Crystal structure of 2-aminopyridinium 6-chloronicotinate
In the title salt, C5H7N+�C6H3ClNO�, the 2-aminopyridinium cation interacts with the carboxylate group of the 6-chloronicotinate anion through a pair of independent N—H� � �O hydrogen bonds, forming an R2 2(8) ring motif. In the crystal, these dimeric units are connected further via N—H� � �O...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2015
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| Subjects: | |
| Online Access: | http://eprints.usm.my/38569/1/Crystal_structure_of_2-aminopyridinium.pdf |
| _version_ | 1825833879803527168 |
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| author | Jeeva Jasmine, N. Rajam, A. Thomas Muthiah, P. Stanley, N. Abdul Razak, I. Mustaqim Rosli, M. |
| author_facet | Jeeva Jasmine, N. Rajam, A. Thomas Muthiah, P. Stanley, N. Abdul Razak, I. Mustaqim Rosli, M. |
| author_sort | Jeeva Jasmine, N. |
| collection | USM |
| description | In the title salt, C5H7N+�C6H3ClNO�, the 2-aminopyridinium
cation interacts with the carboxylate group of the 6-chloronicotinate
anion through a pair of independent N—H� � �O
hydrogen bonds, forming an R2
2(8) ring motif. In the crystal,
these dimeric units are connected further via N—H� � �O
hydrogen bonds, forming chains along [001]. In addition, weak
C—H� � �N and C—H� � �O hydrogen bonds, together with
weak �–� interactions, with centroid–centroid distances of
3.6560 (5) and 3.6295 (5) A ° , connect the chains, forming a twodimensional
network parallel to (100). |
| first_indexed | 2024-03-06T15:14:24Z |
| format | Article |
| id | usm.eprints-38569 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:14:24Z |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | usm.eprints-385692018-01-26T02:12:01Z http://eprints.usm.my/38569/ Crystal structure of 2-aminopyridinium 6-chloronicotinate Jeeva Jasmine, N. Rajam, A. Thomas Muthiah, P. Stanley, N. Abdul Razak, I. Mustaqim Rosli, M. QC1-999 Physics In the title salt, C5H7N+�C6H3ClNO�, the 2-aminopyridinium cation interacts with the carboxylate group of the 6-chloronicotinate anion through a pair of independent N—H� � �O hydrogen bonds, forming an R2 2(8) ring motif. In the crystal, these dimeric units are connected further via N—H� � �O hydrogen bonds, forming chains along [001]. In addition, weak C—H� � �N and C—H� � �O hydrogen bonds, together with weak �–� interactions, with centroid–centroid distances of 3.6560 (5) and 3.6295 (5) A ° , connect the chains, forming a twodimensional network parallel to (100). International Union of Crystallography 2015 Article PeerReviewed application/pdf en http://eprints.usm.my/38569/1/Crystal_structure_of_2-aminopyridinium.pdf Jeeva Jasmine, N. and Rajam, A. and Thomas Muthiah, P. and Stanley, N. and Abdul Razak, I. and Mustaqim Rosli, M. (2015) Crystal structure of 2-aminopyridinium 6-chloronicotinate. Acta Crystallographica Section E: Crystallographic Communications, 71. 0655-0656. ISSN 2056-9890 https://doi.org/10.1107/S2056989015014796 |
| spellingShingle | QC1-999 Physics Jeeva Jasmine, N. Rajam, A. Thomas Muthiah, P. Stanley, N. Abdul Razak, I. Mustaqim Rosli, M. Crystal structure of 2-aminopyridinium 6-chloronicotinate |
| title | Crystal structure of 2-aminopyridinium 6-chloronicotinate |
| title_full | Crystal structure of 2-aminopyridinium 6-chloronicotinate |
| title_fullStr | Crystal structure of 2-aminopyridinium 6-chloronicotinate |
| title_full_unstemmed | Crystal structure of 2-aminopyridinium 6-chloronicotinate |
| title_short | Crystal structure of 2-aminopyridinium 6-chloronicotinate |
| title_sort | crystal structure of 2 aminopyridinium 6 chloronicotinate |
| topic | QC1-999 Physics |
| url | http://eprints.usm.my/38569/1/Crystal_structure_of_2-aminopyridinium.pdf |
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