Synthesis, characterisation, thermal and electrical behaviour of copper and copper sulphide-epoxy nanocomposites.
Nanozarah kuprum (Cu) dan kuprum sulfida (CuS) disintesis di dalam fasa akueus dan serta-merta dipindahkan ke fasa organik yang mengandungi epoksi melalui kaedah pemindahan fasa. Spektrum penyerapan UV-vis menunjukkan kehadiran Cu dan CuS. Penambahan diglisidil eter bisfenol A (DGEBA) ke dalam organ...
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| Format: | Thesis |
| Language: | English |
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2011
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| Online Access: | http://eprints.usm.my/43049/1/Pages_from_SYNTHESIS_CHARACTERISATION_THERMAL_AND_ELECTRICAL.pdf |
| _version_ | 1825834732370264064 |
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| author | Hirmizi, Nor Hashila Mohd |
| author_facet | Hirmizi, Nor Hashila Mohd |
| author_sort | Hirmizi, Nor Hashila Mohd |
| collection | USM |
| description | Nanozarah kuprum (Cu) dan kuprum sulfida (CuS) disintesis di dalam fasa akueus dan serta-merta dipindahkan ke fasa organik yang mengandungi epoksi melalui kaedah pemindahan fasa. Spektrum penyerapan UV-vis menunjukkan kehadiran Cu dan CuS. Penambahan diglisidil eter bisfenol A (DGEBA) ke dalam organosol masing-masing dan setelah penyingkiran pelarut memberikan nanokomposit Cu- dan CuS-epoksi. Komposit ini dimatangkan menggunakan 4,4’-metilenadianilina (MDA). Bagi Cu-epoksi, kecekapan pemindahan zarah yang tertinggi adalah ≈ 97.2% apabila sampel disediakan menggunakan 5 mL isopropanol (IPA). IPA turut memberi kesan terhadap saiz purata zarah.
Copper (Cu) and copper sulphide (CuS) nanoparticles were synthesised in an aqueous phase and subsequently transferred into the organic phase containing epoxy via phase transfer technique. The UV-vis absorption spectra confirmed the existence of Cu and CuS. Incorporation of diglycidyl ether of bisphenol A (DGEBA) into the respective organosols and upon solvent removal afforded Cu- and CuS-epoxy nanocomposites. These composites were cured using 4,4’-methyelene-dianiline (MDA). In the case of Cu-epoxy, the highest particle transfer efficiency was at ≈ 97.2% when the samples were prepared with 5 mL isopropanol (IPA). IPA also exerts influence on the average particle size. |
| first_indexed | 2024-03-06T15:27:06Z |
| format | Thesis |
| id | usm.eprints-43049 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:27:06Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | usm.eprints-430492018-11-28T03:31:35Z http://eprints.usm.my/43049/ Synthesis, characterisation, thermal and electrical behaviour of copper and copper sulphide-epoxy nanocomposites. Hirmizi, Nor Hashila Mohd QD1-999 Chemistry Nanozarah kuprum (Cu) dan kuprum sulfida (CuS) disintesis di dalam fasa akueus dan serta-merta dipindahkan ke fasa organik yang mengandungi epoksi melalui kaedah pemindahan fasa. Spektrum penyerapan UV-vis menunjukkan kehadiran Cu dan CuS. Penambahan diglisidil eter bisfenol A (DGEBA) ke dalam organosol masing-masing dan setelah penyingkiran pelarut memberikan nanokomposit Cu- dan CuS-epoksi. Komposit ini dimatangkan menggunakan 4,4’-metilenadianilina (MDA). Bagi Cu-epoksi, kecekapan pemindahan zarah yang tertinggi adalah ≈ 97.2% apabila sampel disediakan menggunakan 5 mL isopropanol (IPA). IPA turut memberi kesan terhadap saiz purata zarah. Copper (Cu) and copper sulphide (CuS) nanoparticles were synthesised in an aqueous phase and subsequently transferred into the organic phase containing epoxy via phase transfer technique. The UV-vis absorption spectra confirmed the existence of Cu and CuS. Incorporation of diglycidyl ether of bisphenol A (DGEBA) into the respective organosols and upon solvent removal afforded Cu- and CuS-epoxy nanocomposites. These composites were cured using 4,4’-methyelene-dianiline (MDA). In the case of Cu-epoxy, the highest particle transfer efficiency was at ≈ 97.2% when the samples were prepared with 5 mL isopropanol (IPA). IPA also exerts influence on the average particle size. 2011-08 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/43049/1/Pages_from_SYNTHESIS_CHARACTERISATION_THERMAL_AND_ELECTRICAL.pdf Hirmizi, Nor Hashila Mohd (2011) Synthesis, characterisation, thermal and electrical behaviour of copper and copper sulphide-epoxy nanocomposites. Masters thesis, Universiti Sains Malaysia. |
| spellingShingle | QD1-999 Chemistry Hirmizi, Nor Hashila Mohd Synthesis, characterisation, thermal and electrical behaviour of copper and copper sulphide-epoxy nanocomposites. |
| title | Synthesis, characterisation, thermal and electrical behaviour of copper and copper sulphide-epoxy nanocomposites. |
| title_full | Synthesis, characterisation, thermal and electrical behaviour of copper and copper sulphide-epoxy nanocomposites. |
| title_fullStr | Synthesis, characterisation, thermal and electrical behaviour of copper and copper sulphide-epoxy nanocomposites. |
| title_full_unstemmed | Synthesis, characterisation, thermal and electrical behaviour of copper and copper sulphide-epoxy nanocomposites. |
| title_short | Synthesis, characterisation, thermal and electrical behaviour of copper and copper sulphide-epoxy nanocomposites. |
| title_sort | synthesis characterisation thermal and electrical behaviour of copper and copper sulphide epoxy nanocomposites |
| topic | QD1-999 Chemistry |
| url | http://eprints.usm.my/43049/1/Pages_from_SYNTHESIS_CHARACTERISATION_THERMAL_AND_ELECTRICAL.pdf |
| work_keys_str_mv | AT hirmizinorhashilamohd synthesischaracterisationthermalandelectricalbehaviourofcopperandcoppersulphideepoxynanocomposites |