Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films
Radiation-induced grafting of styrene onto poly(tetra¯uoroethylene) (PTFE) films was studied by a simultaneous irradiation technique. Grafting was carried out using g-radiation from a 60Co source at dose rates of 1.32±15.0kGyhÿ1 at room temperature. The effects of type of diluent, dose rate, irra...
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2000
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Online Access: | http://eprints.utm.my/3685/1/Nasef2000_Radiation-induceGraftingStyreneOntoPTFE.pdf |
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author | Nasef, Mohamed Mahmoud Saidi, Hamdani Dessouki, Ahmed Mokhtar EI-Nesr, Eman Mohamed |
author_facet | Nasef, Mohamed Mahmoud Saidi, Hamdani Dessouki, Ahmed Mokhtar EI-Nesr, Eman Mohamed |
author_sort | Nasef, Mohamed Mahmoud |
collection | ePrints |
description | Radiation-induced grafting of styrene onto poly(tetra¯uoroethylene) (PTFE) films was studied by a simultaneous irradiation technique. Grafting was carried out using g-radiation from a 60Co source at dose rates of 1.32±15.0kGyhÿ1 at room temperature. The effects of type of diluent, dose rate, irradiation dose, and the initial monomer concentration in the grafting solution on the degree of grafting were investigated. The degree of grafting was found to be strongly dependent upon the grafting conditions. The dependence of the initial rate of grafting on the dose rate and the initial monomer concentration in the grafting solution was found to be in the order of 0.6 and 1.7, respectively. The chemical structure and the crystallinity of the grafted PTFE films were studied by means of Fouriertransform infrared, (FTIR), electron spectroscopy for chemical analysis (ESCA) and X-ray diffractometry (XRD). |
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institution | Universiti Teknologi Malaysia - ePrints |
language | English |
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publishDate | 2000 |
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spelling | utm.eprints-36852010-06-01T03:11:26Z http://eprints.utm.my/3685/ Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films Nasef, Mohamed Mahmoud Saidi, Hamdani Dessouki, Ahmed Mokhtar EI-Nesr, Eman Mohamed TP Chemical technology Radiation-induced grafting of styrene onto poly(tetra¯uoroethylene) (PTFE) films was studied by a simultaneous irradiation technique. Grafting was carried out using g-radiation from a 60Co source at dose rates of 1.32±15.0kGyhÿ1 at room temperature. The effects of type of diluent, dose rate, irradiation dose, and the initial monomer concentration in the grafting solution on the degree of grafting were investigated. The degree of grafting was found to be strongly dependent upon the grafting conditions. The dependence of the initial rate of grafting on the dose rate and the initial monomer concentration in the grafting solution was found to be in the order of 0.6 and 1.7, respectively. The chemical structure and the crystallinity of the grafted PTFE films were studied by means of Fouriertransform infrared, (FTIR), electron spectroscopy for chemical analysis (ESCA) and X-ray diffractometry (XRD). 2000 Article PeerReviewed application/pdf en http://eprints.utm.my/3685/1/Nasef2000_Radiation-induceGraftingStyreneOntoPTFE.pdf Nasef, Mohamed Mahmoud and Saidi, Hamdani and Dessouki, Ahmed Mokhtar and EI-Nesr, Eman Mohamed (2000) Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films. Polymer International, 49 . pp. 399-406. |
spellingShingle | TP Chemical technology Nasef, Mohamed Mahmoud Saidi, Hamdani Dessouki, Ahmed Mokhtar EI-Nesr, Eman Mohamed Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films |
title | Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films |
title_full | Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films |
title_fullStr | Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films |
title_full_unstemmed | Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films |
title_short | Radiation-induced grafting of styrene onto poly(tetrafluoroethylene) (PTFE) films. I. Effect of grafting conditions and properties of the grafted films |
title_sort | radiation induced grafting of styrene onto poly tetrafluoroethylene ptfe films i effect of grafting conditions and properties of the grafted films |
topic | TP Chemical technology |
url | http://eprints.utm.my/3685/1/Nasef2000_Radiation-induceGraftingStyreneOntoPTFE.pdf |
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