Ibuprofen removal through photocatalytic filtration using antifouling PVDF- ZnO/Ag2CO3/Ag2O nanocomposite membrane
The in-situ phase transformation of Ag2CO3/Ag2O heterojunction over ZnO was synthesized via a facile two-step synthesis method and immobilized in poly (vinylidene fluoride) (PVDF) membrane via a phase inversion process to obtain a novel photocatalytic membrane (PM) for ibuprofen (IBU) removal. The...
| Main Authors: | , , , , , , , , |
|---|---|
| Format: | Other |
| Language: | English |
| Published: |
Elsevier
2021
|
| Subjects: | |
| Online Access: | http://eprints.uthm.edu.my/6655/1/P13069_a2540f59d49a47bfe6a07975c056b1a0.pdf |
| _version_ | 1796869407478120448 |
|---|---|
| author | Rosman, Nurafiqah Wan Salleh, Wan Norharyati Mohd Razali, Nur Aqilah Ahmad, Siti Zu Nurain Ismail, Nor Hafiza Aziz, Farhana Harun, Zawati Ismail, Ahmad Fauzi Yusof, Norhaniza |
| author_facet | Rosman, Nurafiqah Wan Salleh, Wan Norharyati Mohd Razali, Nur Aqilah Ahmad, Siti Zu Nurain Ismail, Nor Hafiza Aziz, Farhana Harun, Zawati Ismail, Ahmad Fauzi Yusof, Norhaniza |
| author_sort | Rosman, Nurafiqah |
| collection | UTHM |
| description | The in-situ phase transformation of Ag2CO3/Ag2O heterojunction over ZnO was synthesized via a facile
two-step synthesis method and immobilized in poly (vinylidene fluoride) (PVDF) membrane via a phase
inversion process to obtain a novel photocatalytic membrane (PM) for ibuprofen (IBU) removal. The
visible-light-driven PVDF ZnO/Ag2CO3/Ag2O membrane possessed a great extent altering its morpholog�ical and wettability properties. The structural characteristics and antifouling property of PMs with the
presence of ZnO/Ag2CO3/Ag2O were systematically investigated. The performance analysis indicated that
PVDF–ZnO/Ag2CO3/Ag2O showed a higher IBU percentage removal of 27.37% in dark condition. However,
as the PVDF–ZnO/Ag2CO3/Ag2O membrane irradiated with visible light, the synergistic effects accom�plished by both, membrane filtration and photocatalysis have significantly enhanced the IBU removal
efficacy compared with that via filtration alone, exhibited 35.27% of IBU removal. The photocatalytic
activity has remarkably reduced the fouling susceptibility of PVDF–ZnO/Ag2CO3/Ag2O membranes, where
the relative flux had reached a relative stable plateau under visible light irradiation after the collection of
150 mL of permeate with 46.85% of flux loss. With its promising performance in terms of IBU removal,
flux and low membrane fouling susceptibility, this PM holds great potential for its application in pharma�ceutical wastewater treatment. |
| first_indexed | 2024-03-05T21:54:26Z |
| format | Other |
| id | uthm.eprints-6655 |
| institution | Universiti Tun Hussein Onn Malaysia |
| language | English |
| last_indexed | 2024-03-05T21:54:26Z |
| publishDate | 2021 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | uthm.eprints-66552022-03-14T01:33:37Z http://eprints.uthm.edu.my/6655/ Ibuprofen removal through photocatalytic filtration using antifouling PVDF- ZnO/Ag2CO3/Ag2O nanocomposite membrane Rosman, Nurafiqah Wan Salleh, Wan Norharyati Mohd Razali, Nur Aqilah Ahmad, Siti Zu Nurain Ismail, Nor Hafiza Aziz, Farhana Harun, Zawati Ismail, Ahmad Fauzi Yusof, Norhaniza TP200-248 Chemicals: Manufacture, use, etc. The in-situ phase transformation of Ag2CO3/Ag2O heterojunction over ZnO was synthesized via a facile two-step synthesis method and immobilized in poly (vinylidene fluoride) (PVDF) membrane via a phase inversion process to obtain a novel photocatalytic membrane (PM) for ibuprofen (IBU) removal. The visible-light-driven PVDF ZnO/Ag2CO3/Ag2O membrane possessed a great extent altering its morpholog�ical and wettability properties. The structural characteristics and antifouling property of PMs with the presence of ZnO/Ag2CO3/Ag2O were systematically investigated. The performance analysis indicated that PVDF–ZnO/Ag2CO3/Ag2O showed a higher IBU percentage removal of 27.37% in dark condition. However, as the PVDF–ZnO/Ag2CO3/Ag2O membrane irradiated with visible light, the synergistic effects accom�plished by both, membrane filtration and photocatalysis have significantly enhanced the IBU removal efficacy compared with that via filtration alone, exhibited 35.27% of IBU removal. The photocatalytic activity has remarkably reduced the fouling susceptibility of PVDF–ZnO/Ag2CO3/Ag2O membranes, where the relative flux had reached a relative stable plateau under visible light irradiation after the collection of 150 mL of permeate with 46.85% of flux loss. With its promising performance in terms of IBU removal, flux and low membrane fouling susceptibility, this PM holds great potential for its application in pharma�ceutical wastewater treatment. Elsevier 2021 Other NonPeerReviewed text en http://eprints.uthm.edu.my/6655/1/P13069_a2540f59d49a47bfe6a07975c056b1a0.pdf Rosman, Nurafiqah and Wan Salleh, Wan Norharyati and Mohd Razali, Nur Aqilah and Ahmad, Siti Zu Nurain and Ismail, Nor Hafiza and Aziz, Farhana and Harun, Zawati and Ismail, Ahmad Fauzi and Yusof, Norhaniza (2021) Ibuprofen removal through photocatalytic filtration using antifouling PVDF- ZnO/Ag2CO3/Ag2O nanocomposite membrane. Elsevier. https://doi.org/10.1016/j.matpr.2020.09.476 |
| spellingShingle | TP200-248 Chemicals: Manufacture, use, etc. Rosman, Nurafiqah Wan Salleh, Wan Norharyati Mohd Razali, Nur Aqilah Ahmad, Siti Zu Nurain Ismail, Nor Hafiza Aziz, Farhana Harun, Zawati Ismail, Ahmad Fauzi Yusof, Norhaniza Ibuprofen removal through photocatalytic filtration using antifouling PVDF- ZnO/Ag2CO3/Ag2O nanocomposite membrane |
| title | Ibuprofen removal through photocatalytic filtration using antifouling PVDF- ZnO/Ag2CO3/Ag2O nanocomposite membrane |
| title_full | Ibuprofen removal through photocatalytic filtration using antifouling PVDF- ZnO/Ag2CO3/Ag2O nanocomposite membrane |
| title_fullStr | Ibuprofen removal through photocatalytic filtration using antifouling PVDF- ZnO/Ag2CO3/Ag2O nanocomposite membrane |
| title_full_unstemmed | Ibuprofen removal through photocatalytic filtration using antifouling PVDF- ZnO/Ag2CO3/Ag2O nanocomposite membrane |
| title_short | Ibuprofen removal through photocatalytic filtration using antifouling PVDF- ZnO/Ag2CO3/Ag2O nanocomposite membrane |
| title_sort | ibuprofen removal through photocatalytic filtration using antifouling pvdf zno ag2co3 ag2o nanocomposite membrane |
| topic | TP200-248 Chemicals: Manufacture, use, etc. |
| url | http://eprints.uthm.edu.my/6655/1/P13069_a2540f59d49a47bfe6a07975c056b1a0.pdf |
| work_keys_str_mv | AT rosmannurafiqah ibuprofenremovalthroughphotocatalyticfiltrationusingantifoulingpvdfznoag2co3ag2onanocompositemembrane AT wansallehwannorharyati ibuprofenremovalthroughphotocatalyticfiltrationusingantifoulingpvdfznoag2co3ag2onanocompositemembrane AT mohdrazalinuraqilah ibuprofenremovalthroughphotocatalyticfiltrationusingantifoulingpvdfznoag2co3ag2onanocompositemembrane AT ahmadsitizunurain ibuprofenremovalthroughphotocatalyticfiltrationusingantifoulingpvdfznoag2co3ag2onanocompositemembrane AT ismailnorhafiza ibuprofenremovalthroughphotocatalyticfiltrationusingantifoulingpvdfznoag2co3ag2onanocompositemembrane AT azizfarhana ibuprofenremovalthroughphotocatalyticfiltrationusingantifoulingpvdfznoag2co3ag2onanocompositemembrane AT harunzawati ibuprofenremovalthroughphotocatalyticfiltrationusingantifoulingpvdfznoag2co3ag2onanocompositemembrane AT ismailahmadfauzi ibuprofenremovalthroughphotocatalyticfiltrationusingantifoulingpvdfznoag2co3ag2onanocompositemembrane AT yusofnorhaniza ibuprofenremovalthroughphotocatalyticfiltrationusingantifoulingpvdfznoag2co3ag2onanocompositemembrane |