Zinc Oxide Nanostructures Grown Using Electric Field-Assisted Aqueous Solution Method For Uv Photodetector Applications

Nanostructured zinc oxide (ZnO) was successfully synthesized using an electric field-assisted aqueous solution (EFAS) technique. ZnO nanostructures were grown with different growth parameters and characterized for the structural, optical and electrical properties. The study employed ZnO-seeded porou...

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Main Author: Dalvand, Ramazanali
Format: Thesis
Language:English
Published: 2019
Subjects:
Online Access:http://eprints.usm.my/48247/1/RAMAZANALI%20DALVAND%20cut.pdf
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author Dalvand, Ramazanali
author_facet Dalvand, Ramazanali
author_sort Dalvand, Ramazanali
collection USM
description Nanostructured zinc oxide (ZnO) was successfully synthesized using an electric field-assisted aqueous solution (EFAS) technique. ZnO nanostructures were grown with different growth parameters and characterized for the structural, optical and electrical properties. The study employed ZnO-seeded porous silicon (PSi) to grow one-dimensional (1-D) ZnO nanostructures. ZnO nanorod arrays were synthesized via the optimization of current density by using EFAS method and the ZnO nanorods were grown on PSi substrates that were prepared via a photo electrochemical etching (PECE) technique. Vertically aligned needle-shaped ZnO sample prepared at a current density of 0.5 mA/cm2, growth temperature of 105 °C, precursor concentration of 50 mM, and growth duration of 60 minutes produced the optimal structural, morphological, and optical properties with the highest (002) XRD peak intensity. Moreover, photoluminescence (PL) data of the optimized sample revealed the highest near-band-edge emission to deep-level emission intensity ratio while Raman data showed the most intense E2 (high) phonon mode compared with that of other samples. Using the optimized precursor concentration in the EFAS method, 1-D ZnO nanostructure arrays were grown on PSi subtrates. 1-D ZnO nanorods with cone heads were produced using the EFAS technique when the growth parameters were tuned at 50 mM precursor concentration, 0.65 mA/cm2 current density, 105 °C growth temperature and 60 minutes growth duration.
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spelling usm.eprints-482472021-02-05T02:40:50Z http://eprints.usm.my/48247/ Zinc Oxide Nanostructures Grown Using Electric Field-Assisted Aqueous Solution Method For Uv Photodetector Applications Dalvand, Ramazanali QC1 Physics (General) Nanostructured zinc oxide (ZnO) was successfully synthesized using an electric field-assisted aqueous solution (EFAS) technique. ZnO nanostructures were grown with different growth parameters and characterized for the structural, optical and electrical properties. The study employed ZnO-seeded porous silicon (PSi) to grow one-dimensional (1-D) ZnO nanostructures. ZnO nanorod arrays were synthesized via the optimization of current density by using EFAS method and the ZnO nanorods were grown on PSi substrates that were prepared via a photo electrochemical etching (PECE) technique. Vertically aligned needle-shaped ZnO sample prepared at a current density of 0.5 mA/cm2, growth temperature of 105 °C, precursor concentration of 50 mM, and growth duration of 60 minutes produced the optimal structural, morphological, and optical properties with the highest (002) XRD peak intensity. Moreover, photoluminescence (PL) data of the optimized sample revealed the highest near-band-edge emission to deep-level emission intensity ratio while Raman data showed the most intense E2 (high) phonon mode compared with that of other samples. Using the optimized precursor concentration in the EFAS method, 1-D ZnO nanostructure arrays were grown on PSi subtrates. 1-D ZnO nanorods with cone heads were produced using the EFAS technique when the growth parameters were tuned at 50 mM precursor concentration, 0.65 mA/cm2 current density, 105 °C growth temperature and 60 minutes growth duration. 2019-06 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/48247/1/RAMAZANALI%20DALVAND%20cut.pdf Dalvand, Ramazanali (2019) Zinc Oxide Nanostructures Grown Using Electric Field-Assisted Aqueous Solution Method For Uv Photodetector Applications. PhD thesis, Universiti Sains Malaysia.
spellingShingle QC1 Physics (General)
Dalvand, Ramazanali
Zinc Oxide Nanostructures Grown Using Electric Field-Assisted Aqueous Solution Method For Uv Photodetector Applications
title Zinc Oxide Nanostructures Grown Using Electric Field-Assisted Aqueous Solution Method For Uv Photodetector Applications
title_full Zinc Oxide Nanostructures Grown Using Electric Field-Assisted Aqueous Solution Method For Uv Photodetector Applications
title_fullStr Zinc Oxide Nanostructures Grown Using Electric Field-Assisted Aqueous Solution Method For Uv Photodetector Applications
title_full_unstemmed Zinc Oxide Nanostructures Grown Using Electric Field-Assisted Aqueous Solution Method For Uv Photodetector Applications
title_short Zinc Oxide Nanostructures Grown Using Electric Field-Assisted Aqueous Solution Method For Uv Photodetector Applications
title_sort zinc oxide nanostructures grown using electric field assisted aqueous solution method for uv photodetector applications
topic QC1 Physics (General)
url http://eprints.usm.my/48247/1/RAMAZANALI%20DALVAND%20cut.pdf
work_keys_str_mv AT dalvandramazanali zincoxidenanostructuresgrownusingelectricfieldassistedaqueoussolutionmethodforuvphotodetectorapplications