Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films

Radiation-induced grafting of styrene onto poly(tetra¯uoroethylene) (PTFE) films was studied by a simultaneous irradiation technique. Grafting was carried out using g-radiation from a 60Co source at dose rates of 1.32±15.0kGyhÿ1 at room temperature. The effects of type of diluent, dose rate, irra...

Full description

Bibliographic Details
Main Authors: Nasef, Mohamed Mahmoud, Saidi, Hamdani, Dessouki, Ahmed Mokhtar, EI-Nesr, Eman Mohamed
Format: Article
Language:English
Published: 2000
Subjects:
Online Access:http://eprints.utm.my/3685/1/Nasef2000_Radiation-induceGraftingStyreneOntoPTFE.pdf
_version_ 1825909430943744000
author Nasef, Mohamed Mahmoud
Saidi, Hamdani
Dessouki, Ahmed Mokhtar
EI-Nesr, Eman Mohamed
author_facet Nasef, Mohamed Mahmoud
Saidi, Hamdani
Dessouki, Ahmed Mokhtar
EI-Nesr, Eman Mohamed
author_sort Nasef, Mohamed Mahmoud
collection ePrints
description Radiation-induced grafting of styrene onto poly(tetra¯uoroethylene) (PTFE) films was studied by a simultaneous irradiation technique. Grafting was carried out using g-radiation from a 60Co source at dose rates of 1.32±15.0kGyhÿ1 at room temperature. The effects of type of diluent, dose rate, irradiation dose, and the initial monomer concentration in the grafting solution on the degree of grafting were investigated. The degree of grafting was found to be strongly dependent upon the grafting conditions. The dependence of the initial rate of grafting on the dose rate and the initial monomer concentration in the grafting solution was found to be in the order of 0.6 and 1.7, respectively. The chemical structure and the crystallinity of the grafted PTFE films were studied by means of Fouriertransform infrared, (FTIR), electron spectroscopy for chemical analysis (ESCA) and X-ray diffractometry (XRD).
first_indexed 2024-03-05T18:02:03Z
format Article
id utm.eprints-3685
institution Universiti Teknologi Malaysia - ePrints
language English
last_indexed 2024-03-05T18:02:03Z
publishDate 2000
record_format dspace
spelling utm.eprints-36852010-06-01T03:11:26Z http://eprints.utm.my/3685/ Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films Nasef, Mohamed Mahmoud Saidi, Hamdani Dessouki, Ahmed Mokhtar EI-Nesr, Eman Mohamed TP Chemical technology Radiation-induced grafting of styrene onto poly(tetra¯uoroethylene) (PTFE) films was studied by a simultaneous irradiation technique. Grafting was carried out using g-radiation from a 60Co source at dose rates of 1.32±15.0kGyhÿ1 at room temperature. The effects of type of diluent, dose rate, irradiation dose, and the initial monomer concentration in the grafting solution on the degree of grafting were investigated. The degree of grafting was found to be strongly dependent upon the grafting conditions. The dependence of the initial rate of grafting on the dose rate and the initial monomer concentration in the grafting solution was found to be in the order of 0.6 and 1.7, respectively. The chemical structure and the crystallinity of the grafted PTFE films were studied by means of Fouriertransform infrared, (FTIR), electron spectroscopy for chemical analysis (ESCA) and X-ray diffractometry (XRD). 2000 Article PeerReviewed application/pdf en http://eprints.utm.my/3685/1/Nasef2000_Radiation-induceGraftingStyreneOntoPTFE.pdf Nasef, Mohamed Mahmoud and Saidi, Hamdani and Dessouki, Ahmed Mokhtar and EI-Nesr, Eman Mohamed (2000) Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films. Polymer International, 49 . pp. 399-406.
spellingShingle TP Chemical technology
Nasef, Mohamed Mahmoud
Saidi, Hamdani
Dessouki, Ahmed Mokhtar
EI-Nesr, Eman Mohamed
Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films
title Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films
title_full Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films
title_fullStr Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films
title_full_unstemmed Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films
title_short Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films
title_sort radiation induced grafting of styrene onto poly tetrafluoroethylene ptfe films i effect of grafting conditions and properties of the grafted films
topic TP Chemical technology
url http://eprints.utm.my/3685/1/Nasef2000_Radiation-induceGraftingStyreneOntoPTFE.pdf
work_keys_str_mv AT nasefmohamedmahmoud radiationinducedgraftingofstyreneontopolytetrafluoroethyleneptfefilmsieffectofgraftingconditionsandpropertiesofthegraftedfilms
AT saidihamdani radiationinducedgraftingofstyreneontopolytetrafluoroethyleneptfefilmsieffectofgraftingconditionsandpropertiesofthegraftedfilms
AT dessoukiahmedmokhtar radiationinducedgraftingofstyreneontopolytetrafluoroethyleneptfefilmsieffectofgraftingconditionsandpropertiesofthegraftedfilms
AT einesremanmohamed radiationinducedgraftingofstyreneontopolytetrafluoroethyleneptfefilmsieffectofgraftingconditionsandpropertiesofthegraftedfilms