromopyridinium 2 phenoxyacetate |
| topic | QC1-999 Physics |
| url | http://eprints.usm.my/37954/1/2-Amino-5-bromopyridinium_2-phenoxyacetate.pdf |
| work_keys_str_mv | AT dhanabalannallathambi 2amino5bromopyridinium2phenoxyacetate AT thanigaimanikaliyaperumal 2amino5bromopyridinium2phenoxyacetate AT chekhalibnuridayanti 2amino5bromopyridinium2phenoxyacetate AT santhanarajkjoseph 2amino5bromopyridinium2phenoxyacetate AT razakibrahimabdul 2amino5bromopyridinium2phenoxyacetate |