Recent progress in ceria-based catalysts for the dry reforming of methane: a review

The mitigation of CO2 and CH4 emissions is feasible by transforming them into valuable syngas via the dry reforming of methane (DRM). However, the problem of catalyst deactivation has restricted its industrial application. Therefore, the development of catalysts for an effective reforming process...

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Main Authors: L. P., Teh, H. D., Setiabudi, S. N., Timmiati, M. A. A., Aziz, N. H. R., Annuar, N. N., Ruslan
Format: Article
Language:English
Published: Elsevier 2021
Subjects:
Online Access:http://eprints.uthm.edu.my/2427/1/J12384_b426494419a20760a0347fa983316d15.pdf
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author L. P., Teh
H. D., Setiabudi
S. N., Timmiati
M. A. A., Aziz
N. H. R., Annuar
N. N., Ruslan
author_facet L. P., Teh
H. D., Setiabudi
S. N., Timmiati
M. A. A., Aziz
N. H. R., Annuar
N. N., Ruslan
author_sort L. P., Teh
collection UTHM
description The mitigation of CO2 and CH4 emissions is feasible by transforming them into valuable syngas via the dry reforming of methane (DRM). However, the problem of catalyst deactivation has restricted its industrial application. Therefore, the development of catalysts for an effective reforming process has been attracted enormous attention. Ceria has a high potential as it can serve as both catalyst support and metal active site for adsorption and dissociation of CO2 and CH4. Material properties, such as redox and acid/base properties, and oxygen storage capacity, greatly affect catalytic behavior and performance, as well as coke inhibition in the DRM. This review aims to provide an up-to-date summary on the DRM over ceria-based catalysts, including aspects of the catalysts, reaction mechanism, deactivation, and regeneration studies. This review also proposes governing factors and new ways for improving the process, to provide a more rational to designing an ideal ceria-based catalyst for DRM.
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spelling uthm.eprints-24272021-10-20T03:09:08Z http://eprints.uthm.edu.my/2427/ Recent progress in ceria-based catalysts for the dry reforming of methane: a review L. P., Teh H. D., Setiabudi S. N., Timmiati M. A. A., Aziz N. H. R., Annuar N. N., Ruslan TP248.13-248.65 Biotechnology The mitigation of CO2 and CH4 emissions is feasible by transforming them into valuable syngas via the dry reforming of methane (DRM). However, the problem of catalyst deactivation has restricted its industrial application. Therefore, the development of catalysts for an effective reforming process has been attracted enormous attention. Ceria has a high potential as it can serve as both catalyst support and metal active site for adsorption and dissociation of CO2 and CH4. Material properties, such as redox and acid/base properties, and oxygen storage capacity, greatly affect catalytic behavior and performance, as well as coke inhibition in the DRM. This review aims to provide an up-to-date summary on the DRM over ceria-based catalysts, including aspects of the catalysts, reaction mechanism, deactivation, and regeneration studies. This review also proposes governing factors and new ways for improving the process, to provide a more rational to designing an ideal ceria-based catalyst for DRM. Elsevier 2021 Article PeerReviewed text en http://eprints.uthm.edu.my/2427/1/J12384_b426494419a20760a0347fa983316d15.pdf L. P., Teh and H. D., Setiabudi and S. N., Timmiati and M. A. A., Aziz and N. H. R., Annuar and N. N., Ruslan (2021) Recent progress in ceria-based catalysts for the dry reforming of methane: a review. Chemical Engineering Science, 242. pp. 1-17. ISSN 0009-2509 https://doi.org/10.1016/j.ces.2021.116606
spellingShingle TP248.13-248.65 Biotechnology
L. P., Teh
H. D., Setiabudi
S. N., Timmiati
M. A. A., Aziz
N. H. R., Annuar
N. N., Ruslan
Recent progress in ceria-based catalysts for the dry reforming of methane: a review
title Recent progress in ceria-based catalysts for the dry reforming of methane: a review
title_full Recent progress in ceria-based catalysts for the dry reforming of methane: a review
title_fullStr Recent progress in ceria-based catalysts for the dry reforming of methane: a review
title_full_unstemmed Recent progress in ceria-based catalysts for the dry reforming of methane: a review
title_short Recent progress in ceria-based catalysts for the dry reforming of methane: a review
title_sort recent progress in ceria based catalysts for the dry reforming of methane a review
topic TP248.13-248.65 Biotechnology
url http://eprints.uthm.edu.my/2427/1/J12384_b426494419a20760a0347fa983316d15.pdf
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