Optimization and kinetic studies on biodiesel conversion from Chlorella vulgaris microalgae using pyrrolidinium-based ionic liquids as a catalyst

This study describes the potential conversion of dried microalgae. Chlorella vulgaris (C. vul-garis) into fatty acid methyl ester (FAME) using the direct transesterification (DT) method and using ionic liquids (ILs) as a catalyst. In this work, the performance of monocationic IL, namely 1-butyl-1-me...

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Bibliographic Details
Main Authors: Hasanudin, Noorhafizah, Abd. Ghani, Noraini, Ab. Rahim, Asyraf Hanim, Azman, Ninna Sakina, Rosdi, Nurhusna Aisyah, Masri, Asiah Nusaibah
Format: Article
Language:English
Published: MDPI 2022
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Online Access:http://eprints.utm.my/101323/1/AsiahNusaibahMasri2022_OptimizationandKineticStudiesonBiodieselConversion.pdf
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Summary:This study describes the potential conversion of dried microalgae. Chlorella vulgaris (C. vul-garis) into fatty acid methyl ester (FAME) using the direct transesterification (DT) method and using ionic liquids (ILs) as a catalyst. In this work, the performance of monocationic IL, namely 1-butyl-1-methylpyrrolidinium bromide (IL 1), and dicationic IL, namely 1,4-bis(1-methylpyrrolidinium-1-yl) butane dibromide (IL 2), as catalysts was compared for DT of C. vulgaris under microwave irradiation. The results revealed that IL 2 showed a better performance in catalyzing the DT reaction by producing 87.9 mg/g% of FAME, while the use of IL 1 led to 74.3 mg/g% of FAME under optimum conditions. The kinetic study for direct transesterification of C. vulgaris showed that the reaction followed a first order kinetic reaction where the activation energies were calculated to be 22.2499 kJ mol-1 and 22.0413 kJ mol-1 for IL 1 and IL 2, respectively.