Comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly(vinyl chloride) compounds and poly(vinyl chloride)/(oil palm empty fruit bunch) composites

The effects of chlorinated polyethylene (CPE) and acrylic impact modifier (AIM) on the thermal degradation of poly(vinyl chloride) (PVC) compounds and composites were investigated. The amounts of AIM and CPE used were fixed at 9 parts per hundred parts of resin (phr), while oil palm empty fruit bunc...

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Main Authors: Abu Bakar, Aznizam, Hassan, Azman, Mohd. Yusof, Ahmad Fuad
Format: Article
Published: Society of Plastics Engineers 2010
Subjects:
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author Abu Bakar, Aznizam
Hassan, Azman
Mohd. Yusof, Ahmad Fuad
author_facet Abu Bakar, Aznizam
Hassan, Azman
Mohd. Yusof, Ahmad Fuad
author_sort Abu Bakar, Aznizam
collection ePrints
description The effects of chlorinated polyethylene (CPE) and acrylic impact modifier (AIM) on the thermal degradation of poly(vinyl chloride) (PVC) compounds and composites were investigated. The amounts of AIM and CPE used were fixed at 9 parts per hundred parts of resin (phr), while oil palm empty fruit bunch (OPEFB) fiber content was increased from 0 to 40 phr. To produce composites, the PVC formulations were dry-blended by using a laboratory blender before being milled into sheets on a two-roll mill at 165°C. The milled sheets were then hot-pressed at 180°C. The thermal degradation of the specimens was evaluated by using thermogravimetry in a nitrogen environment. Thermal stability of the PVC/CPE compounds and PVC/CPE/OPEFB composites was improved by the addition of CPE. The CPE retarded the dehydrochlorination of PVC. However, the stabilization effect was reduced by the incorporation of OPEFB at levels of 30 and 40 phr. The presence of AIM accelerated the dehydrochlorination of PVC/AIM compounds and PVC/AIM/OPEFB composites.
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spelling utm.eprints-229632018-03-22T10:30:39Z http://eprints.utm.my/22963/ Comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly(vinyl chloride) compounds and poly(vinyl chloride)/(oil palm empty fruit bunch) composites Abu Bakar, Aznizam Hassan, Azman Mohd. Yusof, Ahmad Fuad TP Chemical technology The effects of chlorinated polyethylene (CPE) and acrylic impact modifier (AIM) on the thermal degradation of poly(vinyl chloride) (PVC) compounds and composites were investigated. The amounts of AIM and CPE used were fixed at 9 parts per hundred parts of resin (phr), while oil palm empty fruit bunch (OPEFB) fiber content was increased from 0 to 40 phr. To produce composites, the PVC formulations were dry-blended by using a laboratory blender before being milled into sheets on a two-roll mill at 165°C. The milled sheets were then hot-pressed at 180°C. The thermal degradation of the specimens was evaluated by using thermogravimetry in a nitrogen environment. Thermal stability of the PVC/CPE compounds and PVC/CPE/OPEFB composites was improved by the addition of CPE. The CPE retarded the dehydrochlorination of PVC. However, the stabilization effect was reduced by the incorporation of OPEFB at levels of 30 and 40 phr. The presence of AIM accelerated the dehydrochlorination of PVC/AIM compounds and PVC/AIM/OPEFB composites. Society of Plastics Engineers 2010-04-28 Article PeerReviewed Abu Bakar, Aznizam and Hassan, Azman and Mohd. Yusof, Ahmad Fuad (2010) Comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly(vinyl chloride) compounds and poly(vinyl chloride)/(oil palm empty fruit bunch) composites. Journal of Vinyl & Additive Technology, 16 (2). 135 - 140. ISSN 1548-0585 http://dx.doi.org/10.1002/vnl.20237 DOI: 10.1002/vnl.20237
spellingShingle TP Chemical technology
Abu Bakar, Aznizam
Hassan, Azman
Mohd. Yusof, Ahmad Fuad
Comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly(vinyl chloride) compounds and poly(vinyl chloride)/(oil palm empty fruit bunch) composites
title Comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly(vinyl chloride) compounds and poly(vinyl chloride)/(oil palm empty fruit bunch) composites
title_full Comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly(vinyl chloride) compounds and poly(vinyl chloride)/(oil palm empty fruit bunch) composites
title_fullStr Comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly(vinyl chloride) compounds and poly(vinyl chloride)/(oil palm empty fruit bunch) composites
title_full_unstemmed Comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly(vinyl chloride) compounds and poly(vinyl chloride)/(oil palm empty fruit bunch) composites
title_short Comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly(vinyl chloride) compounds and poly(vinyl chloride)/(oil palm empty fruit bunch) composites
title_sort comparative study of the effects of chlorinated polyethylene and acrylic impact modifier on the thermal degradation of poly vinyl chloride compounds and poly vinyl chloride oil palm empty fruit bunch composites
topic TP Chemical technology
work_keys_str_mv AT abubakaraznizam comparativestudyoftheeffectsofchlorinatedpolyethyleneandacrylicimpactmodifieronthethermaldegradationofpolyvinylchloridecompoundsandpolyvinylchlorideoilpalmemptyfruitbunchcomposites
AT hassanazman comparativestudyoftheeffectsofchlorinatedpolyethyleneandacrylicimpactmodifieronthethermaldegradationofpolyvinylchloridecompoundsandpolyvinylchlorideoilpalmemptyfruitbunchcomposites
AT mohdyusofahmadfuad comparativestudyoftheeffectsofchlorinatedpolyethyleneandacrylicimpactmodifieronthethermaldegradationofpolyvinylchloridecompoundsandpolyvinylchlorideoilpalmemptyfruitbunchcomposites