Vibrational spectroscopic methods for the identification and distinction of essential oils in genus ocimum l.: a chemometric approach

Essential oils are mainly analyzed by gas chromatography coupled with mass spectrometry (GC–MS). This is a time consuming technique which requires complex instrumentation assembly. Raman and FTIR spectroscopy are rapid and non-destructive techniques for qualitative characterization, differentiation...

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Main Authors: Tyagi, Archasvi, Yadav, Anil K., Yadav, Akanksha, Saini, Lalita, Kumar, Vivek, Jain, Pooja, Mohammad, Inam, Ansari, Mohammad Javed, El Enshasy, Hesham Ali, Abdel-Gawad, Fagr Kh., Al Obaid, Sami, Siddiqui, Shahida Anusha, Malik, Vijai
Format: Article
Language:English
Published: Elsevier B.V. 2022
Subjects:
Online Access:http://eprints.utm.my/103374/1/HeshamAliElEnshasy2022_VibrationalSpectroscopicMethods.pdf
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author Tyagi, Archasvi
Yadav, Anil K.
Yadav, Akanksha
Saini, Lalita
Kumar, Vivek
Jain, Pooja
Mohammad, Inam
Ansari, Mohammad Javed
El Enshasy, Hesham Ali
Abdel-Gawad, Fagr Kh.
Al Obaid, Sami
Siddiqui, Shahida Anusha
Malik, Vijai
author_facet Tyagi, Archasvi
Yadav, Anil K.
Yadav, Akanksha
Saini, Lalita
Kumar, Vivek
Jain, Pooja
Mohammad, Inam
Ansari, Mohammad Javed
El Enshasy, Hesham Ali
Abdel-Gawad, Fagr Kh.
Al Obaid, Sami
Siddiqui, Shahida Anusha
Malik, Vijai
author_sort Tyagi, Archasvi
collection ePrints
description Essential oils are mainly analyzed by gas chromatography coupled with mass spectrometry (GC–MS). This is a time consuming technique which requires complex instrumentation assembly. Raman and FTIR spectroscopy are rapid and non-destructive techniques for qualitative characterization, differentiation of principal essential oil components, detection of adulteration in the oil, quality control of essential oil in industry as well as to distinguish different taxa. In the present study, five Ocimum spp. (Ocimum tenuiflorum L., Ocimum gratissimum L., Ocimum × africanum Lour., Ocimum basilicum L. and Ocimum americanum L) have been identified on the basis of essential oil by the Raman and FTIR spectroscopic techniques. It was found that methyl eugenol, eugenol, estragole, and camphor are major essential oils components present in Ocimum L. The results of PCA indicate that all five species of Ocimum L. form different clusters on the basis of principal essential oil components. The components of essential oil predicted by Raman spectroscopy correlate well with that of FTIR data. The present study demonstrates the use of Raman and FTIR spectroscopy techniques to distinguish taxa and characterization of essential oil component.
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spelling utm.eprints-1033742023-11-01T09:23:42Z http://eprints.utm.my/103374/ Vibrational spectroscopic methods for the identification and distinction of essential oils in genus ocimum l.: a chemometric approach Tyagi, Archasvi Yadav, Anil K. Yadav, Akanksha Saini, Lalita Kumar, Vivek Jain, Pooja Mohammad, Inam Ansari, Mohammad Javed El Enshasy, Hesham Ali Abdel-Gawad, Fagr Kh. Al Obaid, Sami Siddiqui, Shahida Anusha Malik, Vijai Q Science (General) Essential oils are mainly analyzed by gas chromatography coupled with mass spectrometry (GC–MS). This is a time consuming technique which requires complex instrumentation assembly. Raman and FTIR spectroscopy are rapid and non-destructive techniques for qualitative characterization, differentiation of principal essential oil components, detection of adulteration in the oil, quality control of essential oil in industry as well as to distinguish different taxa. In the present study, five Ocimum spp. (Ocimum tenuiflorum L., Ocimum gratissimum L., Ocimum × africanum Lour., Ocimum basilicum L. and Ocimum americanum L) have been identified on the basis of essential oil by the Raman and FTIR spectroscopic techniques. It was found that methyl eugenol, eugenol, estragole, and camphor are major essential oils components present in Ocimum L. The results of PCA indicate that all five species of Ocimum L. form different clusters on the basis of principal essential oil components. The components of essential oil predicted by Raman spectroscopy correlate well with that of FTIR data. The present study demonstrates the use of Raman and FTIR spectroscopy techniques to distinguish taxa and characterization of essential oil component. Elsevier B.V. 2022 Article PeerReviewed application/pdf en http://eprints.utm.my/103374/1/HeshamAliElEnshasy2022_VibrationalSpectroscopicMethods.pdf Tyagi, Archasvi and Yadav, Anil K. and Yadav, Akanksha and Saini, Lalita and Kumar, Vivek and Jain, Pooja and Mohammad, Inam and Ansari, Mohammad Javed and El Enshasy, Hesham Ali and Abdel-Gawad, Fagr Kh. and Al Obaid, Sami and Siddiqui, Shahida Anusha and Malik, Vijai (2022) Vibrational spectroscopic methods for the identification and distinction of essential oils in genus ocimum l.: a chemometric approach. Journal of King Saud University - Science, 34 (8). pp. 1-8. ISSN 1018-3647 http://dx.doi.org/10.1016/j.jksus.2022.102355 DOI: 10.1016/j.jksus.2022.102355
spellingShingle Q Science (General)
Tyagi, Archasvi
Yadav, Anil K.
Yadav, Akanksha
Saini, Lalita
Kumar, Vivek
Jain, Pooja
Mohammad, Inam
Ansari, Mohammad Javed
El Enshasy, Hesham Ali
Abdel-Gawad, Fagr Kh.
Al Obaid, Sami
Siddiqui, Shahida Anusha
Malik, Vijai
Vibrational spectroscopic methods for the identification and distinction of essential oils in genus ocimum l.: a chemometric approach
title Vibrational spectroscopic methods for the identification and distinction of essential oils in genus ocimum l.: a chemometric approach
title_full Vibrational spectroscopic methods for the identification and distinction of essential oils in genus ocimum l.: a chemometric approach
title_fullStr Vibrational spectroscopic methods for the identification and distinction of essential oils in genus ocimum l.: a chemometric approach
title_full_unstemmed Vibrational spectroscopic methods for the identification and distinction of essential oils in genus ocimum l.: a chemometric approach
title_short Vibrational spectroscopic methods for the identification and distinction of essential oils in genus ocimum l.: a chemometric approach
title_sort vibrational spectroscopic methods for the identification and distinction of essential oils in genus ocimum l a chemometric approach
topic Q Science (General)
url http://eprints.utm.my/103374/1/HeshamAliElEnshasy2022_VibrationalSpectroscopicMethods.pdf
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