Flexible back-illuminated dye sensitised solar cells (DSSCs) with titanium dioxide/silver nanoparticles composite photoanode for improvement of power conversion efficiency

With flexibility practices becoming a vital concern for dye sensitised solar cells (DSSCs) today, researchers are widely developing choices of excel conductivity and durable anode substrate, which is metal. As metals are exposed to light impenetrability caused by its opacity, the illumination sides...

Full description

Bibliographic Details
Main Authors: Shamsudin, Nur Hazahsha, Shafie, S., Ab. Kadir, Mohd. Zainal Abidin, Ahmad, Fauzan, Sulaiman, Yusran, Mohd. Chachuli, Siti Amaniah, Che Razali, Mashitah
Format: Article
Published: Elsevier GmbH 2023
Subjects:
_version_ 1811132274463211520
author Shamsudin, Nur Hazahsha
Shafie, S.
Ab. Kadir, Mohd. Zainal Abidin
Ahmad, Fauzan
Sulaiman, Yusran
Mohd. Chachuli, Siti Amaniah
Che Razali, Mashitah
author_facet Shamsudin, Nur Hazahsha
Shafie, S.
Ab. Kadir, Mohd. Zainal Abidin
Ahmad, Fauzan
Sulaiman, Yusran
Mohd. Chachuli, Siti Amaniah
Che Razali, Mashitah
author_sort Shamsudin, Nur Hazahsha
collection ePrints
description With flexibility practices becoming a vital concern for dye sensitised solar cells (DSSCs) today, researchers are widely developing choices of excel conductivity and durable anode substrate, which is metal. As metals are exposed to light impenetrability caused by its opacity, the illumination sides were transitioned from the front-side to backside of the DSSCs. The less light absorption reduces the power conversion efficiency (PCE). The surface treatment was posited onto the titanium (Ti) substrate in promoting a gap for titanium dioxide (TiO2) during deposition, as well as discarding the oxide layer of the Ti surface. To improve the PCE for backside illumination DSSCs of Ti substrate, this paper proposes the embedment of silver nanoparticles (AgNPs) into TiO2 at various concentrations between 1.0 wt% and 3.0 wt%. The AgNPs were produced by solvothermal method in sizes of 23 nm, 25 nm, 29 nm, and 36 nm. The chosen size of 29 nm has been laid on the ultraviolet-visible (UV-Vis) and transmission electron microscopy (TEM) with the highest absorbance and low status of agglomeration. The back-illuminated AgNPs-TiO2 film acquired optimal PCE = 4.691%, Jsc = 10.0 mA/cm2, FF = 0.67, and Voc = 0.70 mV in response to the 2.0 wt% concentration of AgNPs-TiO2 deposited onto a flexible Ti substrate.
first_indexed 2024-09-24T00:00:42Z
format Article
id utm.eprints-106123
institution Universiti Teknologi Malaysia - ePrints
last_indexed 2024-09-24T00:00:42Z
publishDate 2023
publisher Elsevier GmbH
record_format dspace
spelling utm.eprints-1061232024-06-06T08:42:44Z http://eprints.utm.my/106123/ Flexible back-illuminated dye sensitised solar cells (DSSCs) with titanium dioxide/silver nanoparticles composite photoanode for improvement of power conversion efficiency Shamsudin, Nur Hazahsha Shafie, S. Ab. Kadir, Mohd. Zainal Abidin Ahmad, Fauzan Sulaiman, Yusran Mohd. Chachuli, Siti Amaniah Che Razali, Mashitah TK Electrical engineering. Electronics Nuclear engineering With flexibility practices becoming a vital concern for dye sensitised solar cells (DSSCs) today, researchers are widely developing choices of excel conductivity and durable anode substrate, which is metal. As metals are exposed to light impenetrability caused by its opacity, the illumination sides were transitioned from the front-side to backside of the DSSCs. The less light absorption reduces the power conversion efficiency (PCE). The surface treatment was posited onto the titanium (Ti) substrate in promoting a gap for titanium dioxide (TiO2) during deposition, as well as discarding the oxide layer of the Ti surface. To improve the PCE for backside illumination DSSCs of Ti substrate, this paper proposes the embedment of silver nanoparticles (AgNPs) into TiO2 at various concentrations between 1.0 wt% and 3.0 wt%. The AgNPs were produced by solvothermal method in sizes of 23 nm, 25 nm, 29 nm, and 36 nm. The chosen size of 29 nm has been laid on the ultraviolet-visible (UV-Vis) and transmission electron microscopy (TEM) with the highest absorbance and low status of agglomeration. The back-illuminated AgNPs-TiO2 film acquired optimal PCE = 4.691%, Jsc = 10.0 mA/cm2, FF = 0.67, and Voc = 0.70 mV in response to the 2.0 wt% concentration of AgNPs-TiO2 deposited onto a flexible Ti substrate. Elsevier GmbH 2023-02 Article PeerReviewed Shamsudin, Nur Hazahsha and Shafie, S. and Ab. Kadir, Mohd. Zainal Abidin and Ahmad, Fauzan and Sulaiman, Yusran and Mohd. Chachuli, Siti Amaniah and Che Razali, Mashitah (2023) Flexible back-illuminated dye sensitised solar cells (DSSCs) with titanium dioxide/silver nanoparticles composite photoanode for improvement of power conversion efficiency. Optik, 272 (NA). NA. ISSN 0030-4026 http://dx.doi.org/10.1016/j.ijleo.2022.170237 DOI:10.1016/j.ijleo.2022.170237
spellingShingle TK Electrical engineering. Electronics Nuclear engineering
Shamsudin, Nur Hazahsha
Shafie, S.
Ab. Kadir, Mohd. Zainal Abidin
Ahmad, Fauzan
Sulaiman, Yusran
Mohd. Chachuli, Siti Amaniah
Che Razali, Mashitah
Flexible back-illuminated dye sensitised solar cells (DSSCs) with titanium dioxide/silver nanoparticles composite photoanode for improvement of power conversion efficiency
title Flexible back-illuminated dye sensitised solar cells (DSSCs) with titanium dioxide/silver nanoparticles composite photoanode for improvement of power conversion efficiency
title_full Flexible back-illuminated dye sensitised solar cells (DSSCs) with titanium dioxide/silver nanoparticles composite photoanode for improvement of power conversion efficiency
title_fullStr Flexible back-illuminated dye sensitised solar cells (DSSCs) with titanium dioxide/silver nanoparticles composite photoanode for improvement of power conversion efficiency
title_full_unstemmed Flexible back-illuminated dye sensitised solar cells (DSSCs) with titanium dioxide/silver nanoparticles composite photoanode for improvement of power conversion efficiency
title_short Flexible back-illuminated dye sensitised solar cells (DSSCs) with titanium dioxide/silver nanoparticles composite photoanode for improvement of power conversion efficiency
title_sort flexible back illuminated dye sensitised solar cells dsscs with titanium dioxide silver nanoparticles composite photoanode for improvement of power conversion efficiency
topic TK Electrical engineering. Electronics Nuclear engineering
work_keys_str_mv AT shamsudinnurhazahsha flexiblebackilluminateddyesensitisedsolarcellsdsscswithtitaniumdioxidesilvernanoparticlescompositephotoanodeforimprovementofpowerconversionefficiency
AT shafies flexiblebackilluminateddyesensitisedsolarcellsdsscswithtitaniumdioxidesilvernanoparticlescompositephotoanodeforimprovementofpowerconversionefficiency
AT abkadirmohdzainalabidin flexiblebackilluminateddyesensitisedsolarcellsdsscswithtitaniumdioxidesilvernanoparticlescompositephotoanodeforimprovementofpowerconversionefficiency
AT ahmadfauzan flexiblebackilluminateddyesensitisedsolarcellsdsscswithtitaniumdioxidesilvernanoparticlescompositephotoanodeforimprovementofpowerconversionefficiency
AT sulaimanyusran flexiblebackilluminateddyesensitisedsolarcellsdsscswithtitaniumdioxidesilvernanoparticlescompositephotoanodeforimprovementofpowerconversionefficiency
AT mohdchachulisitiamaniah flexiblebackilluminateddyesensitisedsolarcellsdsscswithtitaniumdioxidesilvernanoparticlescompositephotoanodeforimprovementofpowerconversionefficiency
AT cherazalimashitah flexiblebackilluminateddyesensitisedsolarcellsdsscswithtitaniumdioxidesilvernanoparticlescompositephotoanodeforimprovementofpowerconversionefficiency