Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage
Storing hydrogen efficiently in condensed materials is a key technical challenge. Tremendous efforts have been given to inorganic hydrides containing B-H, Al-H and/or N-H bonds, while organic compounds with a great variety and rich chemistry in manupulating C-H and unsaturated bonds, however, are un...
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| Format: | Thesis |
| Language: | English |
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2020
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| Online Access: | http://eprints.usm.my/52598/1/TAN%20KHAI%20CHEN%20-%20TESIS.pdf%20cut.pdf |
| _version_ | 1797012847747661824 |
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| author | Tan, Khai Chen |
| author_facet | Tan, Khai Chen |
| author_sort | Tan, Khai Chen |
| collection | USM |
| description | Storing hydrogen efficiently in condensed materials is a key technical challenge. Tremendous efforts have been given to inorganic hydrides containing B-H, Al-H and/or N-H bonds, while organic compounds with a great variety and rich chemistry in manupulating C-H and unsaturated bonds, however, are undervalued mainly because of their unfavourable thermodynamics and selectivity in dehydrogenation. Here, we developed a new family of hydrogen storage material spanning across the domain of inorganic and organic hydrogenous compounds, namely metallo-N-heterocycles, utilizing the electron donating nature of alkali or alkaline earth metals to tune the strengths of C-H, C-N and C-C bonds of N-heterocyclic molecules to be suitable for hydrogen storage in terms of thermodynamic and kinetic properties. |
| first_indexed | 2024-03-06T15:53:42Z |
| format | Thesis |
| id | usm.eprints-52598 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:53:42Z |
| publishDate | 2020 |
| record_format | dspace |
| spelling | usm.eprints-525982022-05-26T02:33:18Z http://eprints.usm.my/52598/ Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage Tan, Khai Chen QD241-441 Organic chemistry Storing hydrogen efficiently in condensed materials is a key technical challenge. Tremendous efforts have been given to inorganic hydrides containing B-H, Al-H and/or N-H bonds, while organic compounds with a great variety and rich chemistry in manupulating C-H and unsaturated bonds, however, are undervalued mainly because of their unfavourable thermodynamics and selectivity in dehydrogenation. Here, we developed a new family of hydrogen storage material spanning across the domain of inorganic and organic hydrogenous compounds, namely metallo-N-heterocycles, utilizing the electron donating nature of alkali or alkaline earth metals to tune the strengths of C-H, C-N and C-C bonds of N-heterocyclic molecules to be suitable for hydrogen storage in terms of thermodynamic and kinetic properties. 2020-05 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/52598/1/TAN%20KHAI%20CHEN%20-%20TESIS.pdf%20cut.pdf Tan, Khai Chen (2020) Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage. Masters thesis, Universiti Sains Malaysia. |
| spellingShingle | QD241-441 Organic chemistry Tan, Khai Chen Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage |
| title | Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage |
| title_full | Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage |
| title_fullStr | Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage |
| title_full_unstemmed | Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage |
| title_short | Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage |
| title_sort | development of hybrid organic inorganic hydride for reversible hydrogen storage |
| topic | QD241-441 Organic chemistry |
| url | http://eprints.usm.my/52598/1/TAN%20KHAI%20CHEN%20-%20TESIS.pdf%20cut.pdf |
| work_keys_str_mv | AT tankhaichen developmentofhybridorganicinorganichydrideforreversiblehydrogenstorage |