Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution.
The motivation of the present study was a synthesis of the nanocomposites of UiO-66@ZnO/Biochar to embed carbendazim (CBZ) pesticide inside its porous structures for smart spraying and cleaner production. CBZ@UiO-66@ZnO/Biochar had the purpose of not only smart spraying to avoid releasing a large am...
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| Format: | Article |
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Elsevier Ltd.
2023
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| _version_ | 1811132321533788160 |
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| author | Nguyen, Hoang Ly Nguyen, Binh Nguyen Huynh, Nhu Tran Thi Thuy, Hang Hoang Joo, Sang-Woo Vasseghian, Yasser Kamyab, Hesam Chelliapan, Shreeshivadasan Jirí, Jaromír Klemeš |
| author_facet | Nguyen, Hoang Ly Nguyen, Binh Nguyen Huynh, Nhu Tran Thi Thuy, Hang Hoang Joo, Sang-Woo Vasseghian, Yasser Kamyab, Hesam Chelliapan, Shreeshivadasan Jirí, Jaromír Klemeš |
| author_sort | Nguyen, Hoang Ly |
| collection | ePrints |
| description | The motivation of the present study was a synthesis of the nanocomposites of UiO-66@ZnO/Biochar to embed carbendazim (CBZ) pesticide inside its porous structures for smart spraying and cleaner production. CBZ@UiO-66@ZnO/Biochar had the purpose of not only smart spraying to avoid releasing a large amount of CBZ into the groundwater but also of accurately delivering the CBZ pesticide to the desired grass/plant. High-resolution electron microscopy was introduced to characterise the morphologies of prepared composites with spatial elemental distribution mapping. X-ray diffraction (XRD) patterns and micro-Raman spectroscopy were employed for the crystal structures of UiO-66@ZnO. Spectral UV–Vis and Fourier transform-infrared (FT-IR) tools were utilized to estimate the UiO-66@ZnO/Biochar-based adsorption and release of CBZ into the dimethyl sulfoxide (DMSO)-water mixture. Our results indicated that the adsorption capacities of CBZ into the DMSO-water mixture onto UiO-66@ZnO and UiO-66@ZnO/Biochar nanocomposites were obtained at 68.8% and 72.6%. The half-life of photodegradation rate constants for CBZ@UiO-66@ZnO/Biochar was found to be 12.3 times longer than that of free CBZ. Notably, CBZ@UiO-66@ZnO/Biochar inhibitory concentration 50% (IC50) determination was estimated at 73.8 μg/L and 209 μg/L for Fusarium oxysporum and Aspergillus niger. This work provides a comprehensive experimental scheme for the chemisorption process of CBZ onto the UiO-66@ZnO/Biochar composite materials and the nanopesticide applications in sustainable agriculture towards cleaner productions. |
| first_indexed | 2024-09-24T00:01:41Z |
| format | Article |
| id | utm.eprints-106353 |
| institution | Universiti Teknologi Malaysia - ePrints |
| last_indexed | 2024-09-24T00:01:41Z |
| publishDate | 2023 |
| publisher | Elsevier Ltd. |
| record_format | dspace |
| spelling | utm.eprints-1063532024-06-29T06:57:31Z http://eprints.utm.my/106353/ Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution. Nguyen, Hoang Ly Nguyen, Binh Nguyen Huynh, Nhu Tran Thi Thuy, Hang Hoang Joo, Sang-Woo Vasseghian, Yasser Kamyab, Hesam Chelliapan, Shreeshivadasan Jirí, Jaromír Klemeš QD Chemistry The motivation of the present study was a synthesis of the nanocomposites of UiO-66@ZnO/Biochar to embed carbendazim (CBZ) pesticide inside its porous structures for smart spraying and cleaner production. CBZ@UiO-66@ZnO/Biochar had the purpose of not only smart spraying to avoid releasing a large amount of CBZ into the groundwater but also of accurately delivering the CBZ pesticide to the desired grass/plant. High-resolution electron microscopy was introduced to characterise the morphologies of prepared composites with spatial elemental distribution mapping. X-ray diffraction (XRD) patterns and micro-Raman spectroscopy were employed for the crystal structures of UiO-66@ZnO. Spectral UV–Vis and Fourier transform-infrared (FT-IR) tools were utilized to estimate the UiO-66@ZnO/Biochar-based adsorption and release of CBZ into the dimethyl sulfoxide (DMSO)-water mixture. Our results indicated that the adsorption capacities of CBZ into the DMSO-water mixture onto UiO-66@ZnO and UiO-66@ZnO/Biochar nanocomposites were obtained at 68.8% and 72.6%. The half-life of photodegradation rate constants for CBZ@UiO-66@ZnO/Biochar was found to be 12.3 times longer than that of free CBZ. Notably, CBZ@UiO-66@ZnO/Biochar inhibitory concentration 50% (IC50) determination was estimated at 73.8 μg/L and 209 μg/L for Fusarium oxysporum and Aspergillus niger. This work provides a comprehensive experimental scheme for the chemisorption process of CBZ onto the UiO-66@ZnO/Biochar composite materials and the nanopesticide applications in sustainable agriculture towards cleaner productions. Elsevier Ltd. 2023-05-20 Article PeerReviewed Nguyen, Hoang Ly and Nguyen, Binh Nguyen and Huynh, Nhu Tran and Thi Thuy, Hang Hoang and Joo, Sang-Woo and Vasseghian, Yasser and Kamyab, Hesam and Chelliapan, Shreeshivadasan and Jirí, Jaromír Klemeš (2023) Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution. Journal of Cleaner Production, 402 (136809). NA-NA. ISSN 0959-6526 https://doi.org/10.1016/j.jclepro.2023.136809 DOI: 10.1016/j.jclepro.2023.136809 |
| spellingShingle | QD Chemistry Nguyen, Hoang Ly Nguyen, Binh Nguyen Huynh, Nhu Tran Thi Thuy, Hang Hoang Joo, Sang-Woo Vasseghian, Yasser Kamyab, Hesam Chelliapan, Shreeshivadasan Jirí, Jaromír Klemeš Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution. |
| title | Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution. |
| title_full | Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution. |
| title_fullStr | Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution. |
| title_full_unstemmed | Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution. |
| title_short | Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution. |
| title_sort | metal organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution |
| topic | QD Chemistry |
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