(E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine
The molecule of the title hydrazine derivative, C15H14N4O6, is essentially planar, the dihedral angle between the substituted benzene rings being 2.25 (9)�. The ethoxy and hydroxy groups are almost coplanar with their bound benzene ring [r.m.s. deviation = 0.0153 (2) A ° for the ten non-H atoms]...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2014
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| Subjects: | |
| Online Access: | http://eprints.usm.my/38781/1/E%29-1-%282%2C4-Dinitrophenyl%29-2-%283-ethoxy-4-.pdf |
| _version_ | 1797010101293285376 |
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| author | Fun, Hoong Kun Chantrapromma, Suchada Ruanwas, S Pumsak Kobkeatthawin, Thawanrat Chidan Kumar, C. S. |
| author_facet | Fun, Hoong Kun Chantrapromma, Suchada Ruanwas, S Pumsak Kobkeatthawin, Thawanrat Chidan Kumar, C. S. |
| author_sort | Fun, Hoong Kun |
| collection | USM |
| description | The molecule of the title hydrazine derivative, C15H14N4O6, is
essentially planar, the dihedral angle between the substituted
benzene rings being 2.25 (9)�. The ethoxy and hydroxy groups
are almost coplanar with their bound benzene ring [r.m.s.
deviation = 0.0153 (2) A ° for the ten non-H atoms]. Intramolecular
N—H� � �O and O—H� � �Oethoxy hydrogen bonds
generate S(6) and S(5) ring motifs, respectively. In the crystal,
molecules are linked by O—H� � �Onitro hydrogen bonds into
chains propagating in [010]. Weak aromatic �–� interactions,
with centroid–centroid distances of 3.8192 (19) and
4.0491 (19) A ° , are also observed. |
| first_indexed | 2024-03-06T15:15:01Z |
| format | Article |
| id | usm.eprints-38781 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:15:01Z |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | usm.eprints-387812018-02-12T06:55:29Z http://eprints.usm.my/38781/ (E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine Fun, Hoong Kun Chantrapromma, Suchada Ruanwas, S Pumsak Kobkeatthawin, Thawanrat Chidan Kumar, C. S. QC1-999 Physics The molecule of the title hydrazine derivative, C15H14N4O6, is essentially planar, the dihedral angle between the substituted benzene rings being 2.25 (9)�. The ethoxy and hydroxy groups are almost coplanar with their bound benzene ring [r.m.s. deviation = 0.0153 (2) A ° for the ten non-H atoms]. Intramolecular N—H� � �O and O—H� � �Oethoxy hydrogen bonds generate S(6) and S(5) ring motifs, respectively. In the crystal, molecules are linked by O—H� � �Onitro hydrogen bonds into chains propagating in [010]. Weak aromatic �–� interactions, with centroid–centroid distances of 3.8192 (19) and 4.0491 (19) A ° , are also observed. International Union of Crystallography 2014 Article PeerReviewed application/pdf en http://eprints.usm.my/38781/1/E%29-1-%282%2C4-Dinitrophenyl%29-2-%283-ethoxy-4-.pdf Fun, Hoong Kun and Chantrapromma, Suchada and Ruanwas, S Pumsak and Kobkeatthawin, Thawanrat and Chidan Kumar, C. S. (2014) (E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine. Acta Crystallographica Section E: Structure Reports Online, 70 (1). 089-090. ISSN 1600-5368 https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914112/ |
| spellingShingle | QC1-999 Physics Fun, Hoong Kun Chantrapromma, Suchada Ruanwas, S Pumsak Kobkeatthawin, Thawanrat Chidan Kumar, C. S. (E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine |
| title | (E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine |
| title_full | (E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine |
| title_fullStr | (E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine |
| title_full_unstemmed | (E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine |
| title_short | (E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine |
| title_sort | e 1 2 4 dinitrophenyl 2 3 ethoxy 4 hydroxybenzylidene hydrazine |
| topic | QC1-999 Physics |
| url | http://eprints.usm.my/38781/1/E%29-1-%282%2C4-Dinitrophenyl%29-2-%283-ethoxy-4-.pdf |
| work_keys_str_mv | AT funhoongkun e124dinitrophenyl23ethoxy4hydroxybenzylidenehydrazine AT chantraprommasuchada e124dinitrophenyl23ethoxy4hydroxybenzylidenehydrazine AT ruanwasspumsak e124dinitrophenyl23ethoxy4hydroxybenzylidenehydrazine AT kobkeatthawinthawanrat e124dinitrophenyl23ethoxy4hydroxybenzylidenehydrazine AT chidankumarcs e124dinitrophenyl23ethoxy4hydroxybenzylidenehydrazine |