Synthesis And Characterization Of Zno Nanostructures Using Physical Vapor Deposition And Electrochemical Deposition For Optoelectronic Applications

ZnO nanostructures were grown by simple techniques to develop ZnO-based semiconductor photodetectors (PDs) for UV detection. This work employed two techniques, first, physical vapor deposition (PVD) and second, electrochemical deposition (ECD) techniques. In the PVD process, condensed Zn vapor is re...

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Main Author: Hassan, Nadim Khalid
Format: Thesis
Language:English
Published: 2013
Subjects:
Online Access:http://eprints.usm.my/46173/1/Nadim%20Khalid%20Hassan24.pdf
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author Hassan, Nadim Khalid
author_facet Hassan, Nadim Khalid
author_sort Hassan, Nadim Khalid
collection USM
description ZnO nanostructures were grown by simple techniques to develop ZnO-based semiconductor photodetectors (PDs) for UV detection. This work employed two techniques, first, physical vapor deposition (PVD) and second, electrochemical deposition (ECD) techniques. In the PVD process, condensed Zn vapor is reacted with oxygen via vapor solid mechanism in three-zone tube furnace. The source material for PVD was pure Zn powder evaporated under different reaction conditions. Variations in the reaction time, substrates, and temperature in the furnace were found to control the growth mechanism and morphology of the ZnO nanostructures. For instance, high quality 1D ZnO nanostructures (Rods) were achieved on SiO2 using ZnO thin film as a buffer layer. Also, it was possible to grow tetrapods-like ZnO (TPs) and nanowires with different diameters and lengths as confirmed via SEM imaging. Photoluminescence (PL) measurements at room temperature showed a dominant peak related to a near-band-edge emission at approximately 376 nm with an additional peak related to green-band emission at approximately 520 nm.The highest near-band emission to green band emission ratio of 1D ZnO nanostructures grown on Si(111) could result from the high crystallinity of the fabricated nanostructure. Raman spectra measurements show four peaks, of which E2 high was the dominant peak. The shift in this dominant peak from 437 cm-1 provided accurate information of the stress in the ZnO film lattice.
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spelling usm.eprints-461732020-02-11T04:40:57Z http://eprints.usm.my/46173/ Synthesis And Characterization Of Zno Nanostructures Using Physical Vapor Deposition And Electrochemical Deposition For Optoelectronic Applications Hassan, Nadim Khalid QC1 Physics (General) ZnO nanostructures were grown by simple techniques to develop ZnO-based semiconductor photodetectors (PDs) for UV detection. This work employed two techniques, first, physical vapor deposition (PVD) and second, electrochemical deposition (ECD) techniques. In the PVD process, condensed Zn vapor is reacted with oxygen via vapor solid mechanism in three-zone tube furnace. The source material for PVD was pure Zn powder evaporated under different reaction conditions. Variations in the reaction time, substrates, and temperature in the furnace were found to control the growth mechanism and morphology of the ZnO nanostructures. For instance, high quality 1D ZnO nanostructures (Rods) were achieved on SiO2 using ZnO thin film as a buffer layer. Also, it was possible to grow tetrapods-like ZnO (TPs) and nanowires with different diameters and lengths as confirmed via SEM imaging. Photoluminescence (PL) measurements at room temperature showed a dominant peak related to a near-band-edge emission at approximately 376 nm with an additional peak related to green-band emission at approximately 520 nm.The highest near-band emission to green band emission ratio of 1D ZnO nanostructures grown on Si(111) could result from the high crystallinity of the fabricated nanostructure. Raman spectra measurements show four peaks, of which E2 high was the dominant peak. The shift in this dominant peak from 437 cm-1 provided accurate information of the stress in the ZnO film lattice. 2013-10 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/46173/1/Nadim%20Khalid%20Hassan24.pdf Hassan, Nadim Khalid (2013) Synthesis And Characterization Of Zno Nanostructures Using Physical Vapor Deposition And Electrochemical Deposition For Optoelectronic Applications. PhD thesis, Universiti Sains Malaysia.
spellingShingle QC1 Physics (General)
Hassan, Nadim Khalid
Synthesis And Characterization Of Zno Nanostructures Using Physical Vapor Deposition And Electrochemical Deposition For Optoelectronic Applications
title Synthesis And Characterization Of Zno Nanostructures Using Physical Vapor Deposition And Electrochemical Deposition For Optoelectronic Applications
title_full Synthesis And Characterization Of Zno Nanostructures Using Physical Vapor Deposition And Electrochemical Deposition For Optoelectronic Applications
title_fullStr Synthesis And Characterization Of Zno Nanostructures Using Physical Vapor Deposition And Electrochemical Deposition For Optoelectronic Applications
title_full_unstemmed Synthesis And Characterization Of Zno Nanostructures Using Physical Vapor Deposition And Electrochemical Deposition For Optoelectronic Applications
title_short Synthesis And Characterization Of Zno Nanostructures Using Physical Vapor Deposition And Electrochemical Deposition For Optoelectronic Applications
title_sort synthesis and characterization of zno nanostructures using physical vapor deposition and electrochemical deposition for optoelectronic applications
topic QC1 Physics (General)
url http://eprints.usm.my/46173/1/Nadim%20Khalid%20Hassan24.pdf
work_keys_str_mv AT hassannadimkhalid synthesisandcharacterizationofznonanostructuresusingphysicalvapordepositionandelectrochemicaldepositionforoptoelectronicapplications