(E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine- 1-carbothioamide
In the title compound, C14H18ClN3OS, the phenol ring is almost coplanar with the hydrazinecarbothioamide moiety, making a dihedral angle of 6.92 (8)�. The cyclohexane ring has a chair conformation and the conformation about the C N bond is E. In the crystal, molecules are linked by N—H� � �O and...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2017
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| Subjects: | |
| Online Access: | http://eprints.usm.my/38793/1/E%29-2-%285-Chloro-2-hydroxybenzylidene%29-N-cyclohexylhydrazine-1-carbothioamide.pdf |
| _version_ | 1825833924830429184 |
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| author | Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. |
| author_facet | Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. |
| author_sort | Arafath, Md. Azharul |
| collection | USM |
| description | In the title compound, C14H18ClN3OS, the phenol ring is almost coplanar with
the hydrazinecarbothioamide moiety, making a dihedral angle of 6.92 (8)�. The
cyclohexane ring has a chair conformation and the conformation about the
C N bond is E. In the crystal, molecules are linked by N—H� � �O and O—
H� � �S hydrogen bonds, forming inversion dimers with an R2
2(14) ring motif
flanked by two R2
2(6) ring motifs. The dimers are linked by short Cl� � �Cl
interactions, forming layers parallel to the ab plane. |
| first_indexed | 2024-03-06T15:15:03Z |
| format | Article |
| id | usm.eprints-38793 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:15:03Z |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | usm.eprints-387932018-02-12T07:48:20Z http://eprints.usm.my/38793/ (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine- 1-carbothioamide Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. QD1-999 Chemistry In the title compound, C14H18ClN3OS, the phenol ring is almost coplanar with the hydrazinecarbothioamide moiety, making a dihedral angle of 6.92 (8)�. The cyclohexane ring has a chair conformation and the conformation about the C N bond is E. In the crystal, molecules are linked by N—H� � �O and O— H� � �S hydrogen bonds, forming inversion dimers with an R2 2(14) ring motif flanked by two R2 2(6) ring motifs. The dimers are linked by short Cl� � �Cl interactions, forming layers parallel to the ab plane. International Union of Crystallography 2017-01 Article PeerReviewed application/pdf en http://eprints.usm.my/38793/1/E%29-2-%285-Chloro-2-hydroxybenzylidene%29-N-cyclohexylhydrazine-1-carbothioamide.pdf Arafath, Md. Azharul and Adam, Farook and Razali, Mohd. R. (2017) (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine- 1-carbothioamide. IUCrData , 2 (1). pp. 1-3. ISSN 2414-3146 https://doi.org/10.1107/S2414314616019970 |
| spellingShingle | QD1-999 Chemistry Arafath, Md. Azharul Adam, Farook Razali, Mohd. R. (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine- 1-carbothioamide |
| title | (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-
1-carbothioamide |
| title_full | (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-
1-carbothioamide |
| title_fullStr | (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-
1-carbothioamide |
| title_full_unstemmed | (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-
1-carbothioamide |
| title_short | (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-
1-carbothioamide |
| title_sort | e 2 5 chloro 2 hydroxybenzylidene n cyclohexylhydrazine 1 carbothioamide |
| topic | QD1-999 Chemistry |
| url | http://eprints.usm.my/38793/1/E%29-2-%285-Chloro-2-hydroxybenzylidene%29-N-cyclohexylhydrazine-1-carbothioamide.pdf |
| work_keys_str_mv | AT arafathmdazharul e25chloro2hydroxybenzylidenencyclohexylhydrazine1carbothioamide AT adamfarook e25chloro2hydroxybenzylidenencyclohexylhydrazine1carbothioamide AT razalimohdr e25chloro2hydroxybenzylidenencyclohexylhydrazine1carbothioamide |