Room-Temperature Synthesis Of Bismuth Oxybromide-Based Photocatalysts For The Removal Of Ciprofloxacin From Aqueous Solution Under Visible Light

Semiconductor photocatalysis using visible-light-driven photocatalysts is gaining more attention, due to its wide applications in energy conversion and environmental remediation. Recently, a ternary V-VI-VII semiconductor, bismuth oxybromide (BiOBr) has received extensive attention in photocatalysis...

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Main Author: Imam, Saifullahi Shehu
Format: Thesis
Language:English
Published: 2020
Subjects:
Online Access:http://eprints.usm.my/55185/1/SAIFULLAHI%20SHEHU%20IMAM%20-%20TESIS%20cut.pdf
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author Imam, Saifullahi Shehu
author_facet Imam, Saifullahi Shehu
author_sort Imam, Saifullahi Shehu
collection USM
description Semiconductor photocatalysis using visible-light-driven photocatalysts is gaining more attention, due to its wide applications in energy conversion and environmental remediation. Recently, a ternary V-VI-VII semiconductor, bismuth oxybromide (BiOBr) has received extensive attention in photocatalysis due to its low cost, non-toxicity, and other unique properties. However, BiOBr alone exhibits low photodegradation efficiency, due to low visible light absorption and recombination of photogenerated charge carriers. Furthermore, for practical and large-scale application, the separation of powdered BiOBr is inconvenient. The primary aims of this work are to synthesize BiOBr-based photocatalysts at room-temperature, using facile, low cost and environmentally friendly methods, to enhance the photodegradation activity of BiOBr, as well as to ease the separation of the photocatalyst from the aqueous system. To achieve these goals, two strategies were employed. First, the pristine BiOBr was used as a host material to produce photocatalyst composites. Using this method, three BiOBr-based composites namely Bi/BiOBr, BiOBr/Bi2O3 and BiOBr/Bi2S3 were prepared. Second, the pristine BiOBr was immobilized onto cellulose acetate (CA), forming BiOBr/cellulose acetate (BCA) composite films. The structural and physicochemical properties of both powdered and immobilized BiOBr-composites were characterized using various techniques.
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spelling usm.eprints-551852022-10-06T07:01:17Z http://eprints.usm.my/55185/ Room-Temperature Synthesis Of Bismuth Oxybromide-Based Photocatalysts For The Removal Of Ciprofloxacin From Aqueous Solution Under Visible Light Imam, Saifullahi Shehu QD1-65 General Including alchemy Semiconductor photocatalysis using visible-light-driven photocatalysts is gaining more attention, due to its wide applications in energy conversion and environmental remediation. Recently, a ternary V-VI-VII semiconductor, bismuth oxybromide (BiOBr) has received extensive attention in photocatalysis due to its low cost, non-toxicity, and other unique properties. However, BiOBr alone exhibits low photodegradation efficiency, due to low visible light absorption and recombination of photogenerated charge carriers. Furthermore, for practical and large-scale application, the separation of powdered BiOBr is inconvenient. The primary aims of this work are to synthesize BiOBr-based photocatalysts at room-temperature, using facile, low cost and environmentally friendly methods, to enhance the photodegradation activity of BiOBr, as well as to ease the separation of the photocatalyst from the aqueous system. To achieve these goals, two strategies were employed. First, the pristine BiOBr was used as a host material to produce photocatalyst composites. Using this method, three BiOBr-based composites namely Bi/BiOBr, BiOBr/Bi2O3 and BiOBr/Bi2S3 were prepared. Second, the pristine BiOBr was immobilized onto cellulose acetate (CA), forming BiOBr/cellulose acetate (BCA) composite films. The structural and physicochemical properties of both powdered and immobilized BiOBr-composites were characterized using various techniques. 2020-07 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/55185/1/SAIFULLAHI%20SHEHU%20IMAM%20-%20TESIS%20cut.pdf Imam, Saifullahi Shehu (2020) Room-Temperature Synthesis Of Bismuth Oxybromide-Based Photocatalysts For The Removal Of Ciprofloxacin From Aqueous Solution Under Visible Light. PhD thesis, Universiti Sains Malaysia.
spellingShingle QD1-65 General Including alchemy
Imam, Saifullahi Shehu
Room-Temperature Synthesis Of Bismuth Oxybromide-Based Photocatalysts For The Removal Of Ciprofloxacin From Aqueous Solution Under Visible Light
title Room-Temperature Synthesis Of Bismuth Oxybromide-Based Photocatalysts For The Removal Of Ciprofloxacin From Aqueous Solution Under Visible Light
title_full Room-Temperature Synthesis Of Bismuth Oxybromide-Based Photocatalysts For The Removal Of Ciprofloxacin From Aqueous Solution Under Visible Light
title_fullStr Room-Temperature Synthesis Of Bismuth Oxybromide-Based Photocatalysts For The Removal Of Ciprofloxacin From Aqueous Solution Under Visible Light
title_full_unstemmed Room-Temperature Synthesis Of Bismuth Oxybromide-Based Photocatalysts For The Removal Of Ciprofloxacin From Aqueous Solution Under Visible Light
title_short Room-Temperature Synthesis Of Bismuth Oxybromide-Based Photocatalysts For The Removal Of Ciprofloxacin From Aqueous Solution Under Visible Light
title_sort room temperature synthesis of bismuth oxybromide based photocatalysts for the removal of ciprofloxacin from aqueous solution under visible light
topic QD1-65 General Including alchemy
url http://eprints.usm.my/55185/1/SAIFULLAHI%20SHEHU%20IMAM%20-%20TESIS%20cut.pdf
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