6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid
The asymmetric unit of the title compound, C17H18O3, comprises three independent molecules with similar geometries. In each molecule, the carbonyl group is twisted away from the napthalene ring system, making dihedral angles of 1.0 (2), 1.05 (19)° and 1.5 (2)°. The butene group in all three molecul...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014
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| Subjects: | |
| Online Access: | http://eprints.usm.my/37967/1/6-%28Hex-5-enyloxy%29naphthalene-2-carboxylic.pdf |
| _version_ | 1797009937915707392 |
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| author | Rahman, Md. Lutfor Srinivasa, H. T. Mohd. Yusoff, Mashitah Huey, Chong Kwong Ching, Kheng Quah |
| author_facet | Rahman, Md. Lutfor Srinivasa, H. T. Mohd. Yusoff, Mashitah Huey, Chong Kwong Ching, Kheng Quah |
| author_sort | Rahman, Md. Lutfor |
| collection | USM |
| description | The asymmetric unit of the title compound, C17H18O3,
comprises three independent molecules with similar geometries. In each molecule, the carbonyl group is twisted away from the napthalene ring system, making dihedral angles of 1.0 (2), 1.05 (19)° and 1.5 (2)°. The butene group in all three molecules are disordered over two sets of sites, with a refined occupancy ratio of 0.664 (6):0.336 (6). In the crystal, molecules are oriented with respect to their carbonyl groups, forming head-to-head dimers via O—H...O hydrogen bonds. Adjacent dimers are further interconnected by C—H...O hydrogen bonds into chains along the a-axis direction. The crystal structure is further stabilized by weak C—H...n interactions. |
| first_indexed | 2024-03-06T15:12:38Z |
| format | Article |
| id | usm.eprints-37967 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:12:38Z |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | usm.eprints-379672017-12-19T05:00:30Z http://eprints.usm.my/37967/ 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid Rahman, Md. Lutfor Srinivasa, H. T. Mohd. Yusoff, Mashitah Huey, Chong Kwong Ching, Kheng Quah QC1-999 Physics QD1-999 Chemistry The asymmetric unit of the title compound, C17H18O3, comprises three independent molecules with similar geometries. In each molecule, the carbonyl group is twisted away from the napthalene ring system, making dihedral angles of 1.0 (2), 1.05 (19)° and 1.5 (2)°. The butene group in all three molecules are disordered over two sets of sites, with a refined occupancy ratio of 0.664 (6):0.336 (6). In the crystal, molecules are oriented with respect to their carbonyl groups, forming head-to-head dimers via O—H...O hydrogen bonds. Adjacent dimers are further interconnected by C—H...O hydrogen bonds into chains along the a-axis direction. The crystal structure is further stabilized by weak C—H...n interactions. International Union of Crystallography 2014 Article PeerReviewed application/pdf en http://eprints.usm.my/37967/1/6-%28Hex-5-enyloxy%29naphthalene-2-carboxylic.pdf Rahman, Md. Lutfor and Srinivasa, H. T. and Mohd. Yusoff, Mashitah and Huey, Chong Kwong and Ching, Kheng Quah (2014) 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid. Acta Crystallographica Section E, 2014 (70). 0696-0711. ISSN 1600-5368 https://doi.org/10.1107/S1600536814010642 |
| spellingShingle | QC1-999 Physics QD1-999 Chemistry Rahman, Md. Lutfor Srinivasa, H. T. Mohd. Yusoff, Mashitah Huey, Chong Kwong Ching, Kheng Quah 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title_full | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title_fullStr | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title_full_unstemmed | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title_short | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
| title_sort | 6 hex 5 enyloxy naphthalene 2 carboxylic acid |
| topic | QC1-999 Physics QD1-999 Chemistry |
| url | http://eprints.usm.my/37967/1/6-%28Hex-5-enyloxy%29naphthalene-2-carboxylic.pdf |
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