(Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl- 1j3C,2j3C,3j3C-triangulotriruthenium(0)
The asymmetric unit of the title compound, [Ru3(C19H17P)(C25H22P2)(CO)9], consists of two independent molecules. The bis(diphenylphosphanyl)methane ligand bridges an Ru—Ru bond and the benzyldiphenylphosphane ligand binds to the third Ru atom. The Ru—Ru bond cis to the benzyldiphenylphosphane l...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014
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| Subjects: | |
| Online Access: | http://eprints.usm.my/38389/1/Benzyldiphenylphosphane-1kP%29-.pdf |
| _version_ | 1797010022645891072 |
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| author | Shawkataly, Omar Ahmed Khan, Imthyaz Sirat, Siti Syaida Rosli, Mohd Mustaqim |
| author_facet | Shawkataly, Omar Ahmed Khan, Imthyaz Sirat, Siti Syaida Rosli, Mohd Mustaqim |
| author_sort | Shawkataly, Omar |
| collection | USM |
| description | The asymmetric unit of the title compound,
[Ru3(C19H17P)(C25H22P2)(CO)9], consists of two independent
molecules. The bis(diphenylphosphanyl)methane ligand
bridges an Ru—Ru bond and the benzyldiphenylphosphane
ligand binds to the third Ru atom. The Ru—Ru bond cis to the
benzyldiphenylphosphane ligand is the longest of the three
Ru—Ru bonds in both molecules. In the crystal, molecules are
linked by C—H� � �O hydrogen bonds, forming layers parallel
to the ac plane. C—H� � �� contacts further stabilize the crystal
packing. |
| first_indexed | 2024-03-06T15:13:52Z |
| format | Article |
| id | usm.eprints-38389 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:13:52Z |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | usm.eprints-383892018-01-16T07:23:43Z http://eprints.usm.my/38389/ (Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl- 1j3C,2j3C,3j3C-triangulotriruthenium(0) Shawkataly, Omar Ahmed Khan, Imthyaz Sirat, Siti Syaida Rosli, Mohd Mustaqim LC5800-5808 Distance education. QC1-999 Physics The asymmetric unit of the title compound, [Ru3(C19H17P)(C25H22P2)(CO)9], consists of two independent molecules. The bis(diphenylphosphanyl)methane ligand bridges an Ru—Ru bond and the benzyldiphenylphosphane ligand binds to the third Ru atom. The Ru—Ru bond cis to the benzyldiphenylphosphane ligand is the longest of the three Ru—Ru bonds in both molecules. In the crystal, molecules are linked by C—H� � �O hydrogen bonds, forming layers parallel to the ac plane. C—H� � �� contacts further stabilize the crystal packing. International Union of Crystallography 2014 Article PeerReviewed application/pdf en http://eprints.usm.my/38389/1/Benzyldiphenylphosphane-1kP%29-.pdf Shawkataly, Omar and Ahmed Khan, Imthyaz and Sirat, Siti Syaida and Rosli, Mohd Mustaqim (2014) (Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl- 1j3C,2j3C,3j3C-triangulotriruthenium(0). Acta Crystallographica Section E, 2014 (70). pp. 293-294. ISSN 1600-5368 https://doi.org/10.1107/S1600536814015475 |
| spellingShingle | LC5800-5808 Distance education. QC1-999 Physics Shawkataly, Omar Ahmed Khan, Imthyaz Sirat, Siti Syaida Rosli, Mohd Mustaqim (Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl- 1j3C,2j3C,3j3C-triangulotriruthenium(0) |
| title | (Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl-
1j3C,2j3C,3j3C-triangulotriruthenium(0) |
| title_full | (Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl-
1j3C,2j3C,3j3C-triangulotriruthenium(0) |
| title_fullStr | (Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl-
1j3C,2j3C,3j3C-triangulotriruthenium(0) |
| title_full_unstemmed | (Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl-
1j3C,2j3C,3j3C-triangulotriruthenium(0) |
| title_short | (Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl-
1j3C,2j3C,3j3C-triangulotriruthenium(0) |
| title_sort | benzyldiphenylphosphane 1jp l bis diphenylphosphanyl methane 2 3j2p p0 nonacarbonyl 1j3c 2j3c 3j3c triangulotriruthenium 0 |
| topic | LC5800-5808 Distance education. QC1-999 Physics |
| url | http://eprints.usm.my/38389/1/Benzyldiphenylphosphane-1kP%29-.pdf |
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