Effects of argon/nitrogen sputtering gas on the microstructural, crystallographic and piezoelectric properties of AlN thin films

The growth of highly crystalline c-plane AlN 〈002〉 is extremely difficult, entailing high temperature and ultrahigh vacuum condition. In sputtering technique, the addition of nitrogen into argon sputtering gas can significantly assist the formation of AlN 〈002〉 at low temperature. We incorporated pu...

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Main Authors: Abd Samad, Muhammad Izzuddin, Mohd Noor, Mimiwaty, Nayan, Nafarizal, Abu Bakar, Ahmad Shuhaimi, Mansor, Marwan, Mahmood Zuhdi, Ahmad Wafi, Hamzah, Azrul Azlan, Latif, Rhonira
Format: Article
Language:English
Published: Elsevier 2023
Subjects:
Online Access:http://eprints.uthm.edu.my/10105/1/J16245_20d070df8d4da144f68593929aa9833e.pdf
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author Abd Samad, Muhammad Izzuddin
Mohd Noor, Mimiwaty
Nayan, Nafarizal
Abu Bakar, Ahmad Shuhaimi
Mansor, Marwan
Mahmood Zuhdi, Ahmad Wafi
Hamzah, Azrul Azlan
Latif, Rhonira
author_facet Abd Samad, Muhammad Izzuddin
Mohd Noor, Mimiwaty
Nayan, Nafarizal
Abu Bakar, Ahmad Shuhaimi
Mansor, Marwan
Mahmood Zuhdi, Ahmad Wafi
Hamzah, Azrul Azlan
Latif, Rhonira
author_sort Abd Samad, Muhammad Izzuddin
collection UTHM
description The growth of highly crystalline c-plane AlN 〈002〉 is extremely difficult, entailing high temperature and ultrahigh vacuum condition. In sputtering technique, the addition of nitrogen into argon sputtering gas can significantly assist the formation of AlN 〈002〉 at low temperature. We incorporated purified nitrogen gas and observed the consistent formation of single crystal 〈002〉 AlN thin film layer sputter-deposited on Mo/Si substrate from the AlN ceramic target. Small presence of oxygen content within AlN crystal relates to the preferential growth of AlN 〈002〉. High oxygen content in AlN thin film due to the use of unpurified nitrogen and argon only sputtering gas prefers the formation of AlN 〈100〉. Different AlN crystal structure has shown distinct thin film properties and piezoelectric response. This work provides a method to control the crystal structure of the sputter-deposited AlN thin film layer, either c-plane AlN 〈002〉, a-plane AlN 〈100〉 or polycrystalline AlN.
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spelling uthm.eprints-101052023-10-17T06:54:36Z http://eprints.uthm.edu.my/10105/ Effects of argon/nitrogen sputtering gas on the microstructural, crystallographic and piezoelectric properties of AlN thin films Abd Samad, Muhammad Izzuddin Mohd Noor, Mimiwaty Nayan, Nafarizal Abu Bakar, Ahmad Shuhaimi Mansor, Marwan Mahmood Zuhdi, Ahmad Wafi Hamzah, Azrul Azlan Latif, Rhonira TP Chemical technology The growth of highly crystalline c-plane AlN 〈002〉 is extremely difficult, entailing high temperature and ultrahigh vacuum condition. In sputtering technique, the addition of nitrogen into argon sputtering gas can significantly assist the formation of AlN 〈002〉 at low temperature. We incorporated purified nitrogen gas and observed the consistent formation of single crystal 〈002〉 AlN thin film layer sputter-deposited on Mo/Si substrate from the AlN ceramic target. Small presence of oxygen content within AlN crystal relates to the preferential growth of AlN 〈002〉. High oxygen content in AlN thin film due to the use of unpurified nitrogen and argon only sputtering gas prefers the formation of AlN 〈100〉. Different AlN crystal structure has shown distinct thin film properties and piezoelectric response. This work provides a method to control the crystal structure of the sputter-deposited AlN thin film layer, either c-plane AlN 〈002〉, a-plane AlN 〈100〉 or polycrystalline AlN. Elsevier 2023 Article PeerReviewed text en http://eprints.uthm.edu.my/10105/1/J16245_20d070df8d4da144f68593929aa9833e.pdf Abd Samad, Muhammad Izzuddin and Mohd Noor, Mimiwaty and Nayan, Nafarizal and Abu Bakar, Ahmad Shuhaimi and Mansor, Marwan and Mahmood Zuhdi, Ahmad Wafi and Hamzah, Azrul Azlan and Latif, Rhonira (2023) Effects of argon/nitrogen sputtering gas on the microstructural, crystallographic and piezoelectric properties of AlN thin films. Scripta Materialia, 226. pp. 1-7. https://doi.org/10.1016/j.scriptamat.2022.115228
spellingShingle TP Chemical technology
Abd Samad, Muhammad Izzuddin
Mohd Noor, Mimiwaty
Nayan, Nafarizal
Abu Bakar, Ahmad Shuhaimi
Mansor, Marwan
Mahmood Zuhdi, Ahmad Wafi
Hamzah, Azrul Azlan
Latif, Rhonira
Effects of argon/nitrogen sputtering gas on the microstructural, crystallographic and piezoelectric properties of AlN thin films
title Effects of argon/nitrogen sputtering gas on the microstructural, crystallographic and piezoelectric properties of AlN thin films
title_full Effects of argon/nitrogen sputtering gas on the microstructural, crystallographic and piezoelectric properties of AlN thin films
title_fullStr Effects of argon/nitrogen sputtering gas on the microstructural, crystallographic and piezoelectric properties of AlN thin films
title_full_unstemmed Effects of argon/nitrogen sputtering gas on the microstructural, crystallographic and piezoelectric properties of AlN thin films
title_short Effects of argon/nitrogen sputtering gas on the microstructural, crystallographic and piezoelectric properties of AlN thin films
title_sort effects of argon nitrogen sputtering gas on the microstructural crystallographic and piezoelectric properties of aln thin films
topic TP Chemical technology
url http://eprints.uthm.edu.my/10105/1/J16245_20d070df8d4da144f68593929aa9833e.pdf
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