A Heterobimetallic 2-D Coordination Polymer [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO
A heterobimetallic 2-D coordination polymer, [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (1) (2pyCOO=picolinate) was synthesized and characterized. The complex was also structurally characterized using single X-ray diffraction studies that revealed the complex 1 having a vertex symbol of 4.82 which corresponds to...
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| Format: | Article |
| Language: | English |
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MDPI
2016
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| Online Access: | http://eprints.usm.my/38027/1/A_Heterobimetallic_2-D_Coordination_Polymer_%5BNa2%28Cu2I2%282pyCOO%294%29.pdf |
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| author | Kamari, Anis A. Haque, Rosenani A. Razali, Mohd Rizal |
| author_facet | Kamari, Anis A. Haque, Rosenani A. Razali, Mohd Rizal |
| author_sort | Kamari, Anis A. |
| collection | USM |
| description | A heterobimetallic 2-D coordination polymer, [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (1) (2pyCOO=picolinate) was synthesized and characterized. The complex was also structurally characterized using single X-ray diffraction studies that revealed the complex 1 having a vertex symbol of 4.82 which corresponds to fes topology. Together with hydrogen bonds and interdigitating n...n interactions, these thus facilitate the formation of 3-D supramolecular network. The nitrogen gas absorption amount of 1 at 77 K shows a small volume of N2 sorption isotherm with a small Langmuir and a Brunauer-Emmett-Teller (BET) surface area indicating that the heterobimetallic 3-D supramolecular of 1 exhibits a very weak ability of adsorbing gas. |
| first_indexed | 2024-03-06T15:12:48Z |
| format | Article |
| id | usm.eprints-38027 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:12:48Z |
| publishDate | 2016 |
| publisher | MDPI |
| record_format | dspace |
| spelling | usm.eprints-380272017-12-20T07:15:11Z http://eprints.usm.my/38027/ A Heterobimetallic 2-D Coordination Polymer [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO Kamari, Anis A. Haque, Rosenani A. Razali, Mohd Rizal QD1-999 Chemistry A heterobimetallic 2-D coordination polymer, [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (1) (2pyCOO=picolinate) was synthesized and characterized. The complex was also structurally characterized using single X-ray diffraction studies that revealed the complex 1 having a vertex symbol of 4.82 which corresponds to fes topology. Together with hydrogen bonds and interdigitating n...n interactions, these thus facilitate the formation of 3-D supramolecular network. The nitrogen gas absorption amount of 1 at 77 K shows a small volume of N2 sorption isotherm with a small Langmuir and a Brunauer-Emmett-Teller (BET) surface area indicating that the heterobimetallic 3-D supramolecular of 1 exhibits a very weak ability of adsorbing gas. MDPI 2016 Article PeerReviewed application/pdf en http://eprints.usm.my/38027/1/A_Heterobimetallic_2-D_Coordination_Polymer_%5BNa2%28Cu2I2%282pyCOO%294%29.pdf Kamari, Anis A. and Haque, Rosenani A. and Razali, Mohd Rizal (2016) A Heterobimetallic 2-D Coordination Polymer [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO. Crystals, 6 (10). pp. 1-7. ISSN 2073-4352 http://www.mdpi.com/2073-4352/6/10/96 |
| spellingShingle | QD1-999 Chemistry Kamari, Anis A. Haque, Rosenani A. Razali, Mohd Rizal A Heterobimetallic 2-D Coordination Polymer [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO |
| title | A Heterobimetallic 2-D Coordination Polymer
[Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO |
| title_full | A Heterobimetallic 2-D Coordination Polymer
[Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO |
| title_fullStr | A Heterobimetallic 2-D Coordination Polymer
[Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO |
| title_full_unstemmed | A Heterobimetallic 2-D Coordination Polymer
[Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO |
| title_short | A Heterobimetallic 2-D Coordination Polymer
[Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO |
| title_sort | heterobimetallic 2 d coordination polymer na2 cu2i2 2pycoo 4 h2o 4 n 2pycoo |
| topic | QD1-999 Chemistry |
| url | http://eprints.usm.my/38027/1/A_Heterobimetallic_2-D_Coordination_Polymer_%5BNa2%28Cu2I2%282pyCOO%294%29.pdf |
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