A short review on the promotional effects of ceria-based catalyst for dry reforming methane

Dry reforming of methane (DRM) appears as a promising process for the industrial production of syngas in comparison to other conventional reforming technologies. However, DRM process suffers from catalyst deactivation induced by carbonaceous species which reduces the catalyst lifespan. Currently, ca...

Full description

Bibliographic Details
Main Authors: Liew, S. Y., Jalil, A. A.
Format: Conference or Workshop Item
Language:English
Published: 2022
Subjects:
Online Access:http://eprints.utm.my/103791/1/AishahAbdJalil2022_AShortReviewonthePromotionalEffects.pdf
_version_ 1796867529875914752
author Liew, S. Y.
Jalil, A. A.
author_facet Liew, S. Y.
Jalil, A. A.
author_sort Liew, S. Y.
collection ePrints
description Dry reforming of methane (DRM) appears as a promising process for the industrial production of syngas in comparison to other conventional reforming technologies. However, DRM process suffers from catalyst deactivation induced by carbonaceous species which reduces the catalyst lifespan. Currently, catalytic designs in DRM have trended towards the incorporation rare-earth metals. As such, ceria (Ce) based catalyst has recently attracted research interest for its key feature to mitigate catalyst deactivation owing to its complementary redox and oxygen storage properties for the removal of surface carbon deposit. The present short review summarizes on the recent catalytic performance of Ce-based catalyst and impact of ceria redox on the DRM mechanism. The utilization of oxygen vacancies introduced by the Ce redox support enhances the catalytic activity by providing additional bifunctional sites and intermediate species to facilitate the surface reaction rate. This perspective will elucidate the role of oxygen vacancies in Ce supports and fine tune the catalytic performance of DRM for industrial applications.
first_indexed 2024-03-05T21:28:38Z
format Conference or Workshop Item
id utm.eprints-103791
institution Universiti Teknologi Malaysia - ePrints
language English
last_indexed 2024-03-05T21:28:38Z
publishDate 2022
record_format dspace
spelling utm.eprints-1037912023-11-26T06:33:52Z http://eprints.utm.my/103791/ A short review on the promotional effects of ceria-based catalyst for dry reforming methane Liew, S. Y. Jalil, A. A. TP Chemical technology Dry reforming of methane (DRM) appears as a promising process for the industrial production of syngas in comparison to other conventional reforming technologies. However, DRM process suffers from catalyst deactivation induced by carbonaceous species which reduces the catalyst lifespan. Currently, catalytic designs in DRM have trended towards the incorporation rare-earth metals. As such, ceria (Ce) based catalyst has recently attracted research interest for its key feature to mitigate catalyst deactivation owing to its complementary redox and oxygen storage properties for the removal of surface carbon deposit. The present short review summarizes on the recent catalytic performance of Ce-based catalyst and impact of ceria redox on the DRM mechanism. The utilization of oxygen vacancies introduced by the Ce redox support enhances the catalytic activity by providing additional bifunctional sites and intermediate species to facilitate the surface reaction rate. This perspective will elucidate the role of oxygen vacancies in Ce supports and fine tune the catalytic performance of DRM for industrial applications. 2022 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.utm.my/103791/1/AishahAbdJalil2022_AShortReviewonthePromotionalEffects.pdf Liew, S. Y. and Jalil, A. A. (2022) A short review on the promotional effects of ceria-based catalyst for dry reforming methane. In: 9th Conference on Emerging Energy and Process Technology 2021, CONCEPT 2021, 24 November 2021 - 25 November 2021, Johor Bahru, Johor. http://dx.doi.org/10.1088/1742-6596/2259/1/012020
spellingShingle TP Chemical technology
Liew, S. Y.
Jalil, A. A.
A short review on the promotional effects of ceria-based catalyst for dry reforming methane
title A short review on the promotional effects of ceria-based catalyst for dry reforming methane
title_full A short review on the promotional effects of ceria-based catalyst for dry reforming methane
title_fullStr A short review on the promotional effects of ceria-based catalyst for dry reforming methane
title_full_unstemmed A short review on the promotional effects of ceria-based catalyst for dry reforming methane
title_short A short review on the promotional effects of ceria-based catalyst for dry reforming methane
title_sort short review on the promotional effects of ceria based catalyst for dry reforming methane
topic TP Chemical technology
url http://eprints.utm.my/103791/1/AishahAbdJalil2022_AShortReviewonthePromotionalEffects.pdf
work_keys_str_mv AT liewsy ashortreviewonthepromotionaleffectsofceriabasedcatalystfordryreformingmethane
AT jalilaa ashortreviewonthepromotionaleffectsofceriabasedcatalystfordryreformingmethane
AT liewsy shortreviewonthepromotionaleffectsofceriabasedcatalystfordryreformingmethane
AT jalilaa shortreviewonthepromotionaleffectsofceriabasedcatalystfordryreformingmethane