Effect of Zeolite Modification via Cationic Exchange Method on Mechanical, Thermal, and Morphological Properties of Ethylene Vinyl Acetate/Zeolite Composites
In this research, organozeolite filled ethylene vinyl acetate (EVA) composites were prepared in a melt-mixing process and followed by compressionmolding using hot press machine according to standard test specimen. Prior to mixing process, zeolitewasmodified via cationic exchange of alkylammonium i...
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Format: | Article |
Language: | English |
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Hindawi Publishing Corporation
2013
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Online Access: | http://eprints.usm.my/38894/1/Effect_of_Zeolite_Modification_via_Cationic_Exchange_Method_on_Mechanical%2C_Thermal.pdf |
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author | Zaharri, N. D. Othman, N. Mohd Ishak, Z. A. |
author_facet | Zaharri, N. D. Othman, N. Mohd Ishak, Z. A. |
author_sort | Zaharri, N. D. |
collection | USM |
description | In this research, organozeolite filled ethylene vinyl acetate (EVA) composites were prepared in a melt-mixing process and followed
by compressionmolding using hot press machine according to standard test specimen. Prior to mixing process, zeolitewasmodified
via cationic exchange of alkylammonium ions.The effect of zeolite or organozeolite loading from 5 up to 25 volume percentages
on the properties of EVA/zeolite composites was evaluated. A combination of Fourier Transform Infrared Radiation (FTIR) and
scanning electron microscopy (SEM) coupled with energy dispersive X-ray (EDX) analysis were done to characterize the resultant
organoclay. Tensile test was performed in order to study themechanical properties of the composites. EVA filled with organozeolite
showed better tensile properties compared to EVA filled with unmodified zeolite, which might be an indication of enhanced
dispersion of organophilic clay in the composites. Meanwhile, morphological study using SEM revealed the fibrillation effect of
organozeolite. Besides, thermal properties of the composites were also characterized by using thermogravimetric analysis (TGA)
and differential scanning calorimetry (DSC). The results showed that the application of the cation exchange treatment increases
both decomposition and melting temperature of EVA/zeolite composites. |
first_indexed | 2024-03-06T15:15:21Z |
format | Article |
id | usm.eprints-38894 |
institution | Universiti Sains Malaysia |
language | English |
last_indexed | 2024-03-06T15:15:21Z |
publishDate | 2013 |
publisher | Hindawi Publishing Corporation |
record_format | dspace |
spelling | usm.eprints-388942018-02-13T08:52:59Z http://eprints.usm.my/38894/ Effect of Zeolite Modification via Cationic Exchange Method on Mechanical, Thermal, and Morphological Properties of Ethylene Vinyl Acetate/Zeolite Composites Zaharri, N. D. Othman, N. Mohd Ishak, Z. A. TN1-997 Mining engineering. Metallurgy In this research, organozeolite filled ethylene vinyl acetate (EVA) composites were prepared in a melt-mixing process and followed by compressionmolding using hot press machine according to standard test specimen. Prior to mixing process, zeolitewasmodified via cationic exchange of alkylammonium ions.The effect of zeolite or organozeolite loading from 5 up to 25 volume percentages on the properties of EVA/zeolite composites was evaluated. A combination of Fourier Transform Infrared Radiation (FTIR) and scanning electron microscopy (SEM) coupled with energy dispersive X-ray (EDX) analysis were done to characterize the resultant organoclay. Tensile test was performed in order to study themechanical properties of the composites. EVA filled with organozeolite showed better tensile properties compared to EVA filled with unmodified zeolite, which might be an indication of enhanced dispersion of organophilic clay in the composites. Meanwhile, morphological study using SEM revealed the fibrillation effect of organozeolite. Besides, thermal properties of the composites were also characterized by using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results showed that the application of the cation exchange treatment increases both decomposition and melting temperature of EVA/zeolite composites. Hindawi Publishing Corporation 2013 Article PeerReviewed application/pdf en http://eprints.usm.my/38894/1/Effect_of_Zeolite_Modification_via_Cationic_Exchange_Method_on_Mechanical%2C_Thermal.pdf Zaharri, N. D. and Othman, N. and Mohd Ishak, Z. A. (2013) Effect of Zeolite Modification via Cationic Exchange Method on Mechanical, Thermal, and Morphological Properties of Ethylene Vinyl Acetate/Zeolite Composites. Advances in Materials Science and Engineering, 2013 (394656). pp. 1-9. ISSN 1687-8434 http://dx.doi.org/10.1155/2013/394656 |
spellingShingle | TN1-997 Mining engineering. Metallurgy Zaharri, N. D. Othman, N. Mohd Ishak, Z. A. Effect of Zeolite Modification via Cationic Exchange Method on Mechanical, Thermal, and Morphological Properties of Ethylene Vinyl Acetate/Zeolite Composites |
title | Effect of Zeolite Modification via Cationic Exchange Method on Mechanical, Thermal, and Morphological Properties of Ethylene Vinyl Acetate/Zeolite Composites |
title_full | Effect of Zeolite Modification via Cationic Exchange Method on Mechanical, Thermal, and Morphological Properties of Ethylene Vinyl Acetate/Zeolite Composites |
title_fullStr | Effect of Zeolite Modification via Cationic Exchange Method on Mechanical, Thermal, and Morphological Properties of Ethylene Vinyl Acetate/Zeolite Composites |
title_full_unstemmed | Effect of Zeolite Modification via Cationic Exchange Method on Mechanical, Thermal, and Morphological Properties of Ethylene Vinyl Acetate/Zeolite Composites |
title_short | Effect of Zeolite Modification via Cationic Exchange Method on Mechanical, Thermal, and Morphological Properties of Ethylene Vinyl Acetate/Zeolite Composites |
title_sort | effect of zeolite modification via cationic exchange method on mechanical thermal and morphological properties of ethylene vinyl acetate zeolite composites |
topic | TN1-997 Mining engineering. Metallurgy |
url | http://eprints.usm.my/38894/1/Effect_of_Zeolite_Modification_via_Cationic_Exchange_Method_on_Mechanical%2C_Thermal.pdf |
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