Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating

Vegetable oil has been extensively investigated as a precursor to the eco-friendly coating as an alternative to petrochemical-based resources due to its lower carbon footprint properties. In view of this, jatropha oil (JO), a type of non-edible oil, has received significant attention in this field....

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Main Authors: Wong, Jia Li, Aung, Min Min, Rayung, Marwah, Lim, Hong Ngee, Lee, Mark Wun Fui
Format: Article
Published: Elsevier B.V. 2023
Subjects:
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author Wong, Jia Li
Aung, Min Min
Rayung, Marwah
Lim, Hong Ngee
Lee, Mark Wun Fui
author_facet Wong, Jia Li
Aung, Min Min
Rayung, Marwah
Lim, Hong Ngee
Lee, Mark Wun Fui
author_sort Wong, Jia Li
collection ePrints
description Vegetable oil has been extensively investigated as a precursor to the eco-friendly coating as an alternative to petrochemical-based resources due to its lower carbon footprint properties. In view of this, jatropha oil (JO), a type of non-edible oil, has received significant attention in this field. The present study was undertaken to utilize acrylated epoxidized jatropha oil (AEJO) resin and to evaluate the anti-corrosion performance with the addition of graphene nanoplatelets (GNP). AEJO-GNP nanocomposites coatings were obtained after three passes of ultraviolet (UV) irradiation. The corrosion protection of all nanocomposites coatings was investigated by electrochemical measurements. The results showed that the corrosion performance of AEJO-GNP nanocomposites coatings improved from the blank coating. Among all coatings tested, AEJO-0.5 wt% GNP exhibited the strongest barrier property and maximum performance in corrosion protection. The result was supported by water contact angle and pull-off adhesion tests. In addition, the highest pull-off adhesion strength for GNP fillers added coatings was established at 0.5 wt% of GNP. High hydrophobicity and pull-off adhesion strength coatings provided a physical barrier that created a tortuosity pathway for corrosive electrolytes to reach the metal surface and thus showed better anti-corrosion resistance. Thus, nanocomposites coatings with 0.5 wt% GNP exhibited the best anti-corrosive efficacy and surface coating property.
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spelling utm.eprints-1065502024-07-09T06:52:54Z http://eprints.utm.my/106550/ Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating Wong, Jia Li Aung, Min Min Rayung, Marwah Lim, Hong Ngee Lee, Mark Wun Fui QD Chemistry Vegetable oil has been extensively investigated as a precursor to the eco-friendly coating as an alternative to petrochemical-based resources due to its lower carbon footprint properties. In view of this, jatropha oil (JO), a type of non-edible oil, has received significant attention in this field. The present study was undertaken to utilize acrylated epoxidized jatropha oil (AEJO) resin and to evaluate the anti-corrosion performance with the addition of graphene nanoplatelets (GNP). AEJO-GNP nanocomposites coatings were obtained after three passes of ultraviolet (UV) irradiation. The corrosion protection of all nanocomposites coatings was investigated by electrochemical measurements. The results showed that the corrosion performance of AEJO-GNP nanocomposites coatings improved from the blank coating. Among all coatings tested, AEJO-0.5 wt% GNP exhibited the strongest barrier property and maximum performance in corrosion protection. The result was supported by water contact angle and pull-off adhesion tests. In addition, the highest pull-off adhesion strength for GNP fillers added coatings was established at 0.5 wt% of GNP. High hydrophobicity and pull-off adhesion strength coatings provided a physical barrier that created a tortuosity pathway for corrosive electrolytes to reach the metal surface and thus showed better anti-corrosion resistance. Thus, nanocomposites coatings with 0.5 wt% GNP exhibited the best anti-corrosive efficacy and surface coating property. Elsevier B.V. 2023-02 Article PeerReviewed Wong, Jia Li and Aung, Min Min and Rayung, Marwah and Lim, Hong Ngee and Lee, Mark Wun Fui (2023) Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating. Progress in Organic Coatings, 175 (NA). NA. ISSN 0300-9440 http://dx.doi.org/10.1016/j.porgcoat.2022.107349 DOI:10.1016/j.porgcoat.2022.107349
spellingShingle QD Chemistry
Wong, Jia Li
Aung, Min Min
Rayung, Marwah
Lim, Hong Ngee
Lee, Mark Wun Fui
Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title_full Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title_fullStr Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title_full_unstemmed Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title_short Bio-based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
title_sort bio based acrylated epoxidized jatropha oil incorporated with graphene nanoplatelets in the assessment of corrosion resistance coating
topic QD Chemistry
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