Conceptual Study Of Enzymatic Synthesis Of Propyl Caffeate In Packed Bed Reactor At Steady-State And Isothermal Conditions
The enzymatic propyl caffeate synthesis in packed bed reactor (PBR) at steady-state and isothermal conditions is presented in this thesis. The simulation carried out to study the effects of temperature, substrate/alcohol molar ratio, and substrate concentration on conversion. The mathematical model...
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| Format: | Monograph |
| Language: | English |
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Universiti Sains Malaysia
2021
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| Online Access: | http://eprints.usm.my/54402/1/Conceptual%20Study%20Of%20Enzymatic%20Synthesis%20Of%20Propyl%20Caffeate%20In%20Packed%20Bed%20Reactor%20At%20Steady-State%20And%20Isothermal%20Conditions_Ajayan%20Rajendran_M4_2021_ESAR.pdf |
| _version_ | 1825907085240434688 |
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| author | Rajendran, Ajayan |
| author_facet | Rajendran, Ajayan |
| author_sort | Rajendran, Ajayan |
| collection | USM |
| description | The enzymatic propyl caffeate synthesis in packed bed reactor (PBR) at steady-state and isothermal conditions is presented in this thesis. The simulation carried out to study the effects of temperature, substrate/alcohol molar ratio, and substrate concentration on conversion. The mathematical model is developed in Polymath® software to simulate the results to compare with published experimental data. The highest conversion achieved at 60°C with 99.5% in the experimental data while the proposed simulated data gives 91.1% at 60°C with the error percentage of 8.44% which is considered acceptable error percentage since less than 10%. Based on this simulation results, both conversion and rate of reaction is decreases at
reaction temperature above 80°C which shows the enzyme are start to deactivate at this temperature. This study shows the highest conversion is achieved in both simulation and
experimental results at reaction temperature of 70°C and 60°C respectively. Moreover, both simulated and experimental results indicates that the perfect molar ratio of methyl caffeate to
1-propanol is with range of 1:10 and 1:40 which give higher conversion and producing high yield. In addition, the studies found that low concentration of methyl caffeate of 0.005 mol/L
provide the highest conversion and enhances the enzymatic reaction. |
| first_indexed | 2024-03-06T15:58:58Z |
| format | Monograph |
| id | usm.eprints-54402 |
| institution | Universiti Sains Malaysia |
| language | English |
| last_indexed | 2024-03-06T15:58:58Z |
| publishDate | 2021 |
| publisher | Universiti Sains Malaysia |
| record_format | dspace |
| spelling | usm.eprints-544022022-08-30T03:44:01Z http://eprints.usm.my/54402/ Conceptual Study Of Enzymatic Synthesis Of Propyl Caffeate In Packed Bed Reactor At Steady-State And Isothermal Conditions Rajendran, Ajayan T Technology TP Chemical Technology The enzymatic propyl caffeate synthesis in packed bed reactor (PBR) at steady-state and isothermal conditions is presented in this thesis. The simulation carried out to study the effects of temperature, substrate/alcohol molar ratio, and substrate concentration on conversion. The mathematical model is developed in Polymath® software to simulate the results to compare with published experimental data. The highest conversion achieved at 60°C with 99.5% in the experimental data while the proposed simulated data gives 91.1% at 60°C with the error percentage of 8.44% which is considered acceptable error percentage since less than 10%. Based on this simulation results, both conversion and rate of reaction is decreases at reaction temperature above 80°C which shows the enzyme are start to deactivate at this temperature. This study shows the highest conversion is achieved in both simulation and experimental results at reaction temperature of 70°C and 60°C respectively. Moreover, both simulated and experimental results indicates that the perfect molar ratio of methyl caffeate to 1-propanol is with range of 1:10 and 1:40 which give higher conversion and producing high yield. In addition, the studies found that low concentration of methyl caffeate of 0.005 mol/L provide the highest conversion and enhances the enzymatic reaction. Universiti Sains Malaysia 2021-06-01 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/54402/1/Conceptual%20Study%20Of%20Enzymatic%20Synthesis%20Of%20Propyl%20Caffeate%20In%20Packed%20Bed%20Reactor%20At%20Steady-State%20And%20Isothermal%20Conditions_Ajayan%20Rajendran_M4_2021_ESAR.pdf Rajendran, Ajayan (2021) Conceptual Study Of Enzymatic Synthesis Of Propyl Caffeate In Packed Bed Reactor At Steady-State And Isothermal Conditions. Project Report. Universiti Sains Malaysia, Pusat Pengajian Kejuruteraan Kimia. (Submitted) |
| spellingShingle | T Technology TP Chemical Technology Rajendran, Ajayan Conceptual Study Of Enzymatic Synthesis Of Propyl Caffeate In Packed Bed Reactor At Steady-State And Isothermal Conditions |
| title | Conceptual Study Of Enzymatic Synthesis Of Propyl Caffeate In Packed Bed Reactor At Steady-State And Isothermal Conditions |
| title_full | Conceptual Study Of Enzymatic Synthesis Of Propyl Caffeate In Packed Bed Reactor At Steady-State And Isothermal Conditions |
| title_fullStr | Conceptual Study Of Enzymatic Synthesis Of Propyl Caffeate In Packed Bed Reactor At Steady-State And Isothermal Conditions |
| title_full_unstemmed | Conceptual Study Of Enzymatic Synthesis Of Propyl Caffeate In Packed Bed Reactor At Steady-State And Isothermal Conditions |
| title_short | Conceptual Study Of Enzymatic Synthesis Of Propyl Caffeate In Packed Bed Reactor At Steady-State And Isothermal Conditions |
| title_sort | conceptual study of enzymatic synthesis of propyl caffeate in packed bed reactor at steady state and isothermal conditions |
| topic | T Technology TP Chemical Technology |
| url | http://eprints.usm.my/54402/1/Conceptual%20Study%20Of%20Enzymatic%20Synthesis%20Of%20Propyl%20Caffeate%20In%20Packed%20Bed%20Reactor%20At%20Steady-State%20And%20Isothermal%20Conditions_Ajayan%20Rajendran_M4_2021_ESAR.pdf |
| work_keys_str_mv | AT rajendranajayan conceptualstudyofenzymaticsynthesisofpropylcaffeateinpackedbedreactoratsteadystateandisothermalconditions |