New ray on remediation of high rings polycyclic aromatic hydrocarbons: remediation of raw petroleum sludge using solidification and stabilization method
Solidification/Stabilization (S/S) method with cement as a binder to remediate metals in petroleum sludge has been suc�cessfully proven. However, this technique has not yet been explored to remediate organic contaminants since a high concentra�tion of Total Petroleum Hydrocarbon (TPH) was also detec...
Main Authors: | , , , , , , |
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Format: | Article |
Language: | English |
Published: |
2022
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Subjects: | |
Online Access: | http://eprints.uthm.edu.my/7572/1/J14500_49ab8dc4ed2f712a714ee6e0272c42b4.pdf |
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author | Roslee, Noor Faiza Mohd Kamil, Nor Amani Filzah Abdul Kadir, Aeslina Jalil, Abdul Rahim Hamzah, Nurhidayah Mohamed Noor, Norazian Sandu, Andrei Victor |
author_facet | Roslee, Noor Faiza Mohd Kamil, Nor Amani Filzah Abdul Kadir, Aeslina Jalil, Abdul Rahim Hamzah, Nurhidayah Mohamed Noor, Norazian Sandu, Andrei Victor |
author_sort | Roslee, Noor Faiza |
collection | UTHM |
description | Solidification/Stabilization (S/S) method with cement as a binder to remediate metals in petroleum sludge has been suc�cessfully proven. However, this technique has not yet been explored to remediate organic contaminants since a high concentra�tion of Total Petroleum Hydrocarbon (TPH) was also detected in the sludge. This study focuses on remediating 16 Polycyclic
Aromatic Hydrocarbons (PAHs) compounds in raw petroleum sludge with Portland cement as a binder using the S/S method.
The initial concentration of 16 PAHs in the raw sludge was first measured before the performance of the S/S method to remedi�ate the PAHs were evaluated. The S/S matrices were tested for leaching behavior and strength after 7 and 28 days by air cur�ing. The leaching test was measured using the Toxicity Characteristics Leaching Procedure (TCLP), and the remaining PAHs
concentration in the matrices was analyzed using a Gas Chromatography-Mass Spectrometer (GC-MS). In the raw sludge, all
16 PAHs compounds were below the standard limit except for Benzo(a)anthracene, Benzo(a)pyrene, Dibenzo(ah)anthracene, and
Indeno(1,2,3- cd_ pyrene), which are considered as high rings PAHs. The high rings PAHs show lower concentration in leachate
than low rings PAHs, which indicates the potential of the S/S method in remediating high rings PAHs. The high sludge ratio in
S/S matrices has shown that the percentage strength is increasing, similar to Portland cement. Therefore, this study contributed
to the possibility of the S/S method in the remediation of PAHs in petroleum sludge by using only Portland cement as a binder. |
first_indexed | 2024-03-05T21:57:07Z |
format | Article |
id | uthm.eprints-7572 |
institution | Universiti Tun Hussein Onn Malaysia |
language | English |
last_indexed | 2024-03-05T21:57:07Z |
publishDate | 2022 |
record_format | dspace |
spelling | uthm.eprints-75722022-08-29T07:33:13Z http://eprints.uthm.edu.my/7572/ New ray on remediation of high rings polycyclic aromatic hydrocarbons: remediation of raw petroleum sludge using solidification and stabilization method Roslee, Noor Faiza Mohd Kamil, Nor Amani Filzah Abdul Kadir, Aeslina Jalil, Abdul Rahim Hamzah, Nurhidayah Mohamed Noor, Norazian Sandu, Andrei Victor T Technology (General) Solidification/Stabilization (S/S) method with cement as a binder to remediate metals in petroleum sludge has been suc�cessfully proven. However, this technique has not yet been explored to remediate organic contaminants since a high concentra�tion of Total Petroleum Hydrocarbon (TPH) was also detected in the sludge. This study focuses on remediating 16 Polycyclic Aromatic Hydrocarbons (PAHs) compounds in raw petroleum sludge with Portland cement as a binder using the S/S method. The initial concentration of 16 PAHs in the raw sludge was first measured before the performance of the S/S method to remedi�ate the PAHs were evaluated. The S/S matrices were tested for leaching behavior and strength after 7 and 28 days by air cur�ing. The leaching test was measured using the Toxicity Characteristics Leaching Procedure (TCLP), and the remaining PAHs concentration in the matrices was analyzed using a Gas Chromatography-Mass Spectrometer (GC-MS). In the raw sludge, all 16 PAHs compounds were below the standard limit except for Benzo(a)anthracene, Benzo(a)pyrene, Dibenzo(ah)anthracene, and Indeno(1,2,3- cd_ pyrene), which are considered as high rings PAHs. The high rings PAHs show lower concentration in leachate than low rings PAHs, which indicates the potential of the S/S method in remediating high rings PAHs. The high sludge ratio in S/S matrices has shown that the percentage strength is increasing, similar to Portland cement. Therefore, this study contributed to the possibility of the S/S method in the remediation of PAHs in petroleum sludge by using only Portland cement as a binder. 2022 Article PeerReviewed text en http://eprints.uthm.edu.my/7572/1/J14500_49ab8dc4ed2f712a714ee6e0272c42b4.pdf Roslee, Noor Faiza and Mohd Kamil, Nor Amani Filzah and Abdul Kadir, Aeslina and Jalil, Abdul Rahim and Hamzah, Nurhidayah and Mohamed Noor, Norazian and Sandu, Andrei Victor (2022) New ray on remediation of high rings polycyclic aromatic hydrocarbons: remediation of raw petroleum sludge using solidification and stabilization method. Arch. Metall, 67 (4). pp. 1201-1208. https://doi.org/10.24425/amm.2022.141043 |
spellingShingle | T Technology (General) Roslee, Noor Faiza Mohd Kamil, Nor Amani Filzah Abdul Kadir, Aeslina Jalil, Abdul Rahim Hamzah, Nurhidayah Mohamed Noor, Norazian Sandu, Andrei Victor New ray on remediation of high rings polycyclic aromatic hydrocarbons: remediation of raw petroleum sludge using solidification and stabilization method |
title | New ray on remediation of high rings polycyclic aromatic hydrocarbons: remediation of raw petroleum sludge using solidification and stabilization method |
title_full | New ray on remediation of high rings polycyclic aromatic hydrocarbons: remediation of raw petroleum sludge using solidification and stabilization method |
title_fullStr | New ray on remediation of high rings polycyclic aromatic hydrocarbons: remediation of raw petroleum sludge using solidification and stabilization method |
title_full_unstemmed | New ray on remediation of high rings polycyclic aromatic hydrocarbons: remediation of raw petroleum sludge using solidification and stabilization method |
title_short | New ray on remediation of high rings polycyclic aromatic hydrocarbons: remediation of raw petroleum sludge using solidification and stabilization method |
title_sort | new ray on remediation of high rings polycyclic aromatic hydrocarbons remediation of raw petroleum sludge using solidification and stabilization method |
topic | T Technology (General) |
url | http://eprints.uthm.edu.my/7572/1/J14500_49ab8dc4ed2f712a714ee6e0272c42b4.pdf |
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