Sorption Kinetics, Isotherm Studies and Mechanism of Removal of Organic and Inorganic by Adsorption onto Renewable Biominera

Natural material, agricultural waste, and industrial waste are locally accessible resources that are utilized as environment-friendly and inexpensive sorbent. The natural abundance source like green waste mussel shell (GWMS) adsorbent makes them an advantageous basic sorbent material to produce ine...

Full description

Bibliographic Details
Main Authors: Detho, Amir, Ali Memon, Asif, Hameed Memon, Aftab Hameed, Almohana, Abdulaziz Ibrahim, Daud, Zawawi, Rosli, Mohd Arif
Format: Article
Language:English
Published: Springer 2023
Subjects:
Online Access:http://eprints.uthm.edu.my/8857/1/J15702_dbe8ad6aa57f0020df294ceecd1d5c57.pdf
_version_ 1796869847413424128
author Detho, Amir
Ali Memon, Asif
Hameed Memon, Aftab Hameed
Almohana, Abdulaziz Ibrahim
Daud, Zawawi
Rosli, Mohd Arif
author_facet Detho, Amir
Ali Memon, Asif
Hameed Memon, Aftab Hameed
Almohana, Abdulaziz Ibrahim
Daud, Zawawi
Rosli, Mohd Arif
author_sort Detho, Amir
collection UTHM
description Natural material, agricultural waste, and industrial waste are locally accessible resources that are utilized as environment-friendly and inexpensive sorbent. The natural abundance source like green waste mussel shell (GWMS) adsorbent makes them an advantageous basic sorbent material to produce inexpensive water treatment adsorbent. This study addresses the evaluation of GWMS as an efcient sorbent material to minimize the utilization of traditional adsorbents namely activated carbon (AC) and zeolite (ZEO) for removing pollutants from leachate. COD and ammoniacal nitrogen (NH3–N) were identifed as the two problematic parameters in landfll leachate. Batch adsorption experiments were performed with 100 mL of prepared leachate solution in 2.5 g, 7.5 g, and 12.5 g dosages. The leachate solution was shaken in an incubator for 2 h at 200 rpm shaking speed and pH 7. The GWMS dosage at 7.5 g illustrated that the removal percentage of COD is 71% and that of NH3–N is 47%. The adsorption capacity related to the complete monolayer coverage of saturated molecules shows that the maximum adsorption capacity of COD is 47.39 mg g−1 and that of NH3–N is 26.18 mg g−1. Langmuir and Freundlich values are better described by Langmuir than Freundlich based on R2 values for COD > NH3–N where 0.9941>0.9891. The R2 values for COD > NH3–N for the linear plot of the pseudo-second-order were 0.9997>0.9763, respectively
first_indexed 2024-03-05T22:00:53Z
format Article
id uthm.eprints-8857
institution Universiti Tun Hussein Onn Malaysia
language English
last_indexed 2024-03-05T22:00:53Z
publishDate 2023
publisher Springer
record_format dspace
spelling uthm.eprints-88572023-06-18T01:31:41Z http://eprints.uthm.edu.my/8857/ Sorption Kinetics, Isotherm Studies and Mechanism of Removal of Organic and Inorganic by Adsorption onto Renewable Biominera Detho, Amir Ali Memon, Asif Hameed Memon, Aftab Hameed Almohana, Abdulaziz Ibrahim Daud, Zawawi Rosli, Mohd Arif T Technology (General) Natural material, agricultural waste, and industrial waste are locally accessible resources that are utilized as environment-friendly and inexpensive sorbent. The natural abundance source like green waste mussel shell (GWMS) adsorbent makes them an advantageous basic sorbent material to produce inexpensive water treatment adsorbent. This study addresses the evaluation of GWMS as an efcient sorbent material to minimize the utilization of traditional adsorbents namely activated carbon (AC) and zeolite (ZEO) for removing pollutants from leachate. COD and ammoniacal nitrogen (NH3–N) were identifed as the two problematic parameters in landfll leachate. Batch adsorption experiments were performed with 100 mL of prepared leachate solution in 2.5 g, 7.5 g, and 12.5 g dosages. The leachate solution was shaken in an incubator for 2 h at 200 rpm shaking speed and pH 7. The GWMS dosage at 7.5 g illustrated that the removal percentage of COD is 71% and that of NH3–N is 47%. The adsorption capacity related to the complete monolayer coverage of saturated molecules shows that the maximum adsorption capacity of COD is 47.39 mg g−1 and that of NH3–N is 26.18 mg g−1. Langmuir and Freundlich values are better described by Langmuir than Freundlich based on R2 values for COD > NH3–N where 0.9941>0.9891. The R2 values for COD > NH3–N for the linear plot of the pseudo-second-order were 0.9997>0.9763, respectively Springer 2023 Article PeerReviewed text en http://eprints.uthm.edu.my/8857/1/J15702_dbe8ad6aa57f0020df294ceecd1d5c57.pdf Detho, Amir and Ali Memon, Asif and Hameed Memon, Aftab Hameed and Almohana, Abdulaziz Ibrahim and Daud, Zawawi and Rosli, Mohd Arif (2023) Sorption Kinetics, Isotherm Studies and Mechanism of Removal of Organic and Inorganic by Adsorption onto Renewable Biominera. Water Air Soil Pollut. pp. 1-10. https://doi.org/10.1007/s11270-022-06040-7
spellingShingle T Technology (General)
Detho, Amir
Ali Memon, Asif
Hameed Memon, Aftab Hameed
Almohana, Abdulaziz Ibrahim
Daud, Zawawi
Rosli, Mohd Arif
Sorption Kinetics, Isotherm Studies and Mechanism of Removal of Organic and Inorganic by Adsorption onto Renewable Biominera
title Sorption Kinetics, Isotherm Studies and Mechanism of Removal of Organic and Inorganic by Adsorption onto Renewable Biominera
title_full Sorption Kinetics, Isotherm Studies and Mechanism of Removal of Organic and Inorganic by Adsorption onto Renewable Biominera
title_fullStr Sorption Kinetics, Isotherm Studies and Mechanism of Removal of Organic and Inorganic by Adsorption onto Renewable Biominera
title_full_unstemmed Sorption Kinetics, Isotherm Studies and Mechanism of Removal of Organic and Inorganic by Adsorption onto Renewable Biominera
title_short Sorption Kinetics, Isotherm Studies and Mechanism of Removal of Organic and Inorganic by Adsorption onto Renewable Biominera
title_sort sorption kinetics isotherm studies and mechanism of removal of organic and inorganic by adsorption onto renewable biominera
topic T Technology (General)
url http://eprints.uthm.edu.my/8857/1/J15702_dbe8ad6aa57f0020df294ceecd1d5c57.pdf
work_keys_str_mv AT dethoamir sorptionkineticsisothermstudiesandmechanismofremovaloforganicandinorganicbyadsorptionontorenewablebiominera
AT alimemonasif sorptionkineticsisothermstudiesandmechanismofremovaloforganicandinorganicbyadsorptionontorenewablebiominera
AT hameedmemonaftabhameed sorptionkineticsisothermstudiesandmechanismofremovaloforganicandinorganicbyadsorptionontorenewablebiominera
AT almohanaabdulazizibrahim sorptionkineticsisothermstudiesandmechanismofremovaloforganicandinorganicbyadsorptionontorenewablebiominera
AT daudzawawi sorptionkineticsisothermstudiesandmechanismofremovaloforganicandinorganicbyadsorptionontorenewablebiominera
AT roslimohdarif sorptionkineticsisothermstudiesandmechanismofremovaloforganicandinorganicbyadsorptionontorenewablebiominera