Oil-water interfacial tension, wettability alteration and foaming studies of natural surfactant extracted from Vernonia Amygdalina

Surfactant flooding is an enhanced oil recovery (EOR) method for recovering residual oil in the reservoir through mechanism of interfacial tension (IFT) reduction and wettability alteration. Due to toxicity and high cost associated with conventional surfactants, recent research has focussed on devel...

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Main Authors: Imuetinyan, Happiness, Agi, Augustine, Gbadamosi, Afeez, Junin, Radzuan, Oseh, Jeffrey
Format: Article
Language:English
Published: KeAi Communication Co. Ltd., Elsevier B.V. 2022
Subjects:
Online Access:http://eprints.utm.my/103548/1/RadzuanJunin2022_OilWaterInterfacialTensionWettability.pdf
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author Imuetinyan, Happiness
Agi, Augustine
Gbadamosi, Afeez
Junin, Radzuan
Oseh, Jeffrey
author_facet Imuetinyan, Happiness
Agi, Augustine
Gbadamosi, Afeez
Junin, Radzuan
Oseh, Jeffrey
author_sort Imuetinyan, Happiness
collection ePrints
description Surfactant flooding is an enhanced oil recovery (EOR) method for recovering residual oil in the reservoir through mechanism of interfacial tension (IFT) reduction and wettability alteration. Due to toxicity and high cost associated with conventional surfactants, recent research has focussed on developing low-cost and environmentally benign surfactants. Herein, a low-cost green surfactant is extracted from Vernonia Amygdalina (VA) and appraised for EOR applications. The extracted surfactant was characterized using Fourier Transform Infrared (FTIR) and High-Pressure Liquid Chromatography (HPLC). The IFT of the synthesized surfactant at the oil-water interface was determined using Kruss tensiometer. Additionally, the foam stability of the synthesized surfactant was examined. Moreover, the wettability of the saponin based natural surfactant (SBNS) at the rock-fluid interface was analysed using Dataphysics drop shape analyser. Experimental result revealed that SBNS (1 wt% concentration) stabilized foam for longer periods with half-life of 1100 min. Furthermore, the synthesized surfactant was effective in lowering the IFT of oil-water interface from 18 mN/m to 0.97 mN/m. Finally, SBNS altered the wettability of sandstone cores to water-wetting condition by reducing the contact angle from 118.5 ° to 45.7 °. Overall, SBNS exhibit excellent properties desirable for EOR and thereby recommended as supplementary alternative to conventional surfactants.
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spelling utm.eprints-1035482023-11-14T06:42:43Z http://eprints.utm.my/103548/ Oil-water interfacial tension, wettability alteration and foaming studies of natural surfactant extracted from Vernonia Amygdalina Imuetinyan, Happiness Agi, Augustine Gbadamosi, Afeez Junin, Radzuan Oseh, Jeffrey Q Science (General) Surfactant flooding is an enhanced oil recovery (EOR) method for recovering residual oil in the reservoir through mechanism of interfacial tension (IFT) reduction and wettability alteration. Due to toxicity and high cost associated with conventional surfactants, recent research has focussed on developing low-cost and environmentally benign surfactants. Herein, a low-cost green surfactant is extracted from Vernonia Amygdalina (VA) and appraised for EOR applications. The extracted surfactant was characterized using Fourier Transform Infrared (FTIR) and High-Pressure Liquid Chromatography (HPLC). The IFT of the synthesized surfactant at the oil-water interface was determined using Kruss tensiometer. Additionally, the foam stability of the synthesized surfactant was examined. Moreover, the wettability of the saponin based natural surfactant (SBNS) at the rock-fluid interface was analysed using Dataphysics drop shape analyser. Experimental result revealed that SBNS (1 wt% concentration) stabilized foam for longer periods with half-life of 1100 min. Furthermore, the synthesized surfactant was effective in lowering the IFT of oil-water interface from 18 mN/m to 0.97 mN/m. Finally, SBNS altered the wettability of sandstone cores to water-wetting condition by reducing the contact angle from 118.5 ° to 45.7 °. Overall, SBNS exhibit excellent properties desirable for EOR and thereby recommended as supplementary alternative to conventional surfactants. KeAi Communication Co. Ltd., Elsevier B.V. 2022-09 Article PeerReviewed application/pdf en http://eprints.utm.my/103548/1/RadzuanJunin2022_OilWaterInterfacialTensionWettability.pdf Imuetinyan, Happiness and Agi, Augustine and Gbadamosi, Afeez and Junin, Radzuan and Oseh, Jeffrey (2022) Oil-water interfacial tension, wettability alteration and foaming studies of natural surfactant extracted from Vernonia Amygdalina. Petroleum Research, 7 (3). pp. 350-356. ISSN 2096-2495 http://dx.doi.org/10.1016/j.ptlrs.2021.12.006 DOI:10.1016/j.ptlrs.2021.12.006
spellingShingle Q Science (General)
Imuetinyan, Happiness
Agi, Augustine
Gbadamosi, Afeez
Junin, Radzuan
Oseh, Jeffrey
Oil-water interfacial tension, wettability alteration and foaming studies of natural surfactant extracted from Vernonia Amygdalina
title Oil-water interfacial tension, wettability alteration and foaming studies of natural surfactant extracted from Vernonia Amygdalina
title_full Oil-water interfacial tension, wettability alteration and foaming studies of natural surfactant extracted from Vernonia Amygdalina
title_fullStr Oil-water interfacial tension, wettability alteration and foaming studies of natural surfactant extracted from Vernonia Amygdalina
title_full_unstemmed Oil-water interfacial tension, wettability alteration and foaming studies of natural surfactant extracted from Vernonia Amygdalina
title_short Oil-water interfacial tension, wettability alteration and foaming studies of natural surfactant extracted from Vernonia Amygdalina
title_sort oil water interfacial tension wettability alteration and foaming studies of natural surfactant extracted from vernonia amygdalina
topic Q Science (General)
url http://eprints.utm.my/103548/1/RadzuanJunin2022_OilWaterInterfacialTensionWettability.pdf
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