Reclaimed rockwool fibers for thermally stable palm oil-based polyurethane foam

Due to its non-existent recyclability, industrial rockwool fiber wastes have caused environmental and waste management issues, which, therefore, necessitates an effective and sustainable solution. In this paper, palm oil-based polyurethane (PU) foam is synthesized, incorporating reclaimed rockwool f...

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Main Authors: Dzulkifli, Mohd Haziq, Majid, Rohah A., Yahya, Mohd. Yazid
Format: Article
Published: Springer 2022
Subjects:
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author Dzulkifli, Mohd Haziq
Majid, Rohah A.
Yahya, Mohd. Yazid
author_facet Dzulkifli, Mohd Haziq
Majid, Rohah A.
Yahya, Mohd. Yazid
author_sort Dzulkifli, Mohd Haziq
collection ePrints
description Due to its non-existent recyclability, industrial rockwool fiber wastes have caused environmental and waste management issues, which, therefore, necessitates an effective and sustainable solution. In this paper, palm oil-based polyurethane (PU) foam is synthesized, incorporating reclaimed rockwool fibers from discarded industrial insulation system as fillers. The filler loadings were varied from 1 wt.% to 10 wt.%, and fabricated foams were then characterized for their fire retardancy, thermal stability, foam morphology, and mechanical responses. Thermal stability of the foam was significantly improved with inclusion of rockwool fibers as evidenced by marked delay in 50% degradation temperature, T-50, as well as char residue yield in thermogravimetry analysis (TGA). In contrast, no noticeable change was detected for its flammability. Both cell sizes and open cell contents increased with filler content, probably due to the filler inducing delayed blowing reaction. Increasing rockwool fiber contents showed limited improvement in compressive properties, which is thought owed to restricted polymer-filler interfacial area for efficient load transfer. This novel composite foam shows potential for application requiring moderate thermal stability and load-bearing capabilities.
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spelling utm.eprints-1034082023-11-05T09:48:10Z http://eprints.utm.my/103408/ Reclaimed rockwool fibers for thermally stable palm oil-based polyurethane foam Dzulkifli, Mohd Haziq Majid, Rohah A. Yahya, Mohd. Yazid TP Chemical technology Due to its non-existent recyclability, industrial rockwool fiber wastes have caused environmental and waste management issues, which, therefore, necessitates an effective and sustainable solution. In this paper, palm oil-based polyurethane (PU) foam is synthesized, incorporating reclaimed rockwool fibers from discarded industrial insulation system as fillers. The filler loadings were varied from 1 wt.% to 10 wt.%, and fabricated foams were then characterized for their fire retardancy, thermal stability, foam morphology, and mechanical responses. Thermal stability of the foam was significantly improved with inclusion of rockwool fibers as evidenced by marked delay in 50% degradation temperature, T-50, as well as char residue yield in thermogravimetry analysis (TGA). In contrast, no noticeable change was detected for its flammability. Both cell sizes and open cell contents increased with filler content, probably due to the filler inducing delayed blowing reaction. Increasing rockwool fiber contents showed limited improvement in compressive properties, which is thought owed to restricted polymer-filler interfacial area for efficient load transfer. This novel composite foam shows potential for application requiring moderate thermal stability and load-bearing capabilities. Springer 2022 Article PeerReviewed Dzulkifli, Mohd Haziq and Majid, Rohah A. and Yahya, Mohd. Yazid (2022) Reclaimed rockwool fibers for thermally stable palm oil-based polyurethane foam. 10.1007/s10163-022-01488-5, 24 (6). pp. 2416-2425. ISSN 1438-4957 http://dx.doi.org/10.1007/s10163-022-01488-5 DOI: 10.1007/s10163-022-01488-5
spellingShingle TP Chemical technology
Dzulkifli, Mohd Haziq
Majid, Rohah A.
Yahya, Mohd. Yazid
Reclaimed rockwool fibers for thermally stable palm oil-based polyurethane foam
title Reclaimed rockwool fibers for thermally stable palm oil-based polyurethane foam
title_full Reclaimed rockwool fibers for thermally stable palm oil-based polyurethane foam
title_fullStr Reclaimed rockwool fibers for thermally stable palm oil-based polyurethane foam
title_full_unstemmed Reclaimed rockwool fibers for thermally stable palm oil-based polyurethane foam
title_short Reclaimed rockwool fibers for thermally stable palm oil-based polyurethane foam
title_sort reclaimed rockwool fibers for thermally stable palm oil based polyurethane foam
topic TP Chemical technology
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AT majidrohaha reclaimedrockwoolfibersforthermallystablepalmoilbasedpolyurethanefoam
AT yahyamohdyazid reclaimedrockwoolfibersforthermallystablepalmoilbasedpolyurethanefoam