The effect of gamma irradiation on chemical, morphology and optical properties of polystyrene nanosphere at various exposure time

Irradiation of polymers causes structural, chemical and the optical properties changes. Polystyrene nanosphere was drop coated to substrates and the gamma irradiation was carried out in a Cesium-137 (Cs-137) source chamber at different time (1-5 hours) with constant dose of 30 kGy. Fourier transform...

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Main Authors: Yabagi, Jibrin Alhaji, Kimpa, Mohammed Isah, Muhammad, Muhammad Nmayaya, Rashid, Saiful, Embong, Zaidi, Agam, Mohd Arif
Format: Article
Language:English
Published: IOP Publishing 2017
Subjects:
Online Access:http://eprints.uthm.edu.my/4860/1/AJ%202017%20%28679%29.pdf
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author Yabagi, Jibrin Alhaji
Kimpa, Mohammed Isah
Muhammad, Muhammad Nmayaya
Rashid, Saiful
Embong, Zaidi
Agam, Mohd Arif
author_facet Yabagi, Jibrin Alhaji
Kimpa, Mohammed Isah
Muhammad, Muhammad Nmayaya
Rashid, Saiful
Embong, Zaidi
Agam, Mohd Arif
author_sort Yabagi, Jibrin Alhaji
collection UTHM
description Irradiation of polymers causes structural, chemical and the optical properties changes. Polystyrene nanosphere was drop coated to substrates and the gamma irradiation was carried out in a Cesium-137 (Cs-137) source chamber at different time (1-5 hours) with constant dose of 30 kGy. Fourier transformation infrared spectroscopy (FTIR) and Raman spectroscopy were employed to characterize the chemical properties of irradiated polystyrene while Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM) were used to study the surface morphological changes of the samples. The optical energy band gaps of the thin films were investigated and studied using transmittance and absorbance measurements. The results obtained revealed that as irradiation time increases the optical properties changes and polystyrene gradually undergoes crystal to carbonaceous from its amorphous state. The average particles diameter and roughness of the samples decreases with increasing irradiation time.
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spelling uthm.eprints-48602021-12-23T03:23:41Z http://eprints.uthm.edu.my/4860/ The effect of gamma irradiation on chemical, morphology and optical properties of polystyrene nanosphere at various exposure time Yabagi, Jibrin Alhaji Kimpa, Mohammed Isah Muhammad, Muhammad Nmayaya Rashid, Saiful Embong, Zaidi Agam, Mohd Arif Q Science (General) TP1080-1185 Polymers and polymer manufacture Irradiation of polymers causes structural, chemical and the optical properties changes. Polystyrene nanosphere was drop coated to substrates and the gamma irradiation was carried out in a Cesium-137 (Cs-137) source chamber at different time (1-5 hours) with constant dose of 30 kGy. Fourier transformation infrared spectroscopy (FTIR) and Raman spectroscopy were employed to characterize the chemical properties of irradiated polystyrene while Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM) were used to study the surface morphological changes of the samples. The optical energy band gaps of the thin films were investigated and studied using transmittance and absorbance measurements. The results obtained revealed that as irradiation time increases the optical properties changes and polystyrene gradually undergoes crystal to carbonaceous from its amorphous state. The average particles diameter and roughness of the samples decreases with increasing irradiation time. IOP Publishing 2017 Article PeerReviewed text en http://eprints.uthm.edu.my/4860/1/AJ%202017%20%28679%29.pdf Yabagi, Jibrin Alhaji and Kimpa, Mohammed Isah and Muhammad, Muhammad Nmayaya and Rashid, Saiful and Embong, Zaidi and Agam, Mohd Arif (2017) The effect of gamma irradiation on chemical, morphology and optical properties of polystyrene nanosphere at various exposure time. IOP Conference Series: Materials Science and Engineering, 298 (1). pp. 1-11. ISSN 1757-899X https://dx.doi.org/10.1088/1757-899X/298/1/012004
spellingShingle Q Science (General)
TP1080-1185 Polymers and polymer manufacture
Yabagi, Jibrin Alhaji
Kimpa, Mohammed Isah
Muhammad, Muhammad Nmayaya
Rashid, Saiful
Embong, Zaidi
Agam, Mohd Arif
The effect of gamma irradiation on chemical, morphology and optical properties of polystyrene nanosphere at various exposure time
title The effect of gamma irradiation on chemical, morphology and optical properties of polystyrene nanosphere at various exposure time
title_full The effect of gamma irradiation on chemical, morphology and optical properties of polystyrene nanosphere at various exposure time
title_fullStr The effect of gamma irradiation on chemical, morphology and optical properties of polystyrene nanosphere at various exposure time
title_full_unstemmed The effect of gamma irradiation on chemical, morphology and optical properties of polystyrene nanosphere at various exposure time
title_short The effect of gamma irradiation on chemical, morphology and optical properties of polystyrene nanosphere at various exposure time
title_sort effect of gamma irradiation on chemical morphology and optical properties of polystyrene nanosphere at various exposure time
topic Q Science (General)
TP1080-1185 Polymers and polymer manufacture
url http://eprints.uthm.edu.my/4860/1/AJ%202017%20%28679%29.pdf
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