(E)-4-Methoxy-N00-(2,4,5-trimethoxybenzylidene) benzohydrazide hemihydrate
The title compound crystallizes as a hemihydrate, C18H20N2O5�0.5H2O. The molecule exists in an E conformation with respect to the C N imine bond. The 4-methoxyphenyl unit is disordered over two sets of sites with a refined occupancy ratio of 0.54 (2):0.46 (2). The dihedral angles between the be...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2014
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| Subjects: | |
| Online Access: | http://eprints.usm.my/38796/1/E%29-4-Methoxy-N%27-%282%2C4%2C5-trimethoxybenzylidene%29benzohydrazide.pdf |
| _version_ | 1797010104332058624 |
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| author | Chantrapromma, Suchada Boonnak, Nawong Horkaew, Jirapa Ching, Kheng Quah Fun, Hoong Kun |
| author_facet | Chantrapromma, Suchada Boonnak, Nawong Horkaew, Jirapa Ching, Kheng Quah Fun, Hoong Kun |
| author_sort | Chantrapromma, Suchada |
| collection | USM |
| description | The title compound crystallizes as a hemihydrate,
C18H20N2O5�0.5H2O. The molecule exists in an E conformation
with respect to the C N imine bond. The 4-methoxyphenyl
unit is disordered over two sets of sites with a refined
occupancy ratio of 0.54 (2):0.46 (2). The dihedral angles
between the benzene rings are 29.20 (9) and 26.59 (9)�,
respectively, for the major and minor components of the 4-
methoxy-substituted ring. All methoxy substituents lie close to
the plane of the attached benzene rings [the Cmethyl—O—C—
C torsion angles range from �4.0 (12) to 3.9 (2)�]. In the
crystal, the components are linked into chains propagating
along [001] via N—H� � �O and O—H� � �O hydrogen bonds and
weak C—H� � �O interactions. |
| first_indexed | 2024-03-06T15:15:03Z |
| format | Article |
| id | usm.eprints-38796 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:15:03Z |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | usm.eprints-387962018-02-12T08:49:00Z http://eprints.usm.my/38796/ (E)-4-Methoxy-N00-(2,4,5-trimethoxybenzylidene) benzohydrazide hemihydrate Chantrapromma, Suchada Boonnak, Nawong Horkaew, Jirapa Ching, Kheng Quah Fun, Hoong Kun QC1-999 Physics The title compound crystallizes as a hemihydrate, C18H20N2O5�0.5H2O. The molecule exists in an E conformation with respect to the C N imine bond. The 4-methoxyphenyl unit is disordered over two sets of sites with a refined occupancy ratio of 0.54 (2):0.46 (2). The dihedral angles between the benzene rings are 29.20 (9) and 26.59 (9)�, respectively, for the major and minor components of the 4- methoxy-substituted ring. All methoxy substituents lie close to the plane of the attached benzene rings [the Cmethyl—O—C— C torsion angles range from �4.0 (12) to 3.9 (2)�]. In the crystal, the components are linked into chains propagating along [001] via N—H� � �O and O—H� � �O hydrogen bonds and weak C—H� � �O interactions. International Union of Crystallography 2014-02 Article PeerReviewed application/pdf en http://eprints.usm.my/38796/1/E%29-4-Methoxy-N%27-%282%2C4%2C5-trimethoxybenzylidene%29benzohydrazide.pdf Chantrapromma, Suchada and Boonnak, Nawong and Horkaew, Jirapa and Ching, Kheng Quah and Fun, Hoong Kun (2014) (E)-4-Methoxy-N00-(2,4,5-trimethoxybenzylidene) benzohydrazide hemihydrate. Acta Crystallographica Section E: Structure Reports Online, 70 (2). 0150-0151. ISSN 1600-5368 https://doi.org/10.1107/S1600536814000531 |
| spellingShingle | QC1-999 Physics Chantrapromma, Suchada Boonnak, Nawong Horkaew, Jirapa Ching, Kheng Quah Fun, Hoong Kun (E)-4-Methoxy-N00-(2,4,5-trimethoxybenzylidene) benzohydrazide hemihydrate |
| title | (E)-4-Methoxy-N00-(2,4,5-trimethoxybenzylidene)
benzohydrazide hemihydrate |
| title_full | (E)-4-Methoxy-N00-(2,4,5-trimethoxybenzylidene)
benzohydrazide hemihydrate |
| title_fullStr | (E)-4-Methoxy-N00-(2,4,5-trimethoxybenzylidene)
benzohydrazide hemihydrate |
| title_full_unstemmed | (E)-4-Methoxy-N00-(2,4,5-trimethoxybenzylidene)
benzohydrazide hemihydrate |
| title_short | (E)-4-Methoxy-N00-(2,4,5-trimethoxybenzylidene)
benzohydrazide hemihydrate |
| title_sort | e 4 methoxy n00 2 4 5 trimethoxybenzylidene benzohydrazide hemihydrate |
| topic | QC1-999 Physics |
| url | http://eprints.usm.my/38796/1/E%29-4-Methoxy-N%27-%282%2C4%2C5-trimethoxybenzylidene%29benzohydrazide.pdf |
| work_keys_str_mv | AT chantraprommasuchada e4methoxyn00245trimethoxybenzylidenebenzohydrazidehemihydrate AT boonnaknawong e4methoxyn00245trimethoxybenzylidenebenzohydrazidehemihydrate AT horkaewjirapa e4methoxyn00245trimethoxybenzylidenebenzohydrazidehemihydrate AT chingkhengquah e4methoxyn00245trimethoxybenzylidenebenzohydrazidehemihydrate AT funhoongkun e4methoxyn00245trimethoxybenzylidenebenzohydrazidehemihydrate |