Bromido({2-[2-(Diphenylphosphanyl)Benzylidene]Hydrazin-1-Ylidene} (4-Methoxyanilino)Methanethiolato)Palladium(Ii) Acetone Monosolvate
In the title compound, [PdBr(C27H23N3OPS)]·C3H6O, the coordination geometry about the PdII atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings attached to...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | http://eprints.utm.my/32943/1/MustaffaShamsuddin2012_Bromido%28%7B2-%5B2-%28diphenylphosphanyl%29-benzylidene%5Dhydrazin-1.pdf |
| _version_ | 1796857089464729600 |
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| author | Mokthar, Khalisah Asilah Shamsuddin, Mustaffa Rosli, Mohd. Mustaqim Hoong, Kun Fun |
| author_facet | Mokthar, Khalisah Asilah Shamsuddin, Mustaffa Rosli, Mohd. Mustaqim Hoong, Kun Fun |
| author_sort | Mokthar, Khalisah Asilah |
| collection | ePrints |
| description | In the title compound, [PdBr(C27H23N3OPS)]·C3H6O, the coordination geometry about the PdII atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings attached to the P atom make dihedral angles of 69.78 (7), 87.05 (7) and 77.50 (7)° with each other. An intramolecular C-H...N hydrogen bond forms an S(6) ring motif. In the crystal, the complex molecules form infinite chains along the a-axis direction through C-H...Br interactions, and a C-H...O interaction links the main molecule with the acetone solvent molecule. |
| first_indexed | 2024-03-05T18:52:34Z |
| format | Article |
| id | utm.eprints-32943 |
| institution | Universiti Teknologi Malaysia - ePrints |
| language | English |
| last_indexed | 2024-03-05T18:52:34Z |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | utm.eprints-329432018-11-30T06:33:34Z http://eprints.utm.my/32943/ Bromido({2-[2-(Diphenylphosphanyl)Benzylidene]Hydrazin-1-Ylidene} (4-Methoxyanilino)Methanethiolato)Palladium(Ii) Acetone Monosolvate Mokthar, Khalisah Asilah Shamsuddin, Mustaffa Rosli, Mohd. Mustaqim Hoong, Kun Fun QD Chemistry In the title compound, [PdBr(C27H23N3OPS)]·C3H6O, the coordination geometry about the PdII atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings attached to the P atom make dihedral angles of 69.78 (7), 87.05 (7) and 77.50 (7)° with each other. An intramolecular C-H...N hydrogen bond forms an S(6) ring motif. In the crystal, the complex molecules form infinite chains along the a-axis direction through C-H...Br interactions, and a C-H...O interaction links the main molecule with the acetone solvent molecule. International Union of Crystallography 2012-07 Article PeerReviewed application/pdf en http://eprints.utm.my/32943/1/MustaffaShamsuddin2012_Bromido%28%7B2-%5B2-%28diphenylphosphanyl%29-benzylidene%5Dhydrazin-1.pdf Mokthar, Khalisah Asilah and Shamsuddin, Mustaffa and Rosli, Mohd. Mustaqim and Hoong, Kun Fun (2012) Bromido({2-[2-(Diphenylphosphanyl)Benzylidene]Hydrazin-1-Ylidene} (4-Methoxyanilino)Methanethiolato)Palladium(Ii) Acetone Monosolvate. Acta Crystallographica Section E: Structure Reports Online, 68 (7). pp. 991-992. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536812028760 DOI:10.1107/S1600536812028760 |
| spellingShingle | QD Chemistry Mokthar, Khalisah Asilah Shamsuddin, Mustaffa Rosli, Mohd. Mustaqim Hoong, Kun Fun Bromido({2-[2-(Diphenylphosphanyl)Benzylidene]Hydrazin-1-Ylidene} (4-Methoxyanilino)Methanethiolato)Palladium(Ii) Acetone Monosolvate |
| title | Bromido({2-[2-(Diphenylphosphanyl)Benzylidene]Hydrazin-1-Ylidene} (4-Methoxyanilino)Methanethiolato)Palladium(Ii) Acetone Monosolvate |
| title_full | Bromido({2-[2-(Diphenylphosphanyl)Benzylidene]Hydrazin-1-Ylidene} (4-Methoxyanilino)Methanethiolato)Palladium(Ii) Acetone Monosolvate |
| title_fullStr | Bromido({2-[2-(Diphenylphosphanyl)Benzylidene]Hydrazin-1-Ylidene} (4-Methoxyanilino)Methanethiolato)Palladium(Ii) Acetone Monosolvate |
| title_full_unstemmed | Bromido({2-[2-(Diphenylphosphanyl)Benzylidene]Hydrazin-1-Ylidene} (4-Methoxyanilino)Methanethiolato)Palladium(Ii) Acetone Monosolvate |
| title_short | Bromido({2-[2-(Diphenylphosphanyl)Benzylidene]Hydrazin-1-Ylidene} (4-Methoxyanilino)Methanethiolato)Palladium(Ii) Acetone Monosolvate |
| title_sort | bromido 2 2 diphenylphosphanyl benzylidene hydrazin 1 ylidene 4 methoxyanilino methanethiolato palladium ii acetone monosolvate |
| topic | QD Chemistry |
| url | http://eprints.utm.my/32943/1/MustaffaShamsuddin2012_Bromido%28%7B2-%5B2-%28diphenylphosphanyl%29-benzylidene%5Dhydrazin-1.pdf |
| work_keys_str_mv | AT moktharkhalisahasilah bromido22diphenylphosphanylbenzylidenehydrazin1ylidene4methoxyanilinomethanethiolatopalladiumiiacetonemonosolvate AT shamsuddinmustaffa bromido22diphenylphosphanylbenzylidenehydrazin1ylidene4methoxyanilinomethanethiolatopalladiumiiacetonemonosolvate AT roslimohdmustaqim bromido22diphenylphosphanylbenzylidenehydrazin1ylidene4methoxyanilinomethanethiolatopalladiumiiacetonemonosolvate AT hoongkunfun bromido22diphenylphosphanylbenzylidenehydrazin1ylidene4methoxyanilinomethanethiolatopalladiumiiacetonemonosolvate |