Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud

In this study, calcined Lapindo volcanic mud (LVM) was used as an adsorbent to remove an anionic dye, methyl orange (MO), from an aqueous solution by the batch adsorption technique. Various conditions were evaluated, including initial dye concentration, adsorbent dosage, contact time, solution pH, a...

Full description

Bibliographic Details
Main Authors: A. Jalil, Aishah, Triwahyono, Sugeng, Adam, S. Hazirah, Rahim, N. Diana, A. Aziz, M. Arif, Hairom, Nur Hanis Hayati, M. Razali, N. Aini, A.Z. Abidin, Mahani, A. Mohamadiah, M. Khairul
Format: Article
Language:English
Published: Elsevier 2010
Subjects:
Online Access:http://eprints.uthm.edu.my/3364/1/AJ%202019%20%28122%29.pdf
_version_ 1796868823573331968
author A. Jalil, Aishah
Triwahyono, Sugeng
Adam, S. Hazirah
Rahim, N. Diana
A. Aziz, M. Arif
Hairom, Nur Hanis Hayati
M. Razali, N. Aini
A.Z. Abidin, Mahani
A. Mohamadiah, M. Khairul
author_facet A. Jalil, Aishah
Triwahyono, Sugeng
Adam, S. Hazirah
Rahim, N. Diana
A. Aziz, M. Arif
Hairom, Nur Hanis Hayati
M. Razali, N. Aini
A.Z. Abidin, Mahani
A. Mohamadiah, M. Khairul
author_sort A. Jalil, Aishah
collection UTHM
description In this study, calcined Lapindo volcanic mud (LVM) was used as an adsorbent to remove an anionic dye, methyl orange (MO), from an aqueous solution by the batch adsorption technique. Various conditions were evaluated, including initial dye concentration, adsorbent dosage, contact time, solution pH, and temperature. The adsorption kinetics and equilibrium isotherms of the LVM were studied using pseudofirst- order and -second-order kinetic equations, as well as the Freundlich and Langmuir models. The experimental data obtained withLVMfits best to the Langmuir isotherm model and exhibited amaximum adsorption capacity (qmax) of 333.3mgg−1; the data followed the second-order equation. The intraparticle diffusion studies revealed that the adsorption rates were not controlled only by the diffusion step. The thermodynamic parameters, such as the changes in enthalpy, entropy, and Gibbs free energy, showed that the adsorption is endothermic, random and spontaneous at high temperature. The results indicate that LVM adsorbsMOefficiently and could be utilized as a low-cost alternative adsorbent for the removal of anionic dyes in wastewater treatment.
first_indexed 2024-03-05T21:45:36Z
format Article
id uthm.eprints-3364
institution Universiti Tun Hussein Onn Malaysia
language English
last_indexed 2024-03-05T21:45:36Z
publishDate 2010
publisher Elsevier
record_format dspace
spelling uthm.eprints-33642021-11-17T01:06:37Z http://eprints.uthm.edu.my/3364/ Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud A. Jalil, Aishah Triwahyono, Sugeng Adam, S. Hazirah Rahim, N. Diana A. Aziz, M. Arif Hairom, Nur Hanis Hayati M. Razali, N. Aini A.Z. Abidin, Mahani A. Mohamadiah, M. Khairul TP155-156 Chemical engineering In this study, calcined Lapindo volcanic mud (LVM) was used as an adsorbent to remove an anionic dye, methyl orange (MO), from an aqueous solution by the batch adsorption technique. Various conditions were evaluated, including initial dye concentration, adsorbent dosage, contact time, solution pH, and temperature. The adsorption kinetics and equilibrium isotherms of the LVM were studied using pseudofirst- order and -second-order kinetic equations, as well as the Freundlich and Langmuir models. The experimental data obtained withLVMfits best to the Langmuir isotherm model and exhibited amaximum adsorption capacity (qmax) of 333.3mgg−1; the data followed the second-order equation. The intraparticle diffusion studies revealed that the adsorption rates were not controlled only by the diffusion step. The thermodynamic parameters, such as the changes in enthalpy, entropy, and Gibbs free energy, showed that the adsorption is endothermic, random and spontaneous at high temperature. The results indicate that LVM adsorbsMOefficiently and could be utilized as a low-cost alternative adsorbent for the removal of anionic dyes in wastewater treatment. Elsevier 2010 Article PeerReviewed text en http://eprints.uthm.edu.my/3364/1/AJ%202019%20%28122%29.pdf A. Jalil, Aishah and Triwahyono, Sugeng and Adam, S. Hazirah and Rahim, N. Diana and A. Aziz, M. Arif and Hairom, Nur Hanis Hayati and M. Razali, N. Aini and A.Z. Abidin, Mahani and A. Mohamadiah, M. Khairul (2010) Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud. Journal of Hazardous Materials, 181 (1-3). pp. 755-762. ISSN 0304-3894 https://doi.org/10.1016/j.jhazmat.2010.05.078
spellingShingle TP155-156 Chemical engineering
A. Jalil, Aishah
Triwahyono, Sugeng
Adam, S. Hazirah
Rahim, N. Diana
A. Aziz, M. Arif
Hairom, Nur Hanis Hayati
M. Razali, N. Aini
A.Z. Abidin, Mahani
A. Mohamadiah, M. Khairul
Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title_full Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title_fullStr Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title_full_unstemmed Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title_short Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title_sort adsorption of methyl orange from aqueous solution onto calcined lapindo volcanic mud
topic TP155-156 Chemical engineering
url http://eprints.uthm.edu.my/3364/1/AJ%202019%20%28122%29.pdf
work_keys_str_mv AT ajalilaishah adsorptionofmethylorangefromaqueoussolutionontocalcinedlapindovolcanicmud
AT triwahyonosugeng adsorptionofmethylorangefromaqueoussolutionontocalcinedlapindovolcanicmud
AT adamshazirah adsorptionofmethylorangefromaqueoussolutionontocalcinedlapindovolcanicmud
AT rahimndiana adsorptionofmethylorangefromaqueoussolutionontocalcinedlapindovolcanicmud
AT aazizmarif adsorptionofmethylorangefromaqueoussolutionontocalcinedlapindovolcanicmud
AT hairomnurhanishayati adsorptionofmethylorangefromaqueoussolutionontocalcinedlapindovolcanicmud
AT mrazalinaini adsorptionofmethylorangefromaqueoussolutionontocalcinedlapindovolcanicmud
AT azabidinmahani adsorptionofmethylorangefromaqueoussolutionontocalcinedlapindovolcanicmud
AT amohamadiahmkhairul adsorptionofmethylorangefromaqueoussolutionontocalcinedlapindovolcanicmud