Electrochemical Characterization Of Tin Electrode In Synthetic Seawater

Tin is a common element generally added to many materials to improve the corrosion resistance. This research studies the electrochemical behaviour of tin electrode in synthetic seawater using linear polarization, cyclic voltammetry and EIS and also to investigate the interaction effect of three fa...

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Main Author: Amanda Kwok, Si En
Format: Monograph
Language:English
Published: Universiti Sains Malaysia 2022
Subjects:
Online Access:http://eprints.usm.my/56435/1/Electrochemical%20Characterization%20Of%20Tin%20Electrode%20In%20Synthetic%20Seawater_Amanda%20Kwok%20Si%20En.pdf
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author Amanda Kwok, Si En
author_facet Amanda Kwok, Si En
author_sort Amanda Kwok, Si En
collection USM
description Tin is a common element generally added to many materials to improve the corrosion resistance. This research studies the electrochemical behaviour of tin electrode in synthetic seawater using linear polarization, cyclic voltammetry and EIS and also to investigate the interaction effect of three factors, salinity, temperature and immersion time on the corrosion rate and polarization resistance. Linear polarization is done to study the corrosion rate and polarisation resistance obtained from Tafel plot. Cyclic voltammetry is done to measure the resulting current produced by the Sn electrochemical cell under different parameters of salinity, temperature and immersion time. EIS is used to analyse the chemical processes occurring at the site of the Sn electrode after immersion in synthetic seawater. Design of experiment was used to design the experiment hence the number of samples required prior to experiment can be known. Apart from that it can be used to predict the outcome of the experiment hence it’s easier to come out with a conclusion. For linear polarization, the testing was done based on 3 factors which are salinity, temperature and immersion time. The highest corrosion rate for this testing is 1.6545 mm/year for the sample that has a salinity level of 33ppt, temperature of 25°C and immersion time of 4 days whereas the lowest corrosion rate is 0.00026 mm/year which has a salinity level of 38ppt, temperature of 35°C and immersion time of 2 days. Salinity and temperature factors have an inverse relation to corrosion rate while immersion time is directly proportional to the corrosion rate. For EIS the Nyquist plot play important roles in providing the corrosion rate, as the area plot of semicircle become larger, the corrosion rate will increase. From the testing, equivalent circuit model can be obtained.
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spelling usm.eprints-564352023-01-19T09:14:14Z http://eprints.usm.my/56435/ Electrochemical Characterization Of Tin Electrode In Synthetic Seawater Amanda Kwok, Si En T Technology TN Mining Engineering. Metallurgy Tin is a common element generally added to many materials to improve the corrosion resistance. This research studies the electrochemical behaviour of tin electrode in synthetic seawater using linear polarization, cyclic voltammetry and EIS and also to investigate the interaction effect of three factors, salinity, temperature and immersion time on the corrosion rate and polarization resistance. Linear polarization is done to study the corrosion rate and polarisation resistance obtained from Tafel plot. Cyclic voltammetry is done to measure the resulting current produced by the Sn electrochemical cell under different parameters of salinity, temperature and immersion time. EIS is used to analyse the chemical processes occurring at the site of the Sn electrode after immersion in synthetic seawater. Design of experiment was used to design the experiment hence the number of samples required prior to experiment can be known. Apart from that it can be used to predict the outcome of the experiment hence it’s easier to come out with a conclusion. For linear polarization, the testing was done based on 3 factors which are salinity, temperature and immersion time. The highest corrosion rate for this testing is 1.6545 mm/year for the sample that has a salinity level of 33ppt, temperature of 25°C and immersion time of 4 days whereas the lowest corrosion rate is 0.00026 mm/year which has a salinity level of 38ppt, temperature of 35°C and immersion time of 2 days. Salinity and temperature factors have an inverse relation to corrosion rate while immersion time is directly proportional to the corrosion rate. For EIS the Nyquist plot play important roles in providing the corrosion rate, as the area plot of semicircle become larger, the corrosion rate will increase. From the testing, equivalent circuit model can be obtained. Universiti Sains Malaysia 2022-08-19 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/56435/1/Electrochemical%20Characterization%20Of%20Tin%20Electrode%20In%20Synthetic%20Seawater_Amanda%20Kwok%20Si%20En.pdf Amanda Kwok, Si En (2022) Electrochemical Characterization Of Tin Electrode In Synthetic Seawater. Project Report. Universiti Sains Malaysia, Pusat Pengajian Kejuruteraan Bahan dan Sumber Mineral. (Submitted)
spellingShingle T Technology
TN Mining Engineering. Metallurgy
Amanda Kwok, Si En
Electrochemical Characterization Of Tin Electrode In Synthetic Seawater
title Electrochemical Characterization Of Tin Electrode In Synthetic Seawater
title_full Electrochemical Characterization Of Tin Electrode In Synthetic Seawater
title_fullStr Electrochemical Characterization Of Tin Electrode In Synthetic Seawater
title_full_unstemmed Electrochemical Characterization Of Tin Electrode In Synthetic Seawater
title_short Electrochemical Characterization Of Tin Electrode In Synthetic Seawater
title_sort electrochemical characterization of tin electrode in synthetic seawater
topic T Technology
TN Mining Engineering. Metallurgy
url http://eprints.usm.my/56435/1/Electrochemical%20Characterization%20Of%20Tin%20Electrode%20In%20Synthetic%20Seawater_Amanda%20Kwok%20Si%20En.pdf
work_keys_str_mv AT amandakwoksien electrochemicalcharacterizationoftinelectrodeinsyntheticseawater