Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex
Herein novel mesoporous silica film nanocomposites are successfully synthesized by using phosphorescent columnar assembly of an amphiphilic trinuclear gold (I) pyrazolate complex [Au3Pz3] as a functional template in the sol-gel synthesis. By controlling the molar ratios of silica source tetrabutylor...
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| Format: | Article |
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Trans Tech Publications Ltd.
2012
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| _version_ | 1796859170115289088 |
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| author | Hendrik, O. Lintang Kinbara, Kazushi Aida, Takuzo |
| author_facet | Hendrik, O. Lintang Kinbara, Kazushi Aida, Takuzo |
| author_sort | Hendrik, O. Lintang |
| collection | ePrints |
| description | Herein novel mesoporous silica film nanocomposites are successfully synthesized by using phosphorescent columnar assembly of an amphiphilic trinuclear gold (I) pyrazolate complex [Au3Pz3] as a functional template in the sol-gel synthesis. By controlling the molar ratios of silica source tetrabutylorthosilicate (TBOS) to [Au3Pz3] in an acidic aqueous alcohol solution from 60:1 to 20:1, highly ordered phosphorescent nanocomposites can be fabricated with hexagonal [Au3Pz3]/silicahex and lamellar [Au3Pz3]/silicalam silicates. |
| first_indexed | 2024-03-05T19:23:13Z |
| format | Article |
| id | utm.eprints-47589 |
| institution | Universiti Teknologi Malaysia - ePrints |
| last_indexed | 2024-03-05T19:23:13Z |
| publishDate | 2012 |
| publisher | Trans Tech Publications Ltd. |
| record_format | dspace |
| spelling | utm.eprints-475892020-02-29T13:15:00Z http://eprints.utm.my/47589/ Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex Hendrik, O. Lintang Kinbara, Kazushi Aida, Takuzo TA Engineering (General). Civil engineering (General) Herein novel mesoporous silica film nanocomposites are successfully synthesized by using phosphorescent columnar assembly of an amphiphilic trinuclear gold (I) pyrazolate complex [Au3Pz3] as a functional template in the sol-gel synthesis. By controlling the molar ratios of silica source tetrabutylorthosilicate (TBOS) to [Au3Pz3] in an acidic aqueous alcohol solution from 60:1 to 20:1, highly ordered phosphorescent nanocomposites can be fabricated with hexagonal [Au3Pz3]/silicahex and lamellar [Au3Pz3]/silicalam silicates. Trans Tech Publications Ltd. 2012 Article PeerReviewed Hendrik, O. Lintang and Kinbara, Kazushi and Aida, Takuzo (2012) Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex. Advanced Materials Research, 364 . pp. 55-59. ISSN 1022-6680 https://dx.doi.org/10.4028/www.scientific.net/AMR.364.55 DOI:10.4028/www.scientific.net/AMR.364.55 |
| spellingShingle | TA Engineering (General). Civil engineering (General) Hendrik, O. Lintang Kinbara, Kazushi Aida, Takuzo Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex |
| title | Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex |
| title_full | Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex |
| title_fullStr | Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex |
| title_full_unstemmed | Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex |
| title_short | Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex |
| title_sort | template sol gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold i pyrazolate complex |
| topic | TA Engineering (General). Civil engineering (General) |
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