On the hydrogen-graphene layers interactions, relevance to the onboard storage problem
Empirical evaluations of fundamental characteristics of the physical and chemical interaction of hydrogen with graphene layers in different kinds of graphite and novel carbonaceous nanomaterials of graphene layer structure have been carried out. This was done by using the approaches of the thermodyn...
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| Format: | Article |
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American Scientific Publishers
2012
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| _version_ | 1796859121097506816 |
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| author | Nechaev, Yu S. Ochsner, A. |
| author_facet | Nechaev, Yu S. Ochsner, A. |
| author_sort | Nechaev, Yu S. |
| collection | ePrints |
| description | Empirical evaluations of fundamental characteristics of the physical and chemical interaction of hydrogen with graphene layers in different kinds of graphite and novel carbonaceous nanomaterials of graphene layer structure have been carried out. This was done by using the approaches of the thermodynamics of reversible and irreversible processes for analysis of the adsorption, absorption, diffusion, the temperature-programmed desorption (TPD) and other experimental data and comparing such analytical results with first-principles calculations. Such an analysis of a number of the known experimental and theoretical data has shown a real possibility of the multilayer specific adsorption (intercalation) of hydrogen between graphene layers in novel carbonaceous nanomaterials. This is of relevance for solving the bottle-neck problem of the hydrogen on-board storage in fuel-cell-powered vehicles, and other technical applications. |
| first_indexed | 2024-03-05T19:22:29Z |
| format | Article |
| id | utm.eprints-47300 |
| institution | Universiti Teknologi Malaysia - ePrints |
| last_indexed | 2024-03-05T19:22:29Z |
| publishDate | 2012 |
| publisher | American Scientific Publishers |
| record_format | dspace |
| spelling | utm.eprints-473002019-03-05T01:59:12Z http://eprints.utm.my/47300/ On the hydrogen-graphene layers interactions, relevance to the onboard storage problem Nechaev, Yu S. Ochsner, A. TJ Mechanical engineering and machinery Empirical evaluations of fundamental characteristics of the physical and chemical interaction of hydrogen with graphene layers in different kinds of graphite and novel carbonaceous nanomaterials of graphene layer structure have been carried out. This was done by using the approaches of the thermodynamics of reversible and irreversible processes for analysis of the adsorption, absorption, diffusion, the temperature-programmed desorption (TPD) and other experimental data and comparing such analytical results with first-principles calculations. Such an analysis of a number of the known experimental and theoretical data has shown a real possibility of the multilayer specific adsorption (intercalation) of hydrogen between graphene layers in novel carbonaceous nanomaterials. This is of relevance for solving the bottle-neck problem of the hydrogen on-board storage in fuel-cell-powered vehicles, and other technical applications. American Scientific Publishers 2012 Article PeerReviewed Nechaev, Yu S. and Ochsner, A. (2012) On the hydrogen-graphene layers interactions, relevance to the onboard storage problem. Journal of Nanoscience and Nanotechnology, 12 (10). pp. 8169-8200. ISSN 1533-4880 http://dx.doi.org/10.1166/jnn.2012.4529 DOI:10.1166/jnn.2012.4529 |
| spellingShingle | TJ Mechanical engineering and machinery Nechaev, Yu S. Ochsner, A. On the hydrogen-graphene layers interactions, relevance to the onboard storage problem |
| title | On the hydrogen-graphene layers interactions, relevance to the onboard storage problem |
| title_full | On the hydrogen-graphene layers interactions, relevance to the onboard storage problem |
| title_fullStr | On the hydrogen-graphene layers interactions, relevance to the onboard storage problem |
| title_full_unstemmed | On the hydrogen-graphene layers interactions, relevance to the onboard storage problem |
| title_short | On the hydrogen-graphene layers interactions, relevance to the onboard storage problem |
| title_sort | on the hydrogen graphene layers interactions relevance to the onboard storage problem |
| topic | TJ Mechanical engineering and machinery |
| work_keys_str_mv | AT nechaevyus onthehydrogengraphenelayersinteractionsrelevancetotheonboardstorageproblem AT ochsnera onthehydrogengraphenelayersinteractionsrelevancetotheonboardstorageproblem |