Characterization and review of dual composite cathodes LSCF-SDC/YSZ-SDC for intermediate to low temperature solid oxide fuel cel
Solid oxide fuel cell (SOFC) performance is highly dictated by the ohmic loss of the electrolyte and the resistance due to the cathodic polarization. To reduce the large polarization losses, dual composite cathodes have been introduced. The objectives of this research are to fabricate the LSCF...
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Format: | Other |
Language: | English |
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Penerbit UTHM
2021
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Online Access: | http://eprints.uthm.edu.my/6665/1/P13753_0b4c29a4680839aeecbc6a28690fb32a.pdf |
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author | Shaifull Zaman, Sharmine Wani Zakirah |
author_facet | Shaifull Zaman, Sharmine Wani Zakirah |
author_sort | Shaifull Zaman, Sharmine Wani Zakirah |
collection | UTHM |
description | Solid oxide fuel cell (SOFC) performance is highly dictated by the ohmic
loss of the electrolyte and the resistance due to the cathodic polarization. To reduce
the large polarization losses, dual composite cathodes have been introduced. The
objectives of this research are to fabricate the LSCF-SDCC/YSZ-SDCC and LSCF�SDC/YSZ-SDC dual composite cathodes powders via ball milling process and
evaluate the influence of dual cathode composition and carbonate on the
characteristics on physical, morphology and chemical bonding of cathode. In this
study, the cathode composite powder is developed from mixture of YSZ-SDC
electrolyte powders will be mixed with various ratio 50:50, 60:40 and 70:30 wt%.
Powder mixing was done through ball milling method. After mixing, YSZ-SDC
electrolyte powders were calcined at 950℃. The morphology of YSZ-SDC powder
showed intergranular pores textures are observed at the contact of YSZ and SDC due
to SDC lower melting point compared to YSZ which made SDC easily diffuse into
YSZ. No additional phase formation is presented in XRD patterns which indicates
that there are no crystalline impurities. There is no other chemical bond pattern on
side A and B such as carbon. Therefore, YSZ-SDC combination will work together
to improve the SOFC conductivity and it is expected to allow the cell operates at
intermediate to low temperature. |
first_indexed | 2024-03-05T21:54:27Z |
format | Other |
id | uthm.eprints-6665 |
institution | Universiti Tun Hussein Onn Malaysia |
language | English |
last_indexed | 2024-03-05T21:54:27Z |
publishDate | 2021 |
publisher | Penerbit UTHM |
record_format | dspace |
spelling | uthm.eprints-66652022-03-14T01:43:08Z http://eprints.uthm.edu.my/6665/ Characterization and review of dual composite cathodes LSCF-SDC/YSZ-SDC for intermediate to low temperature solid oxide fuel cel Shaifull Zaman, Sharmine Wani Zakirah TP Chemical technology Solid oxide fuel cell (SOFC) performance is highly dictated by the ohmic loss of the electrolyte and the resistance due to the cathodic polarization. To reduce the large polarization losses, dual composite cathodes have been introduced. The objectives of this research are to fabricate the LSCF-SDCC/YSZ-SDCC and LSCF�SDC/YSZ-SDC dual composite cathodes powders via ball milling process and evaluate the influence of dual cathode composition and carbonate on the characteristics on physical, morphology and chemical bonding of cathode. In this study, the cathode composite powder is developed from mixture of YSZ-SDC electrolyte powders will be mixed with various ratio 50:50, 60:40 and 70:30 wt%. Powder mixing was done through ball milling method. After mixing, YSZ-SDC electrolyte powders were calcined at 950℃. The morphology of YSZ-SDC powder showed intergranular pores textures are observed at the contact of YSZ and SDC due to SDC lower melting point compared to YSZ which made SDC easily diffuse into YSZ. No additional phase formation is presented in XRD patterns which indicates that there are no crystalline impurities. There is no other chemical bond pattern on side A and B such as carbon. Therefore, YSZ-SDC combination will work together to improve the SOFC conductivity and it is expected to allow the cell operates at intermediate to low temperature. Penerbit UTHM 2021 Other NonPeerReviewed text en http://eprints.uthm.edu.my/6665/1/P13753_0b4c29a4680839aeecbc6a28690fb32a.pdf Shaifull Zaman, Sharmine Wani Zakirah and UNSPECIFIED (2021) Characterization and review of dual composite cathodes LSCF-SDC/YSZ-SDC for intermediate to low temperature solid oxide fuel cel. Penerbit UTHM, UTHM. https://doi.org/10.30880/rpmme.2021.02.02.001 |
spellingShingle | TP Chemical technology Shaifull Zaman, Sharmine Wani Zakirah Characterization and review of dual composite cathodes LSCF-SDC/YSZ-SDC for intermediate to low temperature solid oxide fuel cel |
title | Characterization and review of dual composite cathodes LSCF-SDC/YSZ-SDC for intermediate to low temperature solid oxide fuel cel |
title_full | Characterization and review of dual composite cathodes LSCF-SDC/YSZ-SDC for intermediate to low temperature solid oxide fuel cel |
title_fullStr | Characterization and review of dual composite cathodes LSCF-SDC/YSZ-SDC for intermediate to low temperature solid oxide fuel cel |
title_full_unstemmed | Characterization and review of dual composite cathodes LSCF-SDC/YSZ-SDC for intermediate to low temperature solid oxide fuel cel |
title_short | Characterization and review of dual composite cathodes LSCF-SDC/YSZ-SDC for intermediate to low temperature solid oxide fuel cel |
title_sort | characterization and review of dual composite cathodes lscf sdc ysz sdc for intermediate to low temperature solid oxide fuel cel |
topic | TP Chemical technology |
url | http://eprints.uthm.edu.my/6665/1/P13753_0b4c29a4680839aeecbc6a28690fb32a.pdf |
work_keys_str_mv | AT shaifullzamansharminewanizakirah characterizationandreviewofdualcompositecathodeslscfsdcyszsdcforintermediatetolowtemperaturesolidoxidefuelcel AT characterizationandreviewofdualcompositecathodeslscfsdcyszsdcforintermediatetolowtemperaturesolidoxidefuelcel |